期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 1, 页码 74-76出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06809b
关键词
-
资金
- Australian Research Council [DP110104759]
- Australian Commonwealth for the provision of Australian Postgraduate Awards
The air stable NHC IPrBr is reported. A stereoelectronic study of IPrBr and its similarly stable relative IMesBr demonstrates metal complex specific changes in NHC donicity versus the ubiquitous IPr and IMes. Application to a Suzuki coupling and an iridium transfer hydrogenation gives superior outcomes using IPrBr and IMesBr.
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