Scrutinizing pre- and post-device fabrication properties of atomic layer deposition WS2 thin films

In this work, we investigate the physical and electrical properties of WS2 thin films grown by a plasma-enhanced atomic layer deposition process, both before and after device fabrication. The WS2 films were deposited on thermally oxidized silicon substrates using the W(NMe2)(2)(NtBu)(2) precursor and a H2S plasma at 450 & DEG;C. The WS2 films were approximately 8 nm thick, measured from high-resolution cross-sectional transmission electron imaging, and generally exhibited the desired horizontal basal-plane orientation of the WS2 layers to the SiO2 surface. Hall analysis revealed a p-type behavior with a carrier concentration of 1.31 x 10(17) cm(-3). Temperature-dependent electrical analysis of circular transfer length method test structures, with Ni/Au contacts, yielded the activation energy (E-a) of both the specific contact resistivity and the WS2 resistivity as 100 and 91 meV, respectively. The similarity of these two values indicates that the characteristics of both are dominated by the temperature dependence of the WS2 hole concentration. Change in the material, such as in sheet resistance, due to device fabrication is attributed to the chemicals and thermal treatments associated with resist spinning and baking, ambient and UV exposure, metal deposition, and metal lift off for contact pad formation.

Automated summary

In this study, the physical and electrical properties of WS2 thin films grown by plasma-enhanced atomic layer deposition were investigated. The films exhibited the desired orientation and p-type behavior, with a carrier concentration of 1.31 x 10^17 cm(-3). The temperature-dependent analysis revealed similar activation energies for the specific contact resistivity and WS2 resistivity, indicating that both are affected by the temperature dependence of the WS2 hole concentration. Changes in material properties after device fabrication were attributed to various chemical and thermal treatments associated with the process.