期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
WILEY
DOI: 10.1002/aoc.7262
关键词
2-guanidinobenzimidazole; hetero-catalyst; Lewis acid catalysts; outstanding yields; TD-DFT
Three GUBZCu, GUBZVO, and GUBZPd chelates were synthesized and characterized in terms of their molecular formula, stability constant, and catalytic performance. The results confirmed the promising catalytic activity and selectivity of these chelates in environmentally friendly synthesis reactions.
Three GUBZCu, GUBZVO, and GUBZPd chelates have been prepared from 2-guanidino benzimidazole (GUBZ ligand) by a bidentate coordinating approach. FT-IR, mass, and NMR spectra; magnetic moment; CHN analysis; UV-Vis spectra; molar conductance; and TGA were studied to describe and estimate the molecular formulae of tested molecules. The stability constant for GUBZ complexes was estimated in the solution. Also, the pH profile displays the extra stability of tested complexes. Structure elucidation of the studied complexes had been supported by density functional theory (DFT) along with calculated electronic and vibrational spectra. Electronic absorption spectra were estimated practically through UV-Vis spectra and theoretically performed using the time-dependent TD-DFT/B3LYP, for computing the absorption maximum, oscillator strength, and excitation energy of the tested compounds. This study was done into these chelates' catalytic performances for the environmentally friendly synthesis of 7-amino-4,5-dihydro-tetrazolo[1,5-a]pyrimidine-6-carbonitrile derivatives utilizing aromatic aldehyde, malononitrile, and 5-amino tetrazole as reactants. The used reactions have been directed in a concerned environment through a green solvent. The obtained results verified the promising catalytic activity and selectivity of the tested complexes. All tested reaction conditions have been enhanced between variable Lewis acid catalysts in associating to our studied complexes. GUBZPd catalyst presented an advantage in overall tests through high yield, green conditions, and short time. Also, the regaining of hetero-catalyst has prospered as well as recycled through the same effectiveness up to four or five times, and then the performance has been reduced. The mechanism of action has been recommended depending on the capability of the Pd (II) complex for totaling extra bonds above the z-axis as well as reinforced with theoretical study. This strategy's simplicity, safety, commercially accessible catalyst, stability, fast reaction time, and outstanding yields may be used in the industry in the future.
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