Synergetic regulation of CeO2 modification and (W2O7)2- intercalation on NiFe-LDH for high-performance large-current seawater electrooxidation

Four-electron process and the interference of Cl- make sluggish kinetics on oxygen evolution reaction (OER) for seawater electrolysis. Herein, NiFe LDH grown on NiFe-foam with CeO2 modification and (W2O7)(2-)intercalation was synthesized by one-step hydrothermal method. It only needs 353.8 and 386.7 mV to achieve a large current density of 1000 mA center dot cm(-2) in 1 M KOH and alkaline natural seawater, respectively. The catalytic material can stand 100 h with a retention of 98.1% at 1000 mA center dot cm(-2) in alkaline natural seawater. Experiments and theo-retical calculations confirm that the state-of-the-art OER activity comes from the introduced CeO2 with optimized adsorption energy of intermediates. The improved stability and selectivity in seawater can be ascribed to the preferential adsorption of Ni and Fe with higher valence on OH- based on hard and soft acid based (HSAB) principle by (W2O7)(2-)intercalation. This work provides a viable approach to develop efficient catalytic material for large-current seawater electrolysis.

Automated summary

NiFe LDH with CeO2 modification and (W2O7)(2-)intercalation is synthesized for efficient oxygen evolution reaction (OER) in seawater electrolysis. The catalytic material only requires 353.8 and 386.7 mV to achieve a large current density of 1000 mA·cm(-2) in 1 M KOH and alkaline natural seawater, respectively. The introduced CeO2 provides optimized adsorption energy of intermediates, leading to improved stability and selectivity in seawater. The preferential adsorption of Ni and Fe based on hard and soft acid based (HSAB) principle by (W2O7)(2-)intercalation contributes to the enhanced performance.