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Article
Engineering, Manufacturing
Jianjian Luo et al.
Summary: In this study, ZIF-8@PDA@Cu nanohybrids were successfully synthesized using polydopamine (PDA) as a functional adjuvant. These nanohybrids exhibited excellent dispersion and strong interfacial interactions with thermoplastic polyurethane (TPU) substrate. TPU/ZIF-8@PDA@Cu composites demonstrated remarkable thermal stability, flame resistance, and toxic smoke inhibition performance. The metal compounds formed by the thermal degradation of ZIF-8@PDA@Cu nano-hybrids significantly reduced the release of toxic gases through a cyclic redox reaction with carbon monoxide.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2023)
Article
Chemistry, Physical
Kaili Gong et al.
Summary: This study successfully synthesized silicon-reinforced MXene-based nanoarchitectures and demonstrated their enhancement effects on epoxy resin, including improved thermal stability, reduced heat release rate and smoke production rate, and increased yield and stability of chars.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Analytical
Yuhui Wei et al.
Summary: Rationally designing and constructing electrocatalytic nanomaterials is crucial for enhancing the sensitivity and selectivity of non-enzyme-based electrochemical sensors. In this study, a NiMn layered double hydroxide (LDH)-based MOF material was synthesized and used as an electrochemical electrode for highly sensitive detection of glucose. The NiMn-LDH-MOF exhibited excellent electrocatalytic activity for glucose oxidation, and the NiMn-LDH-MOF/GCE sensor showed a wide linear detection range, low detection limit, and high sensitivity. Additionally, the sensor demonstrated good selectivity and reliability for glucose detection in actual serum samples.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Lei Liu et al.
Summary: Frequent fire disasters have caused significant impacts on the environment, humans, and the economy. MXene is a potential flame retardant that can provide passive fire protection and active fire response through its physical barrier and thermoelectric effect. This article provides an overview of passive flame-retardant materials and next-generation smart fire warning materials/sensors based on MXene, discussing their design, characterization, performance, applications, and challenges for future practical use.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Engineering, Environmental
Hao Jiang et al.
Summary: By adding polyphosphazene-functionalized MXene nanosheets into epoxy resin, the mechanical and flame-retardant properties of the resin are significantly improved, demonstrating the potential of this method in designing efficient synergetic flame retardants.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Environmental Sciences
Wenhui Rao et al.
Summary: In this study, copper organophosphate nanosheets were grown on the surface of graphene oxide to improve the flame retardancy and mechanical properties of epoxy resins. The incorporation of functionalized nanosheets significantly improved the impact strength of the nanocomposites. The nanosheets also inhibited smoke and heat release, making the epoxy matrix more fire-safe.
Article
Chemistry, Multidisciplinary
Hao Xie et al.
Summary: NiCoP constructed on a conductive substrate exhibits efficient catalytic activity for oxygen reduction reaction (ORR). In this work, the in-situ growth of NiCoP on MXene nanosheets (MXene@NiCoP) is reported. The presence of MXene nanosheets accelerates electron transfer and enhances the surface activity of NiCoP. Density functional theory calculations show that MXene@NiCoP possesses the advantages of a low overpotential and high OH* adsorption energy during the ORR process. MXene@NiCoP is demonstrated to be a highly active catalyst for ORR with a half-wave potential of 0.71 V vs. RHE. The assembled single-chamber air-cathode microbial fuel cell achieves high electricity generation performance.
Article
Chemistry, Physical
Rui Duan et al.
Summary: The study successfully enhanced the fire safety of epoxy resin (EP) using phosphor nitrile functionalized UiO-66-NH2/graphene (G-U-H) material, with a mechanism involving both condensed phase and gas phase actions, forming stable residual char and non-flammable gases to effectively block heat transmission.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Engineering, Manufacturing
Kaili Gong et al.
Summary: The interface-engineered strategy used in this study, involving the introduction of polyaniline coating, established a strong interfacial linkage between phosphorus-doped cerium oxide and epoxy resin, resulting in superb fire resistance of the epoxy composites.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Engineering, Multidisciplinary
Junling Wang et al.
Summary: A hierarchical structure (MLBCN) based on LDH anchored boron-doped g-C3N4 assembled with MnO2 nanosheets was constructed as a flame retardant additive for epoxy resin. The incorporation of 1.0 wt% MLBCN led to significant decreases in heat release rate and smoke production, along with inhibited emissions of toxic gases. Additionally, MLBCN enhanced the mechanical performance of EP. Overall, using MLBCN achieved simultaneous enhancements in fire safety and mechanical capability of the polymer.
COMPOSITES PART B-ENGINEERING
(2022)
Article
Engineering, Multidisciplinary
Yanlong Sui et al.
Summary: A novel bioderived flame retardant PHDT@FeCo-LDH was successfully synthesized and applied in epoxy resin with significant effects, reducing peak heat release rate, total heat release, and total smoke release. The mechanical properties of the composites were also improved, showing a promising potential for industrial applications.
COMPOSITES PART B-ENGINEERING
(2022)
Article
Chemistry, Physical
Lian Yin et al.
Summary: By in-situ decoration and chemical etching, ternary integrated boron nitride nanosheet nanoparticles were prepared, improving the thermal stability of epoxy resin and reducing fire hazards. The nano barrier effect and catalytic activity help suppress the release of combustible volatile products.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Review
Chemistry, Applied
Baljinder K. Kandola et al.
Summary: This article discusses the flammability and flame retardants of epoxy resins. Epoxy resins are highly versatile and can be tailored for desired properties through different curing agents and processes. The choice of flame retardants is crucial for achieving the required level of flame retardancy, and the processability and performance in different applications are also discussed.
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
(2022)
Article
Polymer Science
Elvara Windra Madyaratri et al.
Summary: Biocomposites reinforced with natural fibers are an eco-friendly and inexpensive alternative to petroleum-based materials. However, their high flammability limits their applications. The use of flame-retardant additives can improve their fire resistance. This study discusses the flammability of wood and natural fibers as material resources and the use of lignin as a flame-retardant additive to produce high-performance biocomposites.
Review
Chemistry, Physical
Duraisami Dhamodharan et al.
Summary: The paper discusses the synthesis, properties, and potential applications of layered two-dimensional (2D) nitrides and carbides (2D-MXenes) in different fields. These materials possess valuable and adjustable mechanical, optical, electrochemical, and electronic properties, making them suitable for electromagnetic interference shielding, medicine, sensing, optoelectronics, energy storage, and catalysis. Additionally, the challenges and prospects of MXenes as materials are highlighted.
Article
Engineering, Environmental
Junling Wang et al.
Summary: The use of metal oxides double-shelled nanocages derived from metal organic frameworks (MOFs) has been shown to effectively suppress the emission of smoke and toxic gases from epoxy resin. In addition, the nanocages also improve the mechanical performance of the material.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Manufacturing
Keqing Zhou et al.
Summary: This study developed a simple strategy to synthesize MXene@LDH nanohybrids for constructing efficient flame retardant systems in polymer composites. The results showed that MXene@LDH improved the flame retardancy and smoke suppression performance of the composites.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Engineering, Multidisciplinary
Kaili Gong et al.
Summary: MXene, a graphene-like material, shows promising flame retardant potential in polymers. This study investigates the effect of bimetallic MXene on flame retardant performance and finds that the introduction of bimetallic MXene into epoxy resin composites significantly improves their flame retardant properties.
COMPOSITES PART B-ENGINEERING
(2022)
Article
Materials Science, Characterization & Testing
Weihua Meng et al.
Summary: In this study, PA-modified MXene (P-MXene) was prepared and mixed with epoxy resin (EP) to investigate its flame retardancy and thermal conductivity. The results showed that P-MXene endowed EP with excellent flame retardancy, while the conductivity and mechanical properties were slightly reduced.
Article
Engineering, Manufacturing
Haobo Zhou et al.
Summary: A ternary hierarchical nano-architecture of Cu2O@LMX was constructed to reduce the heat and toxic volatiles emissions of epoxy resin and improve its mechanical properties. This work may provide valuable insights for the construction of high-performance MXenes-based polymer composites.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Chemistry, Physical
Wenhui Wang et al.
Summary: In this study, Ni2Co(PO4)2 microspheres were synthesized using urea as a pH regulator. The resulting microspheres exhibited uniform and well-dispersed spherical morphology and showed larger electrochemical specific surface area and smaller resistance of electrons/ions transfer compared to traditional particles. The specific capacity of the microspheres reached as high as 153 mAh g(-1), which was 1.59 times higher than that of traditional particles. Additionally, this facile one-step synthetic method could be applied to fabricate Ni-Co phosphates with different Ni/Co atomic ratios.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Polymer Science
Maoyong Zhi et al.
Summary: This review provides a brief analysis of the combustion process, flame-retardant mechanism, and classification of flame-retardant epoxy resins. It introduces important characterization methods and summarizes the latest research progress in reactive flame-retardant epoxy resins. The future perspectives of reactive flame-retardant epoxy resins are also discussed.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Materials Science, Characterization & Testing
Cheng Liu et al.
Summary: A novel reactive multi-element flame retardant, PmDOH, was designed and synthesized to improve the flame retardant performance of epoxy resins. The PmDOH modified epoxy resin showed a more compact and continuous char layer during combustion.
Article
Materials Science, Composites
Zhu-Bao Shao et al.
Summary: A novel constructing strategy was used to obtain super-efficient flame retardants containing metal elements for epoxy resin, resulting in excellent fire protection.
COMPOSITES COMMUNICATIONS
(2022)
Review
Engineering, Environmental
Wenhua Chen et al.
Summary: MXenes, as a new family of two-dimensional nanomaterials, have shown great potential in flame retardant composites due to their metal-like conductivity, diverse surface chemistry and solution processability. This review provides the latest research progress on flame retardant composites using neat MXenes, functionalized MXenes and synergistic systems based on MXenes and other components. The efficiency and modification strategies of MXenes-based flame retardants are discussed, with a focus on the working mechanisms in different matrices. Furthermore, flame retardant MXenes-based composites also exhibit multiple functions such as EMI shielding, thermal conductivity and electro-/photo-thermal conversion, leading to wider applications in high-end fields.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Manufacturing
Kaili Gong et al.
Summary: In this study, MXene-based flame retardants were prepared using an organic-inorganic hybrid strategy and incorporated into epoxy resins. The results showed that these hybrids significantly improved the fire safety and smoke suppression effects of the epoxy resin composites.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2022)
Article
Polymer Science
Long Xia et al.
Summary: This study presents a green method for constructing multi-functional epoxy resins using environmentally friendly techniques. The modified epoxy resins showed improved flame retardancy, heat release rate, thermal conductivity, and mechanical properties.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Polymer Science
Lin-Lin Zhou et al.
Summary: There is a need to enhance the fire safety of silicone foam (SiF) in aircraft and high-speed trains. A novel NiTi-layered double hydroxide nanosheets (NiTi-LDH) was prepared as an effective flame-retardant and smoke-suppressor for SiF. The results showed that NiTi-LDH improved the fire resistance of SiF and greatly inhibited smoke release. The catalytic actions of NiTi-LDH in suppressing smoke and flame retardancy were observed in both condensed and gaseous phases.
POLYMER DEGRADATION AND STABILITY
(2022)
Article
Nanoscience & Nanotechnology
Lian Yin et al.
Summary: In this study, a new BN-PDA-MXene nanohybrid was developed with a stable column-to-beam architecture to improve the thermal stability and flame-retardant performance of thermosetting epoxy resin (EP). The nanohybrid effectively reduced the fire hazard and suppressed smoke production.
ACS APPLIED NANO MATERIALS
(2022)
Review
Chemistry, Physical
Longbo Jiang et al.
Summary: MXenes are a class of two-dimensional inorganic compounds composed of transition metal carbides, nitrides, or carbonitrides, with properties that can be regulated by external strain and number of layers. SFL-MXenes exhibit superior properties such as low ion diffusion barrier and high specific surface area. Fabrication methods for SFL-MXenes include both top-down and bottom-up strategies, with applications spanning various fields.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Engineering, Multidisciplinary
Hafezeh Nabipour et al.
Summary: Organic-inorganic hybrid flame retardant technology can simultaneously improve the flame retardancy, smoke suppression, and mechanical properties of polymers. The novel flame retardant IR-MOF-3-Mel significantly reduces the fire risk of epoxy resin by forming a high thermal resistance char layer, as evidenced by improved LOI, UL-94 classifications, reduced heat release rate, and enhanced mechanical properties.
COMPOSITES PART B-ENGINEERING
(2021)
Article
Chemistry, Multidisciplinary
Minghui Fang et al.
Summary: A novel flame retardant containing phosphorus, nitrogen, and silicon was successfully synthesized and blended with epoxy resin to form a flame-retardant composite material with excellent thermal stability and flame retardancy. The composite material showed promising performance in industrial applications, demonstrating improved fire safety and reduced heat release compared to neat epoxy resin.
Review
Polymer Science
Wei Cai et al.
Summary: This review discusses the application of two-dimensional nanomaterials in enhancing the fire safety of polymers and explores the flame retardant mechanism and functionalization methods of different layered nanomaterials to address the fire hazards of polymer materials.
CHINESE JOURNAL OF POLYMER SCIENCE
(2021)
Review
Engineering, Multidisciplinary
Kaili Gong et al.
Summary: MXenes, as a rising star in the 2D material family, exhibit charming physical and chemical properties due to their unique graphene-like structures and abundant functional groups. They show advantages in combining with polymer matrices and have been widely applied in various fields like electrical, thermal, and mechanical. MXenes play a vital role in developing high-performance composite materials and have considerable prospects in the future.
COMPOSITES PART B-ENGINEERING
(2021)
Article
Chemistry, Physical
Pin Hao et al.
Summary: The translation highlights the importance of preparing high activity electrocatalysts with good stability using NiCoOx solid solution hybrids. These hybrids have a hierarchical structure and high porosity, providing more active sites and facilitating ion permeation for improved catalytic activities. The synergy between (Ni, Co)O and (Ni, Co)(3)O-4 contributes to favorable reaction kinetics and enhanced electrical conductivity, leading to optimal catalytic performances.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Materials Science, Composites
Ying Pan et al.
POLYMER COMPOSITES
(2020)
Article
Chemistry, Multidisciplinary
Xinding Lv et al.
ADVANCED FUNCTIONAL MATERIALS
(2020)
Article
Chemistry, Physical
Kaili Gong et al.
APPLIED SURFACE SCIENCE
(2020)
Review
Chemistry, Physical
Yanyue Liu et al.
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Engineering, Multidisciplinary
Jing Zhang et al.
COMPOSITES PART B-ENGINEERING
(2020)
Review
Chemistry, Physical
Quanyi Liu et al.
Article
Engineering, Environmental
Yijiao Xue et al.
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Engineering, Multidisciplinary
Chuan Liu et al.
COMPOSITES PART B-ENGINEERING
(2020)
Article
Chemistry, Multidisciplinary
Maoyong Zhi et al.
Review
Engineering, Multidisciplinary
Xin Wang et al.
COMPOSITES PART B-ENGINEERING
(2019)
Article
Nanoscience & Nanotechnology
Yun Shu et al.
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Engineering, Environmental
Yuezhan Feng et al.
JOURNAL OF HAZARDOUS MATERIALS
(2018)
Article
Chemistry, Analytical
Dan Shen et al.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2017)
Article
Engineering, Environmental
Keqing Zhou et al.
JOURNAL OF HAZARDOUS MATERIALS
(2017)
Article
Chemistry, Physical
Mohamed Alhabeb et al.
CHEMISTRY OF MATERIALS
(2017)
Article
Engineering, Environmental
Hongyan Xie et al.
CHEMICAL ENGINEERING JOURNAL
(2017)
Article
Multidisciplinary Sciences
Michael Ghidiu et al.
