4.8 Article

Electric-Field-Induced Alignment of Functionalized Carbon Nanotubes Inside Thermally Conductive Liquid Crystalline Polyimide Composite Films

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202309010

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Electric-Field-Induced Alignment; Liquid Crystalline Polyimide; Liquid Crystals; Nanotubes; Thermally Conductive Composite Films

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The positive liquid crystals, 4'-heptyl-4-biphenylcarbonitrile (7CB), are used to functionalize carbon nanotubes (LC-CNT) and fabricate thermally conductive LC-CNT/LC-PI composite films through the oriented alignment of LC-CNT within the LC-PI matrix. The resulting composite films exhibit significantly improved thermal conductivity and mechanical properties compared to the intrinsically thermally conductive LC-PI films and CNT/LC-PI composite films.
The positive liquid crystals, 4'-heptyl-4-biphenylcarbonitrile (7CB), are used to functionalize carbon nanotubes (LC-CNT), which can be aligned in the liquid crystalline polyimide (LC-PI) matrix under an alternating electric field to fabricate the thermally conductive LC-CNT/LC-PI composite films. The efficient establishment of thermal conduction pathways in thermally conductive LC-CNT/LC-PI composite films with a low amount of LC-CNT is achieved through the oriented alignment of LC-CNT within the LC-PI matrix. When the mass fraction of LC-CNT is 15 wt%, the in-plane thermal conductivity coefficient (lambda(||)) and the through-plane thermal conductivity coefficient (lambda(perpendicular to)) of the LC-CNT/LC-PI composite films reach 4.02 W/(m center dot K) and 0.55 W/(m center dot K), which are 90.5% and 71.9% higher than those of the intrinsically thermally conductive LC-PI films respectively, also 28.8% and 5.8% higher than those of the CNT/LC-PI composite films respectively. Meanwhile, the thermally conductive LC-CNT/LC-PI composite films also possess excellent mechanical and heat resistance properties. The Young's modulus and the heat resistance index are 2.3 GPa and 297.7 degrees C, respectively, which are higher than the intrinsically thermally conductive LC-PI films and the thermally conductive CNT/LC-PI composite films under the same amount of CNT.

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