New double perovskite Cd2MgTeO6:Sm3+, Na+ tellurate phosphors with abnormal thermal quenching for applications in white and plant growth lighting

New Sm3+ doped Cd2MgTeO6 tellurate red-emitting phosphors with Na+ ions as charge compensation were obtained using a high-temperature solid-state approach at 1000 degrees C. During this study, the prepared phosphors were subjected to phase purity, particle morphology, luminescence characteristics, thermal stability, and Com-mission Internationale de L & PRIME; Eclairage (CIE) chromaticity. The critical quenching concentration of Sm3+ doped Cd2MgTeO6 phosphor was 2 mol%. According to Dexter's theory and the calculated Rc value (22.21 & ANGS;), the dipole-dipole interaction causes the phenomenon of concentration quenching. Particularly, the Cd2MgTeO6:2 mol%Sm3+, 2 mol%Na+ phosphor exhibited an evident red-light emission (647 nm) at & lambda;ex = 407 nm because of the 4G5/2 to 6H9/2 level transition of Sm3+. Its internal quantum efficiency (IQE) was 38.87%. It is worth noting that the Cd2MgTeO6:Sm3+, Na+ phosphor exhibited abnormal thermal quenching (ATQ) characteristics, and the luminous intensity of the Cd2MgTeO6:2 mol%Sm3+, 2 mol%Na+ increased by 7.20% at 480 K compared with the initial temperature. In addition, white LEDs and red LEDs were successfully manufactured with a 408 nm chip. The prepared red LED showed the emission spectrum similar to the absorption spectrum of Phytochrome Pr, which is expected to be applied in plant growth. The w-LED had a CCT (correlated color temperature) of 4790 K, color rendering index of 91, and color coordinates of (0.348, 0.335). Therefore, the Cd2MgTeO6:Sm3+, Na+ phosphor has demonstrated potential applications in w-LEDs and plant growth LEDs.

Automated summary

New red-emitting phosphors of Sm3+ doped Cd2MgTeO6 tellurate with Na+ ions as charge compensation were successfully synthesized. The prepared phosphors were characterized for their phase purity, particle morphology, luminescence characteristics, thermal stability, and CIE chromaticity. The optimal concentration of Sm3+ dopant in Cd2MgTeO6 phosphor was found to be 2 mol%. The Cd2MgTeO6:2 mol%Sm3+, 2 mol%Na+ phosphor exhibited strong red-light emission at 647 nm, which is suitable for applications in white LEDs and plant growth LEDs.