4.4 Review

A Detailed Discourse on the Epistemology of Lithium-Sulfur Batteries

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/ceat.202300320

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Advancements in Li-S batteries; Energy storage devices; Lithium-sulfur battery; Mitigation of polysulfides; Polysulfide shuttling

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The architecture of lithium-sulfur batteries offers five times more charge capacity compared to lithium-ion batteries. This review highlights recent research findings on sulfur loading, electrolyte-to-sulfur ratio, and the polysulfide shuttling effect. Potential remedies for electrolyte stability issues are discussed, and future scopes for optimizing Li-S batteries are suggested, including pore structure optimization, designing sulfur confinement systems, and exploring innovative components for commercialization. The review also provides an overview of the history of Li-S batteries, summarizes recent research findings, evaluates future challenges and possible solutions, and outlines further steps towards advanced Li-S batteries with new-generation components.
The architecture of lithium-sulfur (Li-S) batteries can hold five times more charge capacity compared to Li-ion batteries. This review emphasizes the recent research findings on the desired loading of sulfur, the electrolyte-to-sulfur ratio, and a detailed view of the polysulfide shuttling effect. Problems with electrolyte stability are also discussed as well as the potential remedies they provided in various systems, as Li-S batteries have great potential to surmount these critical issues by understanding the mechanism. Future scopes of Li-S batteries can be progressively attained by optimizing the pore structure, designing highly conductive and strong sulfur confinement systems, and thereby pairing with anode materials to explore the possibility of innovative components for commercializing Li-S batteries. After an overview of the history behind Li-S batteries, this review summarizes the recent research findings on their crucial parameters and bottlenecks. Future challenges and possible solutions are evaluated and further steps towards new-generation Li-S batteries with advanced components are outlined. image

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