期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 17, 页码 3549-3551出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09567g
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资金
- NFSC [21172062, 21273067, 21373080]
- Fundamental Research Funds for the Central Universities (Hunan University)
The dehydrogenative coupling of terminal alkynes with secondary phosphine oxides is developed. In the presence of a silver additive, palladium acetate could efficiently catalyze the dehydrocoupling of secondary phosphine oxides with a variety of terminal alkynes to produce the corresponding alkynylphosphine oxides in high yields. A reaction mechanism is proposed.
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