期刊
CHEMCATCHEM
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202300600
关键词
Molecularly doped metals; Catalyst cost; Green chemistry; Metal organic alloys; MORAL
MORALs, as active, stable and versatile catalysts, play a role in various reactions in the chemical industry. Despite their great potential, their use in catalysis is still limited. This study investigates practical aspects of using molecularly doped metals as heterogeneous catalysts.
Ranging from silver-entrapped dyes and gold-entrapped enzymes through palladium-entrapped graphene oxide, molecularly doped metals (or metal organic alloys, MORALs) are active, stable and uniquely versatile catalysts in a number of reactions of relevance to the chemical industry. Reactions successfully catalyzed by MORALs concern both industry's main sectors, producing bulk and fine chemicals. Though first reported in 2005, and clearly holding a great applicative potential, their use in catalysis is still surprisingly limited. This study investigates a number of practical aspects concerning molecularly doped metals as heterogeneous catalysts.
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