The structure of Cu(II) complex with chelating fluorinated ligands was investigated using CW X-band electron paramagnetic resonance (EPR) spectroscopy and density functional theory (DFT) at temperatures of 298 K and 90 K. The spin-Hamiltonian and structural parameters were determined and compared with X-ray data, showing good similarity. In addition, the catalytic behavior of the Cu(II) complex during H2O2 decomposition in acetonitrile-aqueous solutions at 313 K was qualitatively studied using EPR and UV-visible spectroscopy.
Structure of Cu(II) complex with chelating fluorinated ligands were studied at 298 K and 90 K using CW X-band electron paramagnetic resonance (EPR) spectroscopy and density functional theory (DFT). Spin-Hamiltonian and structural parameters have been determined and the latter were compared with the X-ray data showing good similarity. A phase transition occurred at 360 K in solid crystalline sample was observed by EPR and discussed. Qualitative kinetic analysis of the catalytic behavior of Cu(II) complex upon H2O2 decomposition in acetonitrile-aqueous solutions at 313 K was studied using EPR and UV-visible spectroscopy.
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