Applications of Carbon-Based Materials in Activated Peroxymonosulfate for the Degradation of Organic Pollutants: A Review

In recent years, water pollution has posed a serious threat to aquatic organisms and humans. Advanced oxidation processes (AOPs) based on activated peroxymonosulfate (PMS) show high oxidation, good selectivity, wide pH range and no secondary pollution in the removal of organic pollutants in water. Carbon-based materials are emerging green catalysts that can effectively activate persulfates to generate radical and non-radical active species to degrade organic pollutants. Compared with transition metal catalysts, carbon-based materials are widely used in SR-AOPs because of their low cost, non-toxicity, acid and alkali resistance, large specific surface area, and scalable surface charge, which can be used for selective control of specific water pollutants. This paper mainly presents several carbon-based materials used to activate PMS, including raw carbon materials and modified carbon materials (heteroatom-doped and metal-doped), analyzes and summarizes the mechanism of activating PMS by carbon-based catalysts, and discusses the influencing factors (temperature, pH, PMS concentration, catalyst concentration, inorganic anions, inorganic cations and dissolved oxygen) in the activation process. Finally, the future challenges and prospects of carbon-based materials in water pollution control are also presented.

Automated summary

Advanced oxidation processes (AOPs) based on activated peroxymonosulfate (PMS) are effective in removing organic pollutants from water due to their high oxidation ability, wide pH range, good selectivity, and absence of secondary pollution. Carbon-based materials, as green catalysts, can activate persulfates to degrade organic pollutants by generating radical and non-radical active species. Compared to transition metal catalysts, carbon-based materials have advantages such as low cost, non-toxicity, acid and alkali resistance, large specific surface area, and scalable surface charge, making them suitable for selective control of water pollutants.