Visible Light and Triselenium Dicyanide (TSD): New Horizons in the Synthesis of Organic Selenocyanates

Article Neurosciences

Involvement of the serotonergic system in the antidepressant-like effect of 1-(phenylselanyl)-2-(p-tolyl)indolizine in mice

Marcia Juciele da Rocha et al.

Summary: The compound MeSeI has shown antidepressant-like effects and may be considered as a potential treatment for depression.

PSYCHOPHARMACOLOGY (2023)

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Article Chemistry, Physical

Visible Light-Triggered Radical Annulation of ortho-Thioaryl Ynones: A General Approach to Prepare 3-Sulfenylthiochromones

Ricardo H. Bartz et al.

Summary: A visible light-mediated protocol for the construction of 3-sulfenylthiochromenones was developed using a radical annulation of ortho-thioaryl ynones. The reaction proceeds through a sulfur-centered radical generated by light excitation of an intramolecular electron donor-acceptor complex (EDA complex). Twenty-one compounds were synthesized in yields ranging from 28% to 98%, with sixteen of them unprecedented. The reactions were conducted under open-air conditions without the need for metal catalysts, oxidant species, or heating, providing a mild and environmentally friendly approach to access valuable compounds.

CHEMCATCHEM (2023)

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Article Biochemistry & Molecular Biology

Synthesis and antitumor activity of some cholesterol-based selenocyanate compounds

Yan-Min Huang et al.

Summary: The synthesis of selenium-containing compounds derived from cholesterol was carried out and the structures of the compounds were characterized. The cholesterol-3-selenocyanoate derivatives showed no significant inhibitory activity against tumor cell lines. However, the B-norcholesterol selenocyanate derivatives displayed good inhibitory activity against tumor cell proliferation.

STEROIDS (2023)

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Article Chemistry, Applied

Synthesis of Isoquinolylselenocyanates and Quinolylselenocyanates via Electrophilic Selenocyanogen Cyclization Induced by Pseudohalogen (SeCN)2 Generated in situ

Jia Wang et al.

Summary: A strategy for the synthesis of isoquinolylselenocyanates and quinolylselenocyanates through electrophilic selenocyanogen cyclization has been developed, with the sequential process induced directly by generated in situ pseudohalogen (SeCN)2. The obtained selenocyanates allowed functional group diversification, potentially serving as valuable intermediates for compounds.

ADVANCED SYNTHESIS & CATALYSIS (2022)

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Review Chemistry, Multidisciplinary

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

Amy Y. Chan et al.

Summary: The merger of photoredox catalysis with transition metal catalysis, known as metallaphotoredox catalysis, has become an important part of synthetic methodology. It combines the bond formation capability of transition metal catalysis with the utility of photoinduced electron and energy transfer processes. Photocatalytic substrate activation allows the involvement of simple starting materials in metal-mediated bond-forming processes, while electron or energy transfer with organometallic intermediates provides a complementary activation mode to traditional catalytic platforms.

CHEMICAL REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Photoredox-Catalyzed C-H Functionalization Reactions

Natalie Holmberg-Douglas et al.

Summary: The fields of C-H functionalization and photoredox catalysis have gained significant interest and utility in various scientific disciplines. This review focuses on the use of photoredox catalysis in C-H functionalization reactions, highlighting both inorganic/organometallic and organic-based photoredox catalytic systems. The subdivision by reaction class (sp(2) or sp(3) C-H functionalization) provides perspective and tactical strategies for synthetic applications.

CHEMICAL REVIEWS (2022)

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Article Biochemistry & Molecular Biology

Antidepressant-Like Effect of a Selenoindolizine in Mice: In Vivo and In Silico Evidence for the Involvement of the Serotonergic 5-HT2A/C Receptors

Cleisson Schossler Garcia et al.

Summary: The study demonstrates that the selenium compound SeI has antidepressant-like effects by modulating the serotonergic system and has low toxicity potential in mice, suggesting it could be included in new treatment approaches for MDD.

ACS CHEMICAL NEUROSCIENCE (2022)

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Article Chemistry, Multidisciplinary

UVA Light-promoted Catalyst-free Cyclization of Vinyl Selenides: Green and Efficient Synthesis of C3-Unsubstituted 2-Selanyl Benzochalcogenophenes

Gelson Perin et al.

Summary: A metal- and catalyst-free photo-promoted cyclization method using UVA irradiation was developed to synthesize new C3-unsubstituted 2-selanyl benzochalcogenophenes, which can be easily functionalized under natural sunlight irradiation. The solvent used in the reaction can be reused multiple times.

CHEMISTRY-AN ASIAN JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Visible light-promoted synthesis of 2-aryl-(3-organoselanyl)thieno[2,3-b]pyridines

Ricardo Hellwig Bartz et al.

Summary: A simple and environment-friendly protocol was described for the synthesis of 2-aryl-(3-organoselanyl)thieno[2,3-b]pyridines, using diorganyl diselenides as selenium source and visible light-promoted selenocyclization reaction.

GREEN CHEMISTRY LETTERS AND REVIEWS (2022)

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Article Chemistry, Organic

Visible-Light-Mediated Photocatalytic Synthesis of 2-Substituted Oxazole-5-carbaldehydes Promoted by Benzeneseleninic Acid

Laura Abenante et al.

Summary: Benzeneseleninic acid was successfully used as a mild and efficient catalyst for the synthesis of a valuable class of compounds, 2-substituted oxazole-5-carbaldehydes, under visible light irradiation. The reaction proceeded smoothly at room temperature within just one hour, and no metal catalysts or strong oxidants were required.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Life cycle sustainability assessment as a metrics towards SDGs 2030

Jana Gerta Backes et al.

Summary: Sustainability has gained increasing importance to the public. The Sustainable Development Goals (SDGs) and the Life Cycle Sustainability Assessment (LCSA) are well-known international targets and assessment approaches for a more sustainable future. While there is a gap in the consensus of combining LCSA indicators and SDGs, a clear direction and recommendations have been provided for some SDGs.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2022)

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Review Chemistry, Organic

Organic Selenocyanates: Rapid Advancements and Applicationsin the Field of Organic Chemistry

Pran Gopal Karmaker et al.

Summary: The incorporation of the cyanato-chalcogen group has attracted the interest of researchers in modern organic synthetic chemistry. However, the development of methodologies for selenocyanation is lagging behind compared to OCN and SCN chemistry due to the scarcity of SeCN transfer reagents and synthetic approaches. In recent years, new reagents and techniques have been introduced that allow the uncomplicated creation of the selenocyanato group under gentle reaction conditions, which was seemingly unimaginable.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2022)

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Article Chemistry, Organic

77Se and 13C NMR Characterization of Selenium Cyanides

Joao Marcos Anghinoni et al.

Summary: In this study, a magnetic resonance spectroscopy characterization was performed to investigate selenium cyanide compounds, including Se(CN)2, Se-2(CN)2, and Se-3(CN)2. The data of these compounds at room temperature were obtained using selenium-77 and carbon-13 nuclides. This study is of significance as it provides the first structural characterization of Se-3(CN)2 and addresses the limitations in previous analyses of Se(CN)2 and Se-2(CN)2, which were conducted at low temperatures.

MOLBANK (2022)

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Article Biochemistry & Molecular Biology

Unveiling a New Selenocyanate as a Multitarget Candidate with Anticancer, Antileishmanial and Antibacterial Potential

Sandra Ramos-Inza et al.

Summary: In this study, a series of selenium-containing compounds were designed and synthesized, and their antiproliferative, antileishmanial, and antibacterial activities were evaluated in vitro. Some of these compounds showed promising therapeutic potential against multiple pathologies, making them attractive candidates for drug development.

MOLECULES (2022)

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Article Biochemistry & Molecular Biology

Synthesis of estrone selenocyanate Compounds, anti-tumor activity evaluation and Structure-activity relationship analysis

Yanmin Huang et al.

Summary: Introducing different functional groups into steroids can alter their biological activities. The study found that introducing selenocyano groups into estrone significantly enhanced its ability to inhibit tumor cell proliferation.

BIOORGANIC & MEDICINAL CHEMISTRY (2022)

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Article Chemistry, Organic

Solvent and catalyst-free synthesis of imidazo[1,2-a]pyridines by grindstone chemistry

Kumar Godugu et al.

Summary: This study presents a solvent and catalyst-free method for the synthesis of imidazo[1,2-a]pyridines, which is green, economical, and environmentally friendly. The method has a wide substrate scope, short reaction times, and eliminates the need for chromatographic purification.

JOURNAL OF HETEROCYCLIC CHEMISTRY (2021)

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Article Chemistry, Applied

Catalyst and Additive-Free Selective Ring-Opening Selenocyanation of Heterocycles with Elemental Selenium and TMSCN

Li-Guo Lu et al.

Summary: A catalyst and additive-free strategy for selective ring-opening selenocyanation of saturated heterocycles has been developed, yielding a series of aliphatic selenocyanates and selenaheterocycles using elemental selenium and TMSCN. In the case of unprotected unstrained N-heterocycles, the reactions produce ammonium selenonitriles which are proven to be efficient selenonitrile reagents.

ADVANCED SYNTHESIS & CATALYSIS (2021)

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Article Chemistry, Organic

Selenocyanation of Aryl and Styryl Methyl Ketones in the Presence of Selenium Dioxide and Malononitrile: An Approach for the Synthesis of α-Carbonyl Selenocyanates

Ibakyntiew D. Marpna et al.

Summary: A convenient method using selenium dioxide as the selenating agent has been developed for the synthesis of alpha-carbonyl selenocyanates from aryl methyl ketones/styryl methyl ketones under simple reaction conditions. This method offers notable advantages in terms of accessibility and affordability of the starting materials when compared to traditional methods. The interaction of aryl methyl ketones/styryl methyl ketones with selenium dioxide and malononitrile results in the formation of a series of alpha-carbonyl selenocyanates in moderate to good yields.

JOURNAL OF ORGANIC CHEMISTRY (2021)

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Review Chemistry, Medicinal

Small molecule selenium-containing compounds: Recent development and therapeutic applications

Hongyan Chuai et al.

Summary: This paper reviews the research progress and therapeutic applications of Se-containing compounds, selecting more than 110 Se-containing compounds with potent activities as representatives, aiming to provide a basis for further study of new promising Se-containing compounds.

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY (2021)

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Article Chemistry, Organic

Transition-Metal-Free HFIP-Mediated Organo Chalcogenylation of Arenes/Indoles with Thio-/Selenocyanates

Pratibha Kalaramna et al.

Summary: A novel protocol for the synthesis of diaryl thio-/selenoethers has been developed using HFIP promoted C-H activation, yielding good to excellent yields without the need for transition metal catalysts. The reaction tolerates a wide range of functional groups, allowing for the synthesis of diversely decorated chalcogenides. The proposed mechanism involves the activation of C-H bonds through hydrogen bonding.

JOURNAL OF ORGANIC CHEMISTRY (2021)

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Article Multidisciplinary Sciences

Inhibition mechanism of SARS-CoV-2 main protease by ebselen and its derivatives

Kangsa Amporndanai et al.

Summary: The study demonstrates that ebselen and its derivatives can effectively inhibit the SARS-CoV-2 main protease with potent antiviral activity. Further analysis reveals that the derivatives show stronger inhibition and ability to rescue infected cells compared to ebselen. The crystallographic structures also confirm the formation of enzyme-bound organoselenium covalent adducts through hydrolysis mechanism, suggesting broader therapeutic applications against SARS-CoV-2 and other zoonotic beta-corona viruses.

NATURE COMMUNICATIONS (2021)

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Editorial Material Chemistry, Multidisciplinary

The Power of the United Nations Sustainable Development Goals in Sustainable Chemistry and Engineering Research

Paul Anastas et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Review Chemistry, Multidisciplinary

Oxidase reactions in photoredox catalysis

Nicholas L. Reed et al.

Summary: The nature of the terminal oxidant in oxidation reactions plays a crucial role in determining the mechanism, efficiency, and practicality of a synthetic protocol. Photoredox catalysis has seen success in oxygenase-type reactions, while progress in photocatalytic oxidase reactions has been slower. This review highlights key classes of terminal oxidants used in photoredox oxidase transformations and their mechanistic features and benefits.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Visible-light-induced oxidative coupling of vinylarenes with diselenides leading to α-aryl and α-alkyl selenomethyl ketones

Gong-Qing Liu et al.

Summary: A novel reaction system has been developed for the oxidative coupling of diselenides with vinylarenes under visible light irradiation, providing a range of alpha-aryl and alpha-alkyl selenomethyl ketones with high yields and excellent compatibility with various functional groups. The use of a green solvent, air as an oxidant, and natural sunlight as a sustainable energy source sets this protocol apart from previous methods, making it an attractive option for the synthesis of medicinal and agrochemical compounds.

GREEN CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Education in green chemistry and in sustainable chemistry: perspectives towards sustainability

Vania G. Zuin et al.

Summary: Green chemistry education and sustainable chemistry education have gained increasing attention in recent years, but there are gaps in understanding their historical roots, differences, and similarities, as well as integrating this knowledge into curricula. Further efforts are needed to mainstream these educational concepts into chemistry and other education curricula, and to establish new partnerships at national, regional, and global levels.

GREEN CHEMISTRY (2021)

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Review Chemistry, Inorganic & Nuclear

Recent progress in the development of transition-metal based photoredox catalysts

Felix Glaser et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Environmental Sciences

Is Green Chemistry a feasible tool for the implementation of a circular economy?

Natalia Loste et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020)

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Article Chemistry, Organic

Oxidative umpolung selenocyanation of ketones and arenes: An efficient protocol to the synthesis of selenocyanates

Jianguo Cui et al.

TETRAHEDRON (2020)

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Article Chemistry, Organic

Photocatalytic Synthesis of 3-Sulfanyl- and 1,3-Bis(sulfanyl)indolizines Mediated by Visible Light

Filipe Penteado et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Environmental Sciences

Implementation of green chemistry principles in circular economy system towards sustainable development goals: Challenges and perspectives

Tse-Lun Chen et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2020)

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Article Multidisciplinary Sciences

Structure of Mpro from SARS-CoV-2 and discovery of its inhibitors

Zhenming Jin et al.

NATURE (2020)

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Article Chemistry, Multidisciplinary

An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst- and oxidant-free conditions

Dongdong He et al.

GREEN CHEMISTRY (2020)

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Editorial Material Chemistry, Multidisciplinary

Circular chemistry to enable a circular economy

Tom Keijer et al.

NATURE CHEMISTRY (2019)

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Article Neurosciences

Lipopolysaccharide-induced depressive-like, anxiogenic-like and hyperalgesic behavior is attenuated by acute administration of α-(phenylselanyl) acetophenone in mice

Fernanda Severo Sabedra Sousa et al.

NEUROPHARMACOLOGY (2019)

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Article Chemistry, Organic

C4-Selective Synthesis of Vinyl Thiocyanates and Selenocyanates Through 3,4-Dihalo-2(5H)-furanones

Han-Qing Wu et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Pronounced activity of aromatic selenocyanates against multidrug resistant ESKAPE bacteria

Muhammad Jawad Nasim et al.

NEW JOURNAL OF CHEMISTRY (2019)

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Review Chemistry, Multidisciplinary

Illuminating Photoredox Catalysis

Rory C. McAtee et al.

TRENDS IN CHEMISTRY (2019)

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Review Chemistry, Multidisciplinary

Exploring green and sustainable chemistry in the context of sustainability transition: The role of visions and policy

Pasquale Marcello Falcone et al.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2019)

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Article Neurosciences

alpha- (phenylselanyl) acetophenone mitigates reserpine-induced pain-depression dyad: Behavioral, biochemical and molecular docking evidences

Fernanda Severo Sabedra Sousa et al.

BRAIN RESEARCH BULLETIN (2018)

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Review Chemistry, Multidisciplinary

Photoredox Catalysis for Building C-C Bonds from C(sp(2))-H Bonds

Chang-Sheng Wang et al.

CHEMICAL REVIEWS (2018)

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Review Biochemistry & Molecular Biology

Selenocysteine in mammalian thioredoxin reductase and application of ebselen as a therapeutic

Xiaoyuan Ren et al.

FREE RADICAL BIOLOGY AND MEDICINE (2018)

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Article Neurosciences

Selanylimidazopyridine Prevents Lipopolysaccharide-Induced Depressive-Like Behavior in Mice by Targeting Neurotrophins and Inflammatory/Oxidative Mediators

Micaela Domingues et al.

FRONTIERS IN NEUROSCIENCE (2018)

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Article Biochemistry & Molecular Biology

alpha-(phenylselanyl) acetophenone abolishes acute restraint stress induced-comorbid pain, depression and anxiety-related behaviors in mice

Fernanda Severo Sabedra Sousa et al.

NEUROCHEMISTRY INTERNATIONAL (2018)

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Review Medicine, General & Internal

First line defence antioxidants-superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPX): Their fundamental role in the entire antioxidant defence grid

O. M. Ighodaro et al.

ALEXANDRIA JOURNAL OF MEDICINE (2018)

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Article Chemistry, Multidisciplinary

The UN Sustainable Development Goals: How can sustainable chemistry contribute? A view from the chemical industry

Sean Axon et al.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2018)

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Article Clinical Neurology

Antidepressant-like effect of a new selenium-containing compound is accompanied by a reduction of neuroinflammation and oxidative stress in lipopolysaccharide-challenged mice

Angela M. Casaril et al.

JOURNAL OF PSYCHOPHARMACOLOGY (2017)

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Review Biochemistry & Molecular Biology

Organoselenium compounds as mimics of selenoproteins and thiol modifier agents

Nilda V. Barbosa et al.

METALLOMICS (2017)

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Article Chemistry, Organic

A novel metal-free method for the selenocyanation of aromatic ketones to afford α-carbonyl selenocyanates

Kai Sun et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2017)

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Article Chemistry, Organic

Transition-Metal-Free Iodine Catalyzed Selenocayanation of Styrenyl Bromides and an Easy Access to Benzoselenophenes via Intermediacy of Styrenyl Selenocyanate

Pintu Maity et al.

ORGANIC LETTERS (2017)

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Article Pharmacology & Pharmacy

Contribution of dopaminergic and noradrenergic systems in the antinociceptive effect of α-(phenylalanyl) acetophenone

Fernanda S. S. Sousa et al.

PHARMACOLOGICAL REPORTS (2017)

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Article Chemistry, Organic

Easy and efficient selenocyanation of imidazoheterocycles using triselenodicyanide

Sebastien Redon et al.

TETRAHEDRON LETTERS (2017)

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Review Chemistry, Multidisciplinary

The merger of transition metal and photocatalysis

Jack Twilton et al.

NATURE REVIEWS CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

The concept of sustainable chemistry: Key drivers for the transition towards sustainable development

Christopher Blum et al.

SUSTAINABLE CHEMISTRY AND PHARMACY (2017)

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Article Chemistry, Multidisciplinary

Multifunctional Antioxidants: Regenerable Radical-Trapping and Hydroperoxide-Decomposing Ebselenols

Shailesh Kumar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Review Chemistry, Multidisciplinary

Cooperative photoredox catalysis

Xianjun Lang et al.

CHEMICAL SOCIETY REVIEWS (2016)

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Article Multidisciplinary Sciences

Ultrasound-promoted two-step synthesis of 3-arylselenylindoles and 3-arylthioindoles as novel combretastatin A-4 analogues

Zhiyong Wen et al.

SCIENTIFIC REPORTS (2016)

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Review Chemistry, Multidisciplinary

Exploring Green Chemistry, Sustainable Chemistry and innovative business models such as Chemical Leasing in the context of international policy discussions

Petra Schwager et al.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2016)

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Article Chemistry, Medicinal

New Organochalcogen Multitarget Drug: Synthesis and Antioxidant and Antitumoral Activities of Chalcogenozidovudine Derivatives

Diego de Souza et al.

JOURNAL OF MEDICINAL CHEMISTRY (2015)

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Article Medicine, Legal

Evaluation of the toxicity of α-(phenylselanyl) acetophenone in mice

Angela M. Casaril et al.

REGULATORY TOXICOLOGY AND PHARMACOLOGY (2015)

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Editorial Material Multidisciplinary Sciences

Sustainable development agenda: 2030

William Colglazier

SCIENCE (2015)

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Article Chemistry, Organic

Efficient synthesis of novel chalcogen-containing derivatives of DNA nucleobases

Guoxiong Hua et al.

TETRAHEDRON (2015)

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Review Biochemistry & Molecular Biology

Organochalcogen peroxidase mimetics as potential drugs: a long story of a promise still unfulfilled

Laura Orian et al.

FREE RADICAL BIOLOGY AND MEDICINE (2014)

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Article Biochemistry & Molecular Biology

Ebselen, a promising antioxidant drug: mechanisms of action and targets of biological pathways

Gajendra Kumar Azad et al.

MOLECULAR BIOLOGY REPORTS (2014)

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Review Chemistry, Multidisciplinary

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

Christopher K. Prier et al.

CHEMICAL REVIEWS (2013)

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Article Behavioral Sciences

In vitro antioxidant activity and in vivo antidepressant-like effect of α-(phenylselanyl) acetophenone in mice

Mariana Freire Barbieri Gerzson et al.

PHARMACOLOGY BIOCHEMISTRY AND BEHAVIOR (2012)

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Review Chemistry, Multidisciplinary

Photochemical Reactions as Key Steps in Natural Product Synthesis

Thorsten Bach et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Review Chemistry, Multidisciplinary

Catalytic Application of Selenium and Tellurium Compounds as Glutathione Peroxidase Enzyme Mimetics

Eduardo E. Alberto et al.

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY (2010)

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Article Chemistry, Organic

Triselenium Dicyanide (TSD) as a New Cyanation Reagent: Synthesis of Cyano Pterins and Quinoxalines Along with Library of Cyano N-Heterocyclic Compounds

Shyamaprosad Goswami et al.

SYNTHETIC COMMUNICATIONS (2009)

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Article Chemistry, Physical

Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections

Jeng-Da Chai et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2008)

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Article Chemistry, Inorganic & Nuclear

Synthesis of 4-aryl-2-imino-2H-selenazolines by a reaction of α-(selenocyanato)acetophenones with anilines

Anja Bodtke et al.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS (2007)

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Article Chemistry, Organic

Anionic activation of the Wittig reaction using a solid-liquid phase transfer: examination of the medium-, temperature-, base- and phase-transfer catalyst effects

Younes Moussaoui et al.

ARKIVOC (2006)

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Review Chemistry, Multidisciplinary

Quantum mechanical continuum solvation models

J Tomasi et al.

CHEMICAL REVIEWS (2005)

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Article Biochemistry & Molecular Biology

A facile synthesis of substituted benzyl selenocyanates

LA Jacob et al.

MOLECULES (2004)

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Review Chemistry, Multidisciplinary

Organoselenium and organotellurium compounds: Toxicology and pharmacology

CW Nogueira et al.

CHEMICAL REVIEWS (2004)

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Article Chemistry, Organic

Triselenium dicyanide from malononitrile and selenium dioxide. One-pot synthesis of selenocyanates

AV Kachanov et al.

TETRAHEDRON LETTERS (2004)

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Article Chemistry, Organic

Electrochemical preparation of α,α'-dicarbonylselenides

MD Otero et al.

TETRAHEDRON (2004)

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Article Multidisciplinary Sciences

Three-dimensional structure of a mammalian thioredoxin reductase: Implications for mechanism and evolution of a selenocysteine-dependent enzyme

T Sandalova et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2001)

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Review Chemistry, Multidisciplinary

Chemistry of biologically important synthetic organoselenium compounds

G Mugesh et al.

CHEMICAL REVIEWS (2001)

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Visible Light and Triselenium Dicyanide (TSD): New Horizons in the Synthesis of Organic Selenocyanates

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