Ultrathin ultrastrong transparent films made from regenerated cellulose and epichlorohydrin

Thin films used in electronic devices are often petroleum-based, non-biodegradable, and non-renewable polymers. Herein, ultrathin ultrastrong regenerated cellulose films were made with a facile method by applying a solution of mildly carboxylated nanocellulose and various amounts of epichlorohydrin (ECH) as a crosslinker. The morphology and physiochemical properties of films were measured using FE-SEM, TEM, FTIR, NMR, UV-Vis, XRD, DLS, and TGA. Carboxylated cellulose with a charge content of 1.5 mmol/g was prepared to make alkaline dopes containing nanocrystalline cellulose (CNC). Then, ECH (0-50%) was added and the dope was blade cast, dried in an oven, regenerated in an acid bath, washed, and air dried to make uniform films approximately 1 & mu;m thick. The tensile stress and elastic modulus of the films were measured and found to be 100-300 MPa and 5-12.7 GPa, respectively. Higher amounts of ECH led to stronger films. All films were over 96% transparent, insoluble in water, and absorbed 24-28% moisture. TGA analysis showed ultrathin films were thermally resistant up to 250 degrees C and were stable and unchanged over a month at 105 degrees C showing excellent thermal aging resistance. Overall, films with 5-10% ECH are extremely strong, which makes them promising bioresource-based candidates for flexible electronic applications.

Automated summary

Ultrathin ultrastrong regenerated cellulose films were prepared using mildly carboxylated nanocellulose and epichlorohydrin as a crosslinker. The films exhibited excellent morphology and physiochemical properties, making them promising candidates for flexible electronic applications. The films were highly transparent and had good thermal resistance.