期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 85, 页码 15530-15533出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06577a
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资金
- Office of Basic Energy Sciences (BES), U.S. Department of Energy (DOE), DOE/BES/Division of Materials Sciences and Engineering [KC020105-FWP12152]
- U.S. Department of Energy by Battelle Memorial Institute [DE-AC05-76RL01830]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152362] Funding Source: National Science Foundation
Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)(2)(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 fromdry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.
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