期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 24, 页码 4969-4972出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09091h
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资金
- National Natural Science Foundation of China [21303038, 21136005, 21476109]
- Jiangsu Province Science Foundation for Youths [BK20130921]
- Specialized Research Fund for the Doctoral Program of Higher Education [20133221120002]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
A hierarchical meso-macroporous poly(ionic liquid) monolith with tunable pore structure is synthesized through free radical self-polymerization of 1-allyl-3-vinylimidazolium ionic liquid by using the tri-block copolymer P123 as the soft template. The obtained polymeric matrix can highly disperse heteropolyanions through anion-exchange, exhibiting superior catalytic activity in cis-cyclooctene epoxidation with H2O2.
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