4.7 Article

Viscose nonwoven fabric with copper and its multifunctional properties

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CELLULOSE
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SPRINGER
DOI: 10.1007/s10570-023-05454-8

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Viscose nonwoven fabric; Copper; Magnetron sputtering; Bioactivity; Electrical conductivity; Comfort properties

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During the COVID-19 pandemic, the antimicrobial functionalization of textile structures with copper and its compounds has significantly increased. This study applied magnetron sputtering with copper to modify viscose needle-punched nonwoven fabric, which showed strong antimicrobial activity against Gram-positive Staphylococcus aureus and Gram-negative Klebsiella pneumoniae. However, it exhibited weak activity against herpes simplex virus type 1 (HSV-1) in the presence of other viruses.
The antimicrobial functionalization of textile structures with copper and its compounds carried out by various methods increased significantly during the SARS-CoV-2 pandemic. So far, in order to obtain antiviral properties the magnetron technique using copper was applied mainly to flat textile structures; polypropylene, polyester and cotton nonwovens, and polyester and cotton woven fabrics. In this study, magnetron sputtering with copper was applied to modify the spatial viscose needle-punched nonwoven fabric. We found that the spatial nonwoven structure made of regenerated cellulose fibers and one-side sputtered with copper has strong antimicrobial activity against Gram-positive Staphylococcus aureus and Gram-negative Klebsiella pneumoniae. In the case of herpes simplex virus type 1 (HSV-1) McKrae strain, vaccinia virus (VACV) WR strain, influenza A virus H1N1 (IFV) and mouse coronavirus (MHV) JHV strain used in the study, Cu modified nonwoven fabric has only weak activity against herpes simplex virus type 1 (HSV-1). It also has no significant toxicity compared to the control medium and pristine nonwoven fabric. The modified nonwoven fabric is characterized also by hydrophobic properties, high electrical conductivity, good air and water vapor permeability, and meets the requirements of breathing resistance for all protection classes (FFP1, FFP2 and FFP3) specified in the EN 149-2001 standard.

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