期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 19, 页码 4013-4016出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10411k
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资金
- Fundamental Research Funds for the Central Universities [DUT13RC(3)34, DUT13RC(3)103]
- China Postdoctoral Science Foundation [2013M541227]
- National Natural Science Foundation of China [21403028, 21120102036, 91233201]
- National Basic Research Program of China (973 program) [2014CB239402]
- Swedish Energy Agency
- K & A Wallenberg Foundation
- NRF of Korea through CRI [NRF-2012R1A3A2048842]
- GRL [NRF-2010-00353]
A nonheme manganese(IV)-oxo complex, [Mn-IV(O)(BQCN)](2+), was generated in the photochemical and chemical oxidation of [Mn-II(BQCN)](2+) with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [Mn-II(BQCN)](2+) has been demonstrated in both neutral and acidic media.
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