4.7 Article

Reversible redox modulation of a lanthanide emissive molecular film

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CHEMICAL COMMUNICATIONS
卷 51, 期 30, 页码 6515-6517

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01097g

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  1. European Research Council under the European Union's seventh Framework Programme [267426]

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Herein we demonstrate redox switchable emission from a sensitised, europium-ferrocene containing, molecular film assembled by a novel nitrene-based strategy. Electrochemical modulation of europium emission upon switching the ferrocene moiety's redox state is ascribed to the reversible generation of a quenching ferrocenium species.

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