4.7 Article

The effects of temperature on shallow borehole NMR measurements in permafrost

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COLD REGIONS SCIENCE AND TECHNOLOGY
卷 211, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.coldregions.2023.103850

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Nuclear magnetic resonance; Unfrozen water; Temperature dependence; Permafrost

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High fidelity observations of water in permafrost are important for understanding soil moisture behavior and its impact on surface energy balance. Temperature-specific calibration of borehole NMR measurements is necessary for accurate results. Failure to compensate for temperature can result in significant bias in reported water content values, especially in conditions with steep temperature gradients.
High fidelity observations of the amount and state of water within permafrost help constrain the seasonal behavior of soil moisture and the effects of soil moisture on the surface energy balance. This work emphasizes the necessity for temperature-specific calibrations of low-frequency borehole NMR measurements. Constraining the effects of temperature on NMR signatures will allow for more reliable NMR inspection of hydrogeochemical parameters in permafrost ecosystems. We find that calibration at typical laboratory temperatures (20 degrees C) and subsequent measurement at typical permafrost active layer temperatures (similar to 0 degrees C) can result in an 18% bias in reported NMR water content values, and therefore temperature compensation is required under most scenarios. This is particularly important for active layer conditions that may include steep vertical temperature gradients. Similarly, seasonal time-lapse measurements of permafrost active layer may encounter substantial soil temperature variations which would also require temperature compensation on the observed NMR water content estimate.

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