期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 35, 页码 7550-7553出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01814e
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资金
- BBSRC [BB/H017011/1, BB/H01683X/1]
- BBSRC [BBS/E/C/00005194] Funding Source: UKRI
- Biotechnology and Biological Sciences Research Council [BB/H01683X/1, BB/H017011/1, BBS/E/C/00005194] Funding Source: researchfish
A synthetic biology approach to the rational design of analogues of olfactory ligands by providing unnatural substrates for the enzyme synthesising (S)-germacrene D, an olfactory ligand acting as a plant derived insect repellent, to produce novel ligands is described as a viable alternative to largely unsuccessful ligand docking studies. (S)-14,15-Dimethylgermacrene D shows an unexpected reversal in behavioural activity.
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