Ultralong hydroxyapatite nanowires-based flow-through reactor with high loading of silver nanoparticles for fast continuous catalytic reduction of organic dyes and disinfection of wastewater

The noble metal nanoparticles (NPs) immobilized flow-through reactors have attracted significant attention for the continuous and efficient purification of wastewater contaminated with organic dyes and microorganisms without the need of subsequent recycling processes. However, achieving both high loading of noble metal NPs and high permeation flux concurrently has been a challenge for most reported flow-through reactors. In this study, inspired by the mussel bio-adhesion strategy, we have employed the tannic acid coating method and successfully synthesized Ag NPs-loaded ultralong hydroxyapatite (HAP) nanowires that exhibited an ultra-high loading amount (21.8 wt%). These nanowires were utilized as building blocks alongside chitosan (CS) to fabricate robust and highly porous flow-through reactors (Ag@HAP/CS) for continuous catalytic reduction of organic dyes and water disinfection. The Ag@HAP/CS reactor demonstrates excellent catalytic reduction efficiency (99.3 %) towards MEB at a high flux (2000 L m- 2 h-1) with an extremely low concentration of NaBH4 (MEB:NaBH4 = 1:1). This result is attributed to the high loading of Ag NPs, great structural stability in flowing water, and sufficient length along the flowing direction. The reactor also shows remarkable recyclability through water flushing. Ag@HAP/CS exhibits remarkable water disinfection performance against Escherichia coli and diverse bacteria in natural river water, achieving nearly 100 % disinfecting efficiency. This study provides new insights into the strategy of using nanomaterials as intermediate carriers of noble metal nanoparticles to fabricate 3D flow-through reactors, which enable fast and continuous purification of wastewater with ultra-high catalytic efficiency and antimicrobial performance.

Automated summary

Inspired by the mussel bio-adhesion strategy, this study successfully synthesized Ag NPs-loaded ultralong hydroxyapatite nanowires and used them in combination with chitosan to fabricate a flow-through reactor for wastewater purification and water disinfection. The reactor exhibited high catalytic reduction efficiency and antimicrobial performance, and could be recycled through water flushing.