期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 12, 页码 2320-2323出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08736d
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资金
- China Scholarship Council
The highly enantioselective synthesis of densely functionalized 2,3-indoline-cyclobutanes by means of chiral gold catalysis is presented. Intermolecular formal [2+2]-cycloaddition reactions between substituted indoles and allenamides enabled direct access to methylenecyclobutane-fused indolines, featuring two consecutive quaternary stereogenic centers with excellent stereochemical control (dr > 20: 1, ee up to 99%).
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