4.7 Article

Synthetic control of composition and crystallite size of silver ferrite composites: profound electrochemistry impacts

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 24, 页码 5120-5123

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10277k

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  1. Department of Energy (DOE), Office of Basic Energy Sciences (BES) [DE-SC0008512]
  2. Gertrude and Maurice Goldhaber Distinguished Fellowship Program
  3. DOE, Office of Science, BES [DE-AC02-98CH10886]
  4. U.S. Department of Energy (DOE) [DE-SC0008512] Funding Source: U.S. Department of Energy (DOE)

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A paradigm for concomitant control of crystallite size and composition of bimetallic composites via co-precipitation is introduced. Direct preparation of composites of silver ferrite and amorphous maghemite via nonstoichiometric synthesis was demonstrated. Notable impact on electrochemistry was observed, with similar to 200% increase in reversible capacity for the small crystallite material.

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