☆ 4.8 Article

Correlating Metal Redox Potentials to Co(III)K(I) Catalyst Performances in Carbon Dioxide and Propene Oxide Ring Opening Copolymerization

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Inorganic & Nuclear

Cooperative Initiation in a Dinuclear Indium Complex for CO2 Epoxide Copolymerization

Hyuk-Joon Jung et al.

Summary: Dinuclear indium complexes have been synthesized and characterized. The neutral indium chloride complex [(ONapNiN)InCl2]2 (4) showed high conversion and selectivity for the alternating copolymerization of cyclohexene oxide and CO2. The reactivity of the dinuclear indium chloride complex 4 differs significantly from that of the mononuclear indium chloride complex 5, suggesting a cooperative initiation mechanism involving the two indium centers in 4.

INORGANIC CHEMISTRY (2023)

添加到收藏夹

Article Polymer Science

Current Challenges and Perspectives in CO2-Based Polymers

Ye Liu et al.

Summary: Carbon dioxide (CO2) is a renewable building block for chemical synthesis, offering advantages like abundance, low toxicity, nonflammability, and availability. Incorporating CO2 into polymers provides desirable material properties and unique degradability under microbial conditions. This Perspective highlights recent advances, catalytic strategies, conceptual routes, and potential applications of CO2-derived polymers, while also discussing future challenges and new strategies for developing CO2-based polymers with desired performance and economic competitiveness comparable to petroleum-based materials.

MACROMOLECULES (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide

Natalia Reis et al.

Summary: This study systematically investigates a series of heterodinuclear Mg(II)M(II) complexes to identify the most effective metal combinations for the catalysed ring opening copolymerizations of carbon dioxide/epoxide and anhydride/epoxide. Mg(II)Co(II) and Mg(II)Fe(II) are found to be the fastest catalysts with high selectivity and control. Additionally, the transition metal heterodinuclear complexes exhibit synergic rate enhancements compared to the homodinuclear Mg(II)Mg(II) complex.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

添加到收藏夹

Article Nanoscience & Nanotechnology

Biodegradable Films of PLA/PPC and Curcumin as Packaging Materials and Smart Indicators of Food Spoilage

Martin Cvek et al.

Summary: In this study, a bio-based and biodegradable material was developed for sustainable packaging and as a smart indicator for ammonia vapor and food spoilage. The material, a blend of poly(lactic acid) and poly(propylene carbonate) loaded with curcumin, exhibited good compatibility and thermal stability. By changing the ratio of the biopolymers, the properties of the material could be easily adjusted. The material showed efficient absorption of UV radiation and the ability to provide effective antioxidant action. It also demonstrated the potential to serve as a cost-effective, easy-to-use, nondestructive, smart indicator for food packaging and NH3 gas monitoring.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synergic Heterodinuclear Catalysts for the Ring-Opening Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides

Wilfred T. Diment et al.

Summary: The development of sustainable plastic materials using sustainable monomers and polymers that can be chemically recycled is a key goal of 21st century chemistry. However, designing efficient catalysts for these processes remains challenging due to issues such as low catalytic activities, high catalyst loading requirements, and the need for costly, toxic cocatalysts.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Buffering Volume Change in Solid-State Battery Composite Cathodes with CO2-Derived Block Polycarbonate Ethers

Georgina L. Gregory et al.

Summary: Polymers with specific properties can help overcome challenges in all-solid-state batteries, resulting in improved capacity retention.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Insights into the Mechanism of Carbon Dioxide and Propylene Oxide Ring-Opening Copolymerization Using a Co(III)/K(I) Heterodinuclear Catalyst

Arron C. Deacy et al.

Summary: A combined computational and experimental investigation was conducted on the catalytic cycle of carbon dioxide and propylene oxide ring-opening copolymerization. The study revealed the role of a Co(III)K(I) heterodinuclear complex in activating and stabilizing the intermediates, as well as the transient carbonate nucleophile provided by potassium. The results provided insights into the key steps and selectivity limitations of the catalytic cycle, aiding future catalyst design and optimization.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Physical

Mechanistic Basis for the High Enantioselectivity and Activity in the Multichiral Bimetallic Complex-Mediated Enantioselective Copolymerization of meso-Epoxides

Bai-Hao Ren et al.

Summary: This study analyzed the basis for the high enantioselectivity and activity of multichiral bimetallic catalysts using experimental observations and theoretical calculations. The results showed that ligand exchange and the opening of the ring were crucial steps for the reaction, and the flexibility of the bimetallic complex played a significant role in achieving high enantioselectivity.

ACS CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Physical

Tertiary and Quaternary Phosphonium Borane Bifunctional Catalysts for CO2/Epoxide Copolymerization: A Mechanistic Investigation Using In Situ Raman Spectroscopy

Jonathan Schaefer et al.

Summary: This study investigates the use of modified tertiary and quaternary phosphonium borane catalysts for CO2/epoxide copolymerization. The catalysts were analyzed using in situ Raman spectroscopy and a nonisothermal kinetic technique to evaluate their performance. The results showed that the substitution of phosphonium/borane groups and the tether length significantly affected the polymerization rates. Additionally, the tertiary phosphonium catalysts maintained high activity in the presence of excess di-alcohols.

ACS CATALYSIS (2022)

添加到收藏夹

Review Chemistry, Physical

Multifunctional Catalysts for Ring-Opening Copolymerizations

Claire A. L. Lidston et al.

Summary: The ring-opening copolymerization (ROCOP) of epoxides with CO2 or cyclic anhydrides using multifunctional catalysts has been explored as a versatile route for synthesizing a wide range of polycarbonate and polyester copolymers. Covalently tethering the Lewis acid catalyst and cocatalyst together has been shown to increase both catalyst activity and selectivity in epoxide ROCOP. This review examines the development of multifunctional catalysts for copolymerization of epoxides with CO2, cyclic anhydrides, carbonyl sulfide (COS), and cyclic thioanhydrides, and evaluates how the mechanisms of these catalysts lead to improved activity and selectivity in ROCOP.

ACS CATALYSIS (2022)

添加到收藏夹

Article Polymer Science

Borinane-based organoboron catalysts for alternating copolymerization of CO2 with cyclic ethers: improved productivity and facile recovery

Chao Chen et al.

Summary: This research describes the design and synthesis of organoboron catalysts for the alternating ring-opening copolymerization (ROCOP) of CO2 with cyclic ethers. The performance of these catalysts was assessed by considering various parameters, such as the type of boron center, the distance between the boron center and the ammonium cation, and the size of the substituents of the cation. Among all the boron-based catalysts, borinane-based catalyst 5 showed the highest productivity in the copolymerization of CO2 and epoxides. Additionally, catalyst 5 could be easily recycled and used as a difunctional initiator. Density Functional Theory computation provided insights into the mechanism of the bifunctional catalyst-mediated CO2 copolymerization and highlighted the importance of the type of boron centers in the overall performance.

POLYMER CHEMISTRY (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Progress in the catalytic reactions of CO2 and epoxides to selectively provide cyclic or polymeric carbonates

Gulzar A. Bhat et al.

Summary: Sustainability requires the reuse of carbon sources from CO2 emissions, making carbon capture and utilization essential. Coupling of oxiranes (epoxides) with CO2 can generate cyclic carbonates and polymeric materials, providing a potential solution. It is important to use epoxides derived from renewable resources for a sustainable process.

GREEN CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chemoselective C-C σ-Bond Activation of the Most Stable Ring in Biphenylene**

Richard Y. Kong et al.

Summary: This study reports the chemoselective cleavage of a six-membered aromatic ring in biphenylene using an aluminum(I) complex, which is unprecedented. Insight into the origin of the chemoselectivity was obtained through a detailed mechanistic analysis, revealing that differences in the symmetry and radial extension of the frontier molecular orbitals of the aluminum(I) fragment compared to common transition metal fragments contribute to the divergent reactivity observed.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity

Guan-Wen Yang et al.

Summary: Organoboron catalysts play a significant role in chemical transformations. This study summarizes recent advances in developing organoboron catalysts that combine high efficiency and easy preparation through modular design, optimizing the catalysts for various chemical reactions.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pinwheel-Shaped Tetranuclear Organoboron Catalysts for Perfectly Alternating Copolymerization of CO2 and Epichlorohydrin

Guan-Wen Yang et al.

Summary: This study presents pinwheel-shaped organoboron catalysts for the copolymerization of epichlorohydrin and CO2, achieving high polymer selectivity and quantitative CO2 uptake under mild conditions. The produced poly(chloropropylene carbonate) exhibits the highest molecular weight and glass transition temperature reported to date. The metal-free catalyst shows robust performance and potential for advancing CO2-based polycarbonates.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Physical

Heterotrinuclear Ring Opening Copolymerization Catalysis: Structure-activity Relationships

Alex J. Plajer et al.

Summary: Heteronuclear complexes exhibit high catalytic activity in ring opening copolymerizations. By studying a series of trinuclear complexes, it was found that certain catalysts show high activity for specific reactions, such as CHO/CO2 ROCOP and CHO/ PA copolymerization, allowing for controlled polyether block formation. These findings can guide future catalyst design and inspire other CO2 utilization processes.

ACS CATALYSIS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations

Wouter Lindeboom et al.

Summary: A series of heterodinuclear catalysts show good performance in the ring opening copolymerization of cyclohexene oxide and carbon dioxide, indicating the importance of auxiliary ligands and metal combinations in the design of efficient catalysts for carbon dioxide copolymerizations.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications

Arron C. Deacy et al.

Summary: The article discusses an efficient and broadly applicable method for producing copolymers using switchable polymerization catalysis, which utilizes a single catalyst switched between different catalytic cycles to prepare block sequence selective copolymers from monomer mixtures. It presents the principles of this catalysis, catalyst design criteria, selectivity and structural copolymer characterization tools, as well as the properties of resulting copolymers.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mg(ii) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers

Gloria Rosetto et al.

Summary: Carbon dioxide derived polymers are becoming useful materials in various applications, requiring more active and selective catalysts for structural diversity. Highly active catalysts can exhibit controllable selectivity for enchainment of mixtures of different compounds, leading to the creation of new polymers with regular carbon dioxide and biomass derived linkages.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom

Ruiyan Sun et al.

Summary: This review comprehensively summarizes the latest advancements in heterogeneous catalysis of CO2 hydrogenation to formic acid/formate, highlighting nanostructured and single atom catalysts based on noble metals. Key factors related to catalytic activity are emphasized, providing a strong foundation for rational catalyst design.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Carbon dioxide copolymers: Emerging sustainable materials for versatile applications

Han Cao et al.

Summary: This review summarizes the recent progress in CO2 copolymer materials, focusing on sustainable materials such as biodegradable polycarbonates and new structure polyurethanes. The research covers synthesis to material performance adjustment.

SUSMAT (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives, Elastomers, and Toughened Plastics

Gregory S. Sulley et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Biochemical Research Methods

Understanding chemical reactivity using the activation strain model

Pascal Vermeeren et al.

NATURE PROTOCOLS (2020)

添加到收藏夹

Review Chemistry, Physical

Machine Learning for Catalysis Informatics: Recent Applications and Prospects

Takashi Toyao et al.

ACS CATALYSIS (2020)

添加到收藏夹

Review Nanoscience & Nanotechnology

Chemical recycling to monomer for an ideal, circular polymer economy

Geoffrey W. Coates et al.

NATURE REVIEWS MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CO2 and epoxides

Arron C. Deacy et al.

NATURE CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes

Hiroki Asaba et al.

INORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bio-based and Degradable Block Polyester Pressure-Sensitive Adhesives

Thomas T. D. Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency

Guan-Wen Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Co(III)/Alkali-Metal(I) Heterodinuclear Catalysts for the Ring-Opening Copolymerization of CO2 and Propylene Oxide

Arron C. Deacy et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

CO2-Based Block Copolymers: Present and Future Designs

Yao-Yao Zhang et al.

TRENDS IN CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization

Georgina L. Gregory et al.

CHEMICAL SCIENCE (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

autoDIAS: a python tool for an automated distortion/interaction activation strain analysis

Dennis Svatunek et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Physical

Homogeneous Metallic Oligomer Catalyst with Multisite Intramolecular Cooperativity for the Synthesis of CO2 -Based Polymers

Han Cao et al.

ACS CATALYSIS (2019)

添加到收藏夹

Article Multidisciplinary Sciences

The technological and economic prospects for CO2 utilization and removal

Cameron Hepburn et al.

NATURE (2019)

添加到收藏夹

Article Multidisciplinary Sciences

Sustainable polycarbonate adhesives for dry and aqueous conditions with thermoresponsive properties

Anjeza Beharaj et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Physical

Deciphering key intermediates in the transformation of carbon dioxide into heterocyclic products

Rui Huang et al.

NATURE CATALYSIS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chain transfer agents utilized in epoxide and CO2 copolymerization processes

Donald J. Darensbourg

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Conjugated tri-nuclear salen-Co complexes for the copolymerization of epoxides/CO2: cocatalyst-free catalysis

Ranlong Duan et al.

GREEN CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Heterodinuclear zinc and magnesium catalysts for epoxide/CO2 ring opening copolymerizations

Gemma Trott et al.

CHEMICAL SCIENCE (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Functional Polycarbonates from Carbon Dioxide and Tailored Epoxide Monomers: Degradable Materials and Their Application Potential

Markus Scharfenberg et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Lanthanide Complexes Supported by a Trizinc Crown Ether as Catalysts for Alternating Copolymerization of Epoxide and CO2: Telomerization Controlled by Carboxylate Anions

Haruki Nagae et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Article Polymer Science

Making Various Degradable Polymers from Epoxides Using a Versatile Dinuclear Chromium Catalyst

Ye Liu et al.

MACROMOLECULES (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

The Multifaceted Reactivity of Single-Atom Heterogeneous Catalysts

Sharon Mitchell et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment

Jens Artz et al.

CHEMICAL REVIEWS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Redox Potential and Electronic Structure Effects of Proximal Nonredox Active Cations in Cobalt Schiff Base Complexes

Alexander H. Reath et al.

INORGANIC CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mechanistic Insights into the Alternating Copolymerization of Epoxides and Cyclic Anhydrides Using a (Salph)AICI and Iminium Salt Catalytic System

Megan E. Fieser et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Polymer Science

Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide

Masahiro Hatazawa et al.

MACROMOLECULES (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Highly Active and Readily Accessible Proline-Based Dizinc Catalyst for CO2/Epoxide Copolymerization

Mike Schuetze et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Analyzing Reaction Rates with the Distortion/Interaction-Activation Strain Model

F. Matthias Bickelhaupt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites

Markus Stuerzel et al.

CHEMICAL REVIEWS (2016)

添加到收藏夹

Review Pharmacology & Pharmacy

Poly(lactic acid)-Mass production, processing, industrial applications, and end of life

E. Castro-Aguirre et al.

ADVANCED DRUG DELIVERY REVIEWS (2016)

添加到收藏夹

Article Chemistry, Physical

Rigid linked dinuclear salph-co(III) catalyst for carbondioxide/epoxides copolymerization

Xiang Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure-Property Relationships

Julie M. Longo et al.

CHEMICAL REVIEWS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Development of Highly Active and Regioselective Catalysts for the Copolymerization of Epoxides with Cyclic Anhydrides: An Unanticipated Effect of Electronic Variation

Angela M. DiCiccio et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Metal-Free Alternating Copolymerization of CO2 with Epoxides: Fulfilling Green Synthesis and Activity

Dongyue Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Review Multidisciplinary Sciences

Sustainable polymers from renewable resources

Yunqing Zhu et al.

NATURE (2016)

添加到收藏夹

Article Chemistry, Physical

First principles optimally tuned range-separated density functional theory for prediction of phosphorus-hydrogen spin-spin coupling constants

Mojtaba Alipour et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

添加到收藏夹

Article Chemistry, Physical

Bimetallic bis(benzotriazole iminophenolate) cobalt, nickel and zinc complexes as versatile catalysts for coupling of carbon dioxide with epoxides and copolymerization of phthalic anhydride with cyclohexene oxide

Chun-Yue Yu et al.

CATALYSIS SCIENCE & TECHNOLOGY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Concerning the Deactivation of Cobalt(III)-Based Porphyrin and Salen Catalysts in Epoxide/CO2 Copolymerization

Wei Xia et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dinuclear metal catalysts: improved performance of heterodinuclear mixed catalysts for CO2-epoxide copolymerization

P. K. Saini et al.

CHEMICAL COMMUNICATIONS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Life cycle assessment of polyols for polyurethane production using CO2 as feedstock: insights from an industrial case study

Niklas von der Assen et al.

GREEN CHEMISTRY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Facile Estimation of Catalytic Activity and Selectivities in Copolymerization of Propylene Oxide with Carbon Dioxide Mediated by Metal Complexes with Planar Tetradentate Ligand

Takahiro Ohkawara et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Polymer Science

Mechanistic Understanding of Dinuclear Cobalt(III) Complex Mediated Highly Enantioselective Copolymerization of meso-Epoxides with CO2

Ye Liu et al.

MACROMOLECULES (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copolymerization of carbon dioxide and butadiene via a lactone intermediate

Ryo Nakano et al.

NATURE CHEMISTRY (2014)

添加到收藏夹

Review Polymer Science

A concise review of computational studies of the carbon dioxide-epoxide copolymerization reactions

Donald J. Darensbourg et al.

POLYMER CHEMISTRY (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copolymerization of CO2 and meso epoxides using enantioselective β-diiminate catalysts: a route to highly isotactic polycarbonates

W. Chadwick Ellis et al.

CHEMICAL SCIENCE (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Asymmetric Copolymerization of CO2 with meso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity

Ye Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Flexibly Tethered Dinuclear Zinc Complexes: A Solution to the Entropy Problem in CO2/Epoxide Copolymerization Catalysis?

Maximilian W. Lehenmeier et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

A One-Pot Synthesis of a Triblock Copolymer from Propylene Oxide/Carbon Dioxide and Lactide: Intermediacy of Polyol Initiators

Donald J. Darensbourg et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Reaction of CO2 with propylene oxide and styrene oxide catalyzed by a chromium(III) amine-bis-(phenolate) complex

Rebecca K. Dean et al.

DALTON TRANSACTIONS (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

CO2/ethylene oxide copolymerization and ligand variation for a highly active salen-cobalt(III) complex tethering 4 quaternary ammonium salts

Jong Yeob Jeon et al.

DALTON TRANSACTIONS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Modeling of phytochrome absorption spectra

Olle Falklof et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Physical

In situ FTIR investigation of the solubility and swelling of model epoxides in supercritical CO2

Stephanie Foltran et al.

JOURNAL OF SUPERCRITICAL FLUIDS (2012)

添加到收藏夹

Article Polymer Science

Experimental and Computational Investigation of the Mechanism of Carbon Dioxide/Cyclohexene Oxide Copolymerization Using a Dizinc Catalyst

Antoine Buchard et al.

MACROMOLECULES (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Di-cobalt(II) catalysts for the copolymerisation of CO2 and cyclohexene oxide: support for a dinuclear mechanism?

Michael R. Kember et al.

CHEMICAL SCIENCE (2012)

添加到收藏夹

Article Polymer Science

Kinetic and Mechanistic Investigation of Mononuclear and Flexibly Linked Dinuclear Complexes for Copolymerization of CO2 and Epoxides

Stephan Klaus et al.

MACROMOLECULES (2011)

添加到收藏夹

Article Polymer Science

Connection of polymer chains using diepoxide in CO2/propylene oxide copolymerizations

Anish Cyriac et al.

POLYMER CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes

Koji Nakano et al.

CHEMICAL SCIENCE (2010)

添加到收藏夹

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mechanistic Aspects of the Copolymerization of CO2 with Epoxides Using a Thermally Stable Single-Site Cobalt(III) Catalyst

Wei-Min Ren et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Physical

Systematic optimization of long-range corrected hybrid density functionals

Jeng-Da Chai et al.

JOURNAL OF CHEMICAL PHYSICS (2008)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2 Copolymerization

Dirk F. -J. Piesik et al.

ORGANOMETALLICS (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Two components in a molecule:: Highly efficient and thermally robust catalytic system for CO2/Epoxide copolymerization

Eun Kyung Noh et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

Design of highly active binary catalyst systems for CO2/epoxide copolymerization:: Polymer selectivity, enantioselectivity, and stereochemistry control

XB Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

Selective formation of polycarbonate over cyclic carbonate: Copolymerization of epoxides with carbon dioxide catalyzed by a cobalt(III) complex with a piperidinium end-capping arm

Koji Nakano et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cobalt catalysts for the alternating copolymerization of propylene oxide and carbon dioxide: Combining high activity and selectivity

CT Cohen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copolymerization of cyclohexene oxide with CO2 by using intramolecular dinuclear zinc catalysts

YL Xiao et al.

CHEMISTRY-A EUROPEAN JOURNAL (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bimetallic anilido-aldimine zinc complexes for epoxide/CO2 copolymerization

BY Lee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Polymer Science

Copolymerization of carbon dioxide and epoxide

H Sugimoto et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2004)

添加到收藏夹

Review Chemistry, Multidisciplinary

Mechanism of the alternating copolymerization of epoxides and CO2 using β-diiminate zinc catalysts:: Evidence for a bimetallic epoxide enchainment

DR Moore et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.