期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 38, 页码 8161-8164出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01973g
关键词
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资金
- University of Otago
- NZ Ministry of Business, Innovation and Employment Science Investment Fund [UOOX1206]
- Scientific Research at King Saud University [RGP-VPP-236]
- Marsden Fund [UOO1124]
- University of Otago (Division of Sciences Research Grant)
A 2,2'-bipyridine-appended ferrocene rotor, 1,1'-di(5-yl-ethynyl-2,2'-bipyridine)ferrocene, can be switched from a folded/stacked (syn) conformation to an extended/unstacked (anti) conformation by the addition of [Cu(CH3CN)(4)](PF6) and 6,6'-dimesityl-2,2'-bipyridine. This extension and contraction process was completely reversible and could be triggered either chemically or electrochemically.
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