期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 54, 页码 10937-10940出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03298a
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资金
- MINECO of Spain [CTQ2010-14796/BQU, CTQ2013-40591-P]
- Gobierno del Principado de Asturias [GRUPIN14-006]
- COST action [SIPs-CM1302]
- MINECO
- European Social Fund
The ruthenium-catalysed isomerisation of allylic alcohols was coupled, for the first time, with asymmetric bioamination in a one-pot process in an aqueous medium. In the cases involving prochiral ketones, the omega-TA exhibited excellent enantioselectivity, identical to that observed in the single step. As a result, amines were obtained from allylic alcohols with high overall yields and excellent enantiomeric excesses.
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