☆ 4.6 Article

Hexaguanidino-Triptycenes and Triphenylenes: Electronic Coupling in Molecules Containing Three Redox-Active o-Diguanidinobenzene Units Connected either Directly or Interacting Through Homoconjugation

CHEMISTRY-A EUROPEAN JOURNAL (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Quantitative Electromerism of a Well-defined Mononuclear Copper Complex Through Reversible Intramolecular Metal-Ligand Electron Transfer

Johanna Osterbrink et al.

Summary: Copper amine oxidases are enzymes that exhibit a mononuclear copper complex and a 2,4,5-trihydroxyphenylalanine quinone cofactor. They regulate their activity through a temperature-dependent electron transfer equilibrium. The study reports the first mononuclear copper complex with reversible electromerism between a Cu-II electromer and a Cu-I electromer. Solvent has a significant effect on this electromerism.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

添加到收藏夹

Review Materials Science, Multidisciplinary

Homoconjugation effects in triptycene based organic optoelectronic materials

Jai-Ram Mistry et al.

Summary: Molecular size and shape greatly influence the electronic structure and photophysical properties of organic optoelectronic molecules. Small structural changes can fine tune the functionalities of these molecules, while enforcing homoconjugation can have even more significant effects. Triptycene, as an archetypical homoconjugated molecule, provides insights into optimizing functional molecular properties. This review highlights the enhanced optoelectronic properties of triptycene-based molecules and discusses their performance and future potential in devices.

MATERIALS ADVANCES (2023)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Complexes of late transition metals of the 3d row based on functionalized o-iminobenzoquinone type ligands: Interrelation of molecular and electronic structure, magnetic behaviour

Kira I. Pashanova et al.

Summary: This review focuses on the coordination compounds of late transition metals based on sterically hindered functionalized o-iminobenzoquinone type ligands. It discusses the relationship between structural modifications and magnetic behavior, as well as the effect of molecular structure transformations on the oxidation state, spin state multiplicity, and redox state of the metal center and organic ligands.

COORDINATION CHEMISTRY REVIEWS (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Solvent-Induced Redox Isomerism of Cobalt Complexes with Redox-Active Bisguanidine Ligands

Lukas Lohmeyer et al.

Summary: This study investigates the redox properties of cobalt complexes with redox-active bisguanidine ligands, and fine-tuning of the electronic structure is achieved through systematic modifications at the ligand units. The first observation of redox isomerism for cobalt complexes with redox-active guanidine ligands is reported.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

Akinobu Nakada et al.

Summary: The hybridization of functional ligands with metal atoms is a central issue in the design of reactions and catalysts based on metal complexes. Recent studies have shown that redox-active/non-innocent ligands can play various roles, such as spectators, moderators, electron/H+/0/- suppliers/poolers, cooperators, or actors, in reactions. This review highlights stoichiometric or catalytic reactions driven by substituted ethylenes and dithiolenes, as well as six-membered ligands like catecholato, benezendithiolato, aminophenolato, and o-phenelyenediamine derivatives. The chemically, electrochemically, and photochemically induced lability of these ligands is expected to provide a rich platform for useful bond-activation and bond-formation processes.

COORDINATION CHEMISTRY REVIEWS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Versatile Redox-Active Organic Materials for Rechargeable Energy Storage

Giyun Kwon et al.

Summary: This article discusses the utilization and development of high-performance ROMs for battery systems. These ROMs are based on earth-abundant elements, exhibit structural diversity, and possess strong chemical tunability, making them suitable for future sustainable energy solutions.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stimulation of Redox-Induced Electron Transfer by Interligand Hydrogen Bonding in a Cobalt Complex with Redox-Active Guanidine Ligand

Lukas Lohmeyer et al.

Summary: Octahedrally coordinated cobalt(II) complexes with redox-active bisguanidine ligands and acac co-ligands were synthesized and their redox chemistry was analyzed in detail. The formation of hydrogen bonds between the N-H functions of the bisguanidine ligands and the acac co-ligands significantly influenced the redox chemistry, providing examples of metal-centered and ligand-centered oxidation pathways.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Switching from Metal- to Ligand-Based Oxidation in Cobalt Complexes with Redox-Active Bisguanidine Ligands

Lukas Lohmeyer et al.

Summary: The study shows that by replacing auxiliary ligands, the redox chemistry of the complex and its properties can be significantly altered. The control over the redox states and understanding the changes in magnetic and optical properties allow for rational applications in catalysis and materials science. Further analysis with quantum-chemical calculations helps in understanding the electronic structures and redox isomers.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Review Chemistry, Organic

Copper catalysis with redox-active ligands

Agnideep Das et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mercury 4.0: from visualization to analysis, design and prediction

Clare F. Macrae et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2020)

添加到收藏夹

Review Chemistry, Physical

Redox-Active Organic Compounds for Future Sustainable Energy Storage System

Sechan Lee et al.

ADVANCED ENERGY MATERIALS (2020)

添加到收藏夹

Article Chemistry, Organic

Homoconjugation and Intramolecular Charge Transfer in Extended Aromatic Triptycenes with Different π-Planes

Kevin Baumgaertner et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands

Jarl Ivar van der Vlugt

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Valence tautomerism in copper coordination chemistry

Hans-Joerg Himmel

INORGANICA CHIMICA ACTA (2018)

添加到收藏夹

Article Chemistry, Physical

Game of Frontier Orbitals: A View on the Rational Design of Novel Charge-Transfer Materials

Maxim V. Ivanov et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2018)

添加到收藏夹

Article Chemistry, Organic

Guanidines as Reagents in Proton-Coupled Electron-Transfer Reactions and Redox Catalysts

Hans-Joerg Himmel

SYNLETT (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Redox-Flow Batteries: From Metals to Organic Redox-Active Materials

Jan Winsberg et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Oxidation of Organic Molecules with a Redox-Active Guanidine Catalyst

Ute Wild et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Inter- and Intramolecular Electron Transfer in Copper Complexes: Electronic Entatic State with Redox-Active Guanidine Ligands

David F. Schrempp et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint

Jesus Ferrando-Soria et al.

COORDINATION CHEMISTRY REVIEWS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Stable Hexakis(guanidino)benzene: Realization of the Strongest Neutral Organic Four-Electron Donor

Benjamin Eberle et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper Complexes of New Redox-Active 4,5-Bisguanidino-Substituted Benzodioxole Ligands: Control of the Electronic Structure by Counter-Ligands, Solvent, and Temperature

David Fridolin Schrempp et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Valence Tautomeric Dinuclear Copper Tetrakisguanidine Complex

Sven Wiesner et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

The control of the electronic structure of dinuclear copper complexes of redox-active tetrakisguanidine ligands by the environment

Sven Wiesner et al.

DALTON TRANSACTIONS (2016)

添加到收藏夹

Review Chemistry, Physical

Metal-Promoted Coupling Reactions Implying Ligand-Based Redox Changes

Jeremy Jacquet et al.

CHEMCATCHEM (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors

Anthony L. Spek

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Trinuclear Complexes and Coordination Polymers of Redox-Active Guanidino-Functionalized Aromatic (GFA) Compounds with a Triphenylene Core

Anna Lebkuecher et al.

INORGANIC CHEMISTRY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Turbomole

Filipp Furche et al.

WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

Complexes with Nitrogen-Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications

Alma I. Olivos Suarez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Redox-active ligands in catalysis

Oana R. Luca et al.

CHEMICAL SOCIETY REVIEWS (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Guanidinyl-Functionalized Aromatic Compounds (GFAs) - Charge and Spin Density Studies as Starting Points for the Development of a New Class of Redox-active Ligands

Hans-Joerg Himmel

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enhanced rigid-bond restraints

Andrea Thorn et al.

ACTA CRYSTALLOGRAPHICA SECTION A (2012)

添加到收藏夹

Review Chemistry, Multidisciplinary

Organic Mixed-Valence Compounds: A Playground for Electrons and Holes

Alexander Heckmann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Review Chemistry, Multidisciplinary

Redox-Active Ligands in Catalysis

Vijayendran K. K. Praneeth et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Non-Innocent Ligands: New Opportunities in Iron Catalysis

Sebastien Blanchard et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2012)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Cooperative Catalysis with First-Row Late Transition Metals

Jarl Ivar van der Vlugt

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Charge Delocalization in Self-Assembled Mixed-Valence Aromatic Cation Radicals

Tushar S. Navale et al.

LANGMUIR (2012)

添加到收藏夹

Article Chemistry, Physical

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

Volodymyr Lyaskovskyy et al.

ACS CATALYSIS (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ligands that Store and Release Electrons during Catalysis

Wojciech I. Dzik et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Organic Mixed Valence

Jihane Hankache et al.

CHEMICAL REVIEWS (2011)

添加到收藏夹

Article Chemistry, Organic

Two-Step Synthesis of Hexaammonium Triptycene: An Air-Stable Building Block for Condensation Reactions to Extended Triptycene Derivatives

Michael Mastalerz et al.

JOURNAL OF ORGANIC CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

On the Electronic Structure of Ni-II Complexes That Feature Chelating Bisguanidine Ligands

Pascal Roquette et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Successive Ligand and Metal Oxidation: Redox Reactions Involving Binuclear CuI Complexes of Chelating Guanidine Ligands

Dimitri Emeljanenko et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2010)

添加到收藏夹

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates

Long Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Organic

X-ray Structural Characterization of Charge Delocalization onto the Three Equivalent Benzenoid Rings in Hexamethoxytriptycene Cation Radical

Vincent J. Chebny et al.

ORGANIC LETTERS (2009)

添加到收藏夹

Article Chemistry, Organic

1,2,4,5-Tetrakis(tetramethylguanidino)benzene: Synthesis and Properties of a New Molecular Electron Donor

Anastasia Peters et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2008)

添加到收藏夹

Review Multidisciplinary Sciences

Biologically inspired oxidation catalysis

Lawrence Que et al.

NATURE (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

A short history of SHELX

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2008)

添加到收藏夹

Article Chemistry, Physical

Nuclear second analytical derivative calculations using auxiliary basis set expansions

P Deglmann et al.

CHEMICAL PHYSICS LETTERS (2004)

添加到收藏夹

Article Chemistry, Physical

A new hybrid exchange-correlation functional using the Coulomb-attenuating method (CAM-B3LYP)

T Yanai et al.

CHEMICAL PHYSICS LETTERS (2004)

添加到收藏夹

Article Chemistry, Multidisciplinary

Single-crystal structure validation with the program PLATON

AL Spek

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2003)

添加到收藏夹

Review Chemistry, Multidisciplinary

Homoaromaticity

RV Williams

CHEMICAL REVIEWS (2001)

添加到收藏夹

Article Chemistry, Physical

Ab initio computations of effective exchange integrals for H-H, H-He-H and Mn2O2 complex:: comparison of broken-symmetry approaches

T Soda et al.

CHEMICAL PHYSICS LETTERS (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.