期刊
APPLIED SURFACE SCIENCE
卷 645, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2023.158757
关键词
Cobalt sulfide; Carbon nanotube; Hollow cattail shape; Supercapacitor electrode
Hollow composites with hierarchical channels were prepared using an in situ self-assembly strategy, resulting in excellent electrochemical energy storage performance.
Despite the achievement in generating various hollow architectures, designing hollow composites with hierar-chical channels remains challenging to achieve excellent electrochemical energy storage performance. To address this issue, we developed an in situ self-assembly strategy to prepare hollow composites using zeolitic-imidazolate frameworks and carbon nanotubes (ZIF@CNT). These ZIF@CNT architectures with different ap-pearances are prepared by adjusting the stirring rate during the reaction. Subsequently, the sulfurization strategy is applied to convert ZIF-67 to cobalt sulfide (CoS), resulting in the hollow CoS@CNT hybrids. These hierarchical channels include the hollow CoS cavities and CNT channels. The unique hollow composites with different di-mensions played a synergistic effect between subunits, thus giving excellent electrochemical properties. The impact of particle cavity channel size on electrochemical properties was evaluated systematically. As expected, CoS@CNT with hollow cattail-shape structures (HCCoS@CNT) resulted in the optimal specific capacitance (1250 F/g) and cyclic stability (90.4 % for over 10,000 times of cycling at 10 A/g). The designed hybrid supercapacitor, HCCoS@CNT//active carbon (AC), delivered an exceptional energy density of 40 Wh kg-1 at 800 W kg-1 of the power density. Together, these findings provide a reference for preparing complex hollow structures as high-performance electrodes, clarifying the optimization of composites for improved electrochemical properties.
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