4.7 Article

New insights into effects of Ru on the oxidation behaviour of Ni-based single-crystal superalloys at 1150 °C

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CORROSION SCIENCE
卷 223, 期 -, 页码 -

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2023.111464

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A. Ni-based superalloys; B. TEM; EPMA; Weight loss; C. High-temperature corrosion; Oxidation

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This study provides new insights into the Ru-effects on the oxidation resistance of some fourth-generation single-crystal Ni-based superalloys at 1150 degrees C. Ru additions were found to decrease the oxidation resistance of the alloys due to the formation of micro-pores and cracks in the oxide scale, despite inhibiting the precipitation of undesirable TCP phases.
This study provides new insights into Ru-effects on the oxidation resistance of some fourth-generation singlecrystal Ni-based superalloys at 1150 degrees C. No apparent evaporation of Ru-oxides was observed. On the contrary, HCP-structured Ru-Re solid solution ((Ru,Re)ss) particles were found to be embedded in the oxide scale for the Ru-added alloys. Local evaporation of Re-oxides from the (Ru,Re)ss particles, as well as the internal stress at their boundaries, gives birth to micro-pores and cracks and increased the spallation of oxide scales upon cooling. Despite the inhibition of undesirable TCP phase precipitation, Ru additions degrade the high-temperature oxidation resistance of the alloys considerably.

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