期刊
APPLIED CLAY SCIENCE
卷 239, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.clay.2023.106951
关键词
Composite membrane; Magnetic palygorskite; Anti-fouling; Easy-cleaning; Poly(vinylidene fluoride)
In this study, magnetic palygorskite (m-Pal) nanofibers were obtained by anchoring Fe3O4 nanoparticles onto the surface of palygorskite. Composite membranes composed of poly(vinylidene fluoride) (PVDF) and m-Pal were prepared during a magnetic field assisted phase inversion process. The m-Pal can be elevated to the membrane surface due to magnetic force, thus adjusting membrane performance.
Membrane technology can realize wastewater recycling in industry, but its efficiency is threatened by fouling. In this study, magnetic palygorskite (m-Pal) nanofibers were obtained by anchoring Fe3O4 nanoparticles onto the surface of palygorskite. Then, composite membranes composed of poly(vinylidene fluoride) (PVDF) and m-Pal were prepared during a magnetic field assisted phase inversion process. The m-Pal can be elevated to the membrane surface due to magnetic force, thus adjusting membrane performance. The PVDF/m-Pal composite membrane prepared with magnetic field displayed higher water flux and better hydrophilicity than that of pristine PVDF membrane. The water flux can be increased to 343.2 L.m(-2).h(-1).bar(-1), and water contact angle decreases to 71.8 degrees with the addition of 7% m-Pal. Moreover, the anti-fouling and easy-cleaning performance of the composite membrane was demonstrated in bovine serum albumin (BSA) solution separation, with BSA flux and flux recovery ratio increased by 41.3% and 155.4%, respectively, compared with the control PVDF membrane.
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