期刊
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
卷 193, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cep.2023.109556
关键词
Natural rubber latex; Coagulation; Microbubbles; CO 2 utilization; Latex waste serum; Carbonic acid
This study presents an innovative approach that utilizes CO2 microbubbles as a process intensification technique in the production of natural rubber sheets. The use of CO2 microbubbles not only improves the quality and waste management issues associated with traditional methods, but also enhances the key properties of rubber products. Furthermore, this approach promotes sustainable processes by utilizing CO2 as a feedstock.
Traditionally, acids have been employed in the production of raw rubber sheets. Using concentrated acids to coagulate natural rubber latex has led to issues such as subpar product quality and the generation of a significant volume of acidic latex serum waste. In contrast, opting for weak acids results in increased production costs. To address these limitations, this research adopts an innovative approach that leverages CO2 microbubbles as a process intensification technique. CO2 was bubbling into a bubble column filled with fresh natural rubber latex and closely monitored the pH and coagulation percentage over time. The physical and mechanical properties of the solid rubber products were characterized, in comparison with the products gained from conventional techniques. The use of CO2 microbubbles yielded shorter processing times and reduced the generation of acidic waste serum. Notably, this approach also led to significant improvements in key properties such as initial Wallace plasticity (P0), plasticity retention index (PRI), nitrogen content, and biodegradability in soil of the rubber samples. Interestingly, the utilization of CO2 as a feedstock highlights its role in promoting a sustainable process. This innovative approach not only minimizes environmental impact but also results in the production of valueadded rubber products with enhanced properties.
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