期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 44, 页码 9097-9100出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02947c
关键词
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资金
- National Natural Science Foundation of China (NSFC) [21225103, 21471087, 21301105, 21221062]
- Beijing Natural Science Foundation [2144051]
- Specialized Research Fund for the Doctoral Program of Higher Education of China
- Tsinghua University Initiative Foundation Research Program [20131089204]
- THSJZ
- Key Laboratory of Polyoxometalate Science of the Ministry of Education of China
The mu(2)-O atom in Anderson polyoxometalates was regioselectively activated by the introduction of protons, which, upon functionalization with triol ligands, could afford a series of unique chi isomers of the organically-derived Anderson cluster {[RCC(CH2O)(3)]MMo6O18(OH)(3)}(3-). Herein proton-controlled isomer transformation between the delta and chi isomer was observed by using the fingerprint region in the IR spectra and C-13 NMR spectra.
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