☆ 4.8 Review

Dynamic Cages-Towards Nanostructured Smart Materials

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Inorganic & Nuclear

Trefoil-Shaped Metal-Organic Cages as Fluorescent Chemosensors for Multiple Detection of Fe3+, Cr2O72-, and Antibiotics

Zhaoxin Meng et al.

Summary: A novel phenanthroline-based metal-organic cage with a rare trefoil-shaped structure and excellent fluorescence sensing abilities was successfully synthesized. Through X-ray analysis, it was found that the cage exhibits a rare trefoil-shaped structure and has further stacked into a 3D porous supramolecular structure through abundant intermolecular interactions. Experimental results showed that the cage has excellent fluorescence sensing abilities for Fe3+, Cr2O72-, and nitrofuran and nitroimidazole antibiotics.

INORGANIC CHEMISTRY (2023)

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Review Chemistry, Multidisciplinary

Porous Organic Cages

Xinchun Yang et al.

Summary: Porous organic cages (POCs) are a new class of low-density crystalline materials that have wide applications in molecular recognition, gas storage and separation, and proton conduction. Compared to other porous structures like MOFs, COFs, and POPs, POCs have the advantages of specific surface areas, porosities, open pore channels, tunable structures, and solubilities in common solvents. This review summarizes recent progress in POCs, including their design, synthesis, characterization, and applications, and discusses future challenges and opportunities in the field.

CHEMICAL REVIEWS (2023)

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Article Chemistry, Multidisciplinary

Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic CO2 Reduction

Lun An et al.

Summary: We present a supramolecular approach to catalyzing photochemical CO2 reduction using second-sphere porosity and charge effects. This work establishes that synergistic pendants in the secondary coordination sphere can be leveraged as a design element to augment catalysis at primary active sites within confined spaces.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Article Chemistry, Multidisciplinary

Mechanoresponsive Metal-Organic Cage-Crosslinked Polymer Hydrogels

Robin Kueng et al.

Summary: We have developed metal-organic cage-crosslinked polymer hydrogels by using bipyridine-functionalized polyethylene glycol chains. These hydrogels can encapsulate guest molecules and can be disassembled by ultrasound to release the cargo. The performance of the hydrogels was characterized by various techniques, including NMR, rheology, and SAXS experiments. The study also reveals the mechanism of cage-opening and demonstrates the enhanced drug-loading capacity of the hydrogels compared to non-crosslinked assemblies.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

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Article Chemistry, Multidisciplinary

Coordination Cage-Based Emulsifiers: Templated Formation of Metal Oxide Microcapsules Monitored by In Situ LC-TEM

Subhadeep Saha et al.

Summary: This study introduces a new type of metallo-supramolecular surfactant capable of stabilizing non-aqueous emulsions for a significant period, which is used for the synthesis of discrete amphiphiles with tailor-made polarity profiles, and utilizes in situ liquid cell transmission electron microscopy to visualize the formation dynamics of hollow inorganic titanium oxide and zirconium oxide microspheres.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Nonaqueous Emulsion Polycondensation Enabled by a Self-Assembled Cage-like Surfactant

Sudhakar Ganta et al.

Summary: This study introduces a self-assembled coordination cage as a molecular surfactant to stabilize various oil-in-oil emulsions. The cage can also be used for templated polycondensation reactions and guest molecule encapsulation.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Multidisciplinary

A coordination cage hosting ultrafine and highly catalytically active gold nanoparticles

Xinxin Hang et al.

Summary: The size-controlled synthesis of gold nanoparticles using CIAC-108 as a host or stabilizer resulted in smaller nanoparticles with superior catalytic capabilities. The cage-embedded gold nanoparticles showed enhanced catalytic activities and remarkable stability compared to their larger counterparts.

CHEMICAL SCIENCE (2022)

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Review Chemistry, Multidisciplinary

Beyond Platonic: How to Build Metal-Organic Polyhedra Capable of Binding Low-Symmetry, Information-Rich Molecular Cargoes

Charlie T. McTernan et al.

Summary: The field of metallosupramolecular chemistry has made rapid progress in recent years, focusing on the formation of hollow self-assembled metalorganic structures and their applications in confining nanospaces. However, most of the structures studied so far exhibit high symmetry, which limits their ability to interact with asymmetrical biomolecules and synthetic compounds. Therefore, the design of lower-symmetry metal-organic structures is necessary to bind, sense, separate, and transform such substrates.

CHEMICAL REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Post-synthetic modifications of metal-organic cages

Jinjin Liu et al.

Summary: This review explores the post-synthetic modification strategies for metal-organic cages (MOCs) and details the effects of newly introduced functional groups on MOCs. The development of this research provides systematic approaches for the development and characterization of MOC families and offers insights into the structure-function relationships for future developments.

NATURE REVIEWS CHEMISTRY (2022)

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Review Chemistry, Inorganic & Nuclear

Self-assembly of nanostructures with high complexity based on metal•••unsaturated-bond coordination

Yuya Domoto et al.

Summary: The coordinative self-assembly of simple building blocks towards complex nanostructures is currently a popular research area in the development of artificial nanomaterials comparable to biological systems. Traditional coordination donors have been widely used in previous studies, but the recent emergence of weak pi-coordination between metal ions and unsaturated carbon-carbon bonds offers a flexible and highly tolerant bonding approach for complex nanoarchitectures. The combination of metal-acetylene pi-coordination with conventional coordination has allowed for the formation of large polyhedral complexes with unprecedented molecular entanglement, highlighting the potential advantages of this concept.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Chemistry, Inorganic & Nuclear

Coordination/metal-organic cages inside out

Tomoki Tateishi et al.

Summary: Cage-like molecules formed by the coordination of metal ions and organic links have unique chemical properties and design flexibility, and are pushing the boundaries of science. This review article compares coordination cages (CCs) and metal-organic cages (MOCs) from two distinct chemistry communities, highlighting their similarities and differences. The article provides insights into synthetic conditions and identifies new research directions in the field.

COORDINATION CHEMISTRY REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Molecular engineering of confined space in metal-organic cages

James E. M. Lewis

Summary: Metal-organic cages (MOCs) are a highly studied class of abiotic host molecules, with the ability to be engineered at the molecular level and encapsulate molecular guests. This article focuses on the three key parameters of MOC cavities: size, shape, and functionality, and discusses the importance of chemical modifications in achieving precise engineering control.

CHEMICAL COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Metal-Organic Cages: Applications in Organic Reactions

Shangjun Chen et al.

Summary: Supramolecular metal-organic cages, as a type of molecular containers with structural aesthetics and unique properties, have been widely applied in catalysis. Their confined cavity analogous to enzymes and tunability of building blocks provide a diverse platform for organic reactions, leading to advancements in accelerating reactions, improving selectivity, and promoting tandem or cascade reactions.

CHEMISTRY-SWITZERLAND (2022)

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Review Chemistry, Multidisciplinary

Assembling metal-organic cages as porous materials

Eli Sanchez-Gonzalez et al.

Summary: In this tutorial review, the authors discuss the use of metal-organic cages (MOCs) as core building units for porous materials. They highlight the role of surface functionalization in achieving a range of states, including crystalline solids, soft matter, liquids, and composites. The review provides insights into the opportunities for developing increasingly complex functional porous materials.

CHEMICAL SOCIETY REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Practical considerations in the design and use of porous liquids

Hamidreza Mahdavi et al.

Summary: This article reviews the design, synthesis, and applicability of porous liquids (PLs), and discusses their pathway from the laboratory to practical application, while outlining possible challenges and opportunities.

MATERIALS HORIZONS (2022)

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Article Chemistry, Multidisciplinary

Schiff base capped gold nanoparticles for transition metal cation sensing in organic media

Miroslava Conkova et al.

Summary: We present a rapid and highly sensitive colorimetric method for detecting transition metal ions using Schiff base functionalized gold nanoparticles in a toluene-acetonitrile mixture. The limits of detection for Fe3+, Cu2+, and Ni2+ were at least two orders of magnitude lower than the EU recommended limits. Moreover, we demonstrated the applicability of this method for determining nickel in organic waste from an industrial reaction.

CHEMICAL COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Metallosupramolecular cages: from design principles and characterisation techniques to applications

Anna J. McConnell

Summary: This tutorial review introduces the principles for designing metallosupramolecular cages, with a focus on the design of large and lower symmetry cages. The characterization and identification of cages rely on complementary techniques such as NMR spectroscopy, mass spectrometry, X-ray crystallography, and computational methods. Finally, examples of cages are discussed where these design principles and characterization techniques are applied for specific applications or functions of the cages.

CHEMICAL SOCIETY REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Unlocking the computational design of metal-organic cages

Andrew Tarzia et al.

Summary: Metal-organic cages are macrocyclic structures with intrinsic voids that can hold molecules, offering a diverse range of shapes and sizes for tuning targeted properties. Computational design plays a crucial role in exploring and optimizing metal-organic cages, with examples of structure prediction and property evaluation showcasing the potential of high-throughput methods in this field. The development of automated cage design workflows is crucial in pushing toward functional and complex metal-organic cages, highlighting the importance of considering realistic, flexible systems.

CHEMICAL COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Coordination Cage-Based Emulsifiers: Templated Formation of Metal Oxide Microcapsules Monitored by In Situ LC-TEM

Subhadeep Saha et al.

Summary: The paper introduces a novel metallo-supramolecular surfactant that stabilizes non-aqueous emulsions for the synthesis of metal oxide microcapsules, analyzed using electron microscopic techniques. The dynamics of emulsion-templated hollow inorganic titanium oxide and zirconium oxide microspheres formation were visualized using in situ liquid cell transmission electron microscopy (LC-TEM) for the first time.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Catenated Cages Mediated by Enthalpic Reaction Intermediates

Shijun Xu et al.

Summary: By investigating the mechanism of catenated cages and considering factors such as the structural effects of building blocks and solvent influence, we have identified some design principles for constructing catenated cages effectively. Steric hindrance linkers and rigid panels play crucial roles in forming an enthalpy-favored encapsulated intermediate before catenation, while the stability of this intermediate is essential for successful catenation.

CCS CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Guest Encapsulation within Surface-Adsorbed Self-Assembled Cages

Hugh P. Ryan et al.

Summary: A method for immobilizing coordination cages on alumina has been reported, allowing for the encapsulation and separation of guest and non-guest molecules. Quantification of cage loadings and guest displacement assays demonstrate the retained ability of the adsorbed cages.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Non-covalent Interaction-directed Coordination-driven Self-assembly of Non-trivial Supramolecular Topologies

Jatinder Singh et al.

Summary: This review provides a comprehensive insight into the methods and challenges of obtaining non-trivial topologies through template-free, coordination-driven, and non-covalent interaction-directed self-assembly.

CHEMICAL RECORD (2021)

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Review Chemistry, Multidisciplinary

Metal-organic cages for molecular separations

Dawei Zhang et al.

Summary: Metal-organic cages, formed via coordination-driven self-assembly, show great promise as separation agents by selectively binding and distinguishing substances in solution through precise control of their structure. The use of cages as absorbents or incorporation into polymer membranes can enhance the efficiency and selectivity of separation processes. Challenges and potential future developments in using metal-organic cages for separations are also discussed.

NATURE REVIEWS CHEMISTRY (2021)

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Article Engineering, Chemical

Homoporous hybrid membranes containing metal-organic cages for gas separation

Ziqi Yang et al.

Summary: A strategy involving chemically cross-linking polymerizable metal-organic cages with polymeric precursors via UV-induced polymerization has been developed to fabricate homoporous hybrid membranes. This approach improves the thermal stability of the membranes and enhances their CO2 permeability and selectivity.

JOURNAL OF MEMBRANE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Porous Colloidal Hydrogels Formed by Coordination-Driven Self-Assembly of Charged Metal-Organic Polyhedra

Zaoming Wang et al.

Summary: Introduction of porosity into supramolecular gels endows soft materials with functionalities for molecular encapsulation, release, separation and conversion. Most of the materials can only be synthesized in organic solvents, and the examples of porous, MOP-based hydrogels are scarce. Gas sorption measurements confirmed the permanent porosity of the corresponding aerogels obtained from these MOP-based hydrogels, showing potentials for applications in gas sorption and catalysis.

CHEMISTRY-AN ASIAN JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Catalysis within coordination cages

Yadan Xue et al.

Summary: Coordination cages with well-defined cavities have attracted attention for their structural aesthetics and unique properties in various fields. This review summarizes the achievements of these materials in catalytic applications, including their use as catalysts and their ability to encapsulate catalytic cofactors. Furthermore, the current challenges and great potential of coordination cages in catalysis are discussed.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Spatiotemporal Control of Supramolecular Polymerization and Gelation of Metal-Organic Polyhedra

Alexandre Legrand et al.

Summary: This study demonstrates the spatiotemporal control of the structures, mechanical properties, and shape of porous soft materials based on metal-organic polyhedra (MOPs) using light and acids as stimuli. By adjusting the acid concentration, the cross-linking between MOPs, size of colloidal particles, density of the network, and ductility and stiffness of the resulting gel can be controlled. Additionally, local triggering of the self-assembly process using dispersed photoacid generator enables precise patterning of the gel into desired shapes, allowing integration into devices for sensing, separation, catalysis, or drug release applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Inorganic & Nuclear

Fluorescent sensors: A bright future for cages

Anna Brzechwa-Chodzynska et al.

Summary: This review gives a general overview of the development of fluorescent chemosensors based on closed three-dimensional architectures, highlighting examples from research groups that have made significant contributions to this field. It discusses the basic principles and challenges in designing cage-like fluorescence chemosensors for various guest molecules, with particular emphasis on the use of molecular and supramolecular fluorescent architectures for detecting explosives/hazardous substances, aromatics, and biologically active compounds.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Heng Wang et al.

Summary: Parastichy, the spiral arrangement of plant organs, provides both an aesthetic challenge and a mathematical inspiration to scientists. Synthetic efforts to replicate its regularity may allow for molecular-scale control over particle arrangement processes. This study on the packing of a supramolecular truncated cuboctahedron into double-helical nanowires with a non-natural parastichy pattern is expected to advance understanding of designing complex, precisely controlled hierarchical materials.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Physical

One-Dimensional (1D) Nanostructured Materials for Energy Applications

Abniel Machin et al.

Summary: The world is currently facing a paradigm shift in energy resources due to the depletion of traditional fossil fuels, leading to a progressive movement towards more sustainable and less polluting alternatives. Nanotechnology plays a significant role in this change, with 1D nanostructures being highlighted for their unique properties and potential applications in energy-related fields such as optoelectronics, hydrogen production, and energy storage. Research on nanostructured materials is essential for the future development of energy processes.

MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Promotion of Proton Conductivity by Encapsulation of Metal-Organic Polyhedra in Metal-Organic Frameworks

Bin-Cheng Wang et al.

Summary: A Zr-based metal-organic polyhedron (MOP) was synthesized in a porous MOF host, DUT-68, resulting in MOP-1@DUT-68. The encapsulation of MOP-1 in the MOF's cavities effectively prevented migration and leaching, leading to higher proton conductivity.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Engineering, Chemical

Metal-organic polyhedron membranes for molecular separation

Xiangyu Guo et al.

Summary: By utilizing ZrT-1-NH2, a type of water-stable metal-organic polyhedron, to construct porous MOP membranes, this study successfully created a defect-free separating layer with high water permeance and excellent dye rejection. The MOP membrane also demonstrated good antifouling and antibacterial properties, showing potential for practical molecular separations.

JOURNAL OF MEMBRANE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Coordination Cages Selectively Transport Molecular Cargoes Across Liquid Membranes

Bao-Nguyen T. Nguyen et al.

Summary: Chemical purifications require a significant amount of global energy, with coordination cages offering a new technological basis for achieving chemical separation. The selective transport of complex hydrocarbons across liquid membranes enables the isolation of target compounds from mixtures under ambient conditions. By using the selectivities of the cages, a two-stage separation process can isolate a single compound from a mixture of physicochemically similar molecules.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Ionic organic cage-encapsulated metal clusters for switchable catalysis

Wei Cao et al.

Summary: Stable and switchable catalysts have been engineered by locking catalytically active metal clusters inside molecular organic cages, enabling precise control over chemical reactions using light and pH stimuli.

CELL REPORTS PHYSICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Multiscale structural control of linked metal-organic polyhedra gel by aging-induced linkage-reorganization

Zaoming Wang et al.

Summary: The study demonstrates that aging is an effective strategy to control the hierarchical network of supramolecular gels, allowing tuning of the linked MOP gel network over multiple length scales. This provides an opportunity to engineer the structure and permanent porosity of amorphous materials for further applications.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Post-synthetic modification of porous organic cages

Hailong Wang et al.

Summary: Porous organic cages (POCs) are a class of organic materials with intrinsic porosity. Post-synthetic modification (PSM) has emerged as a highly viable strategy for broadening the functions and applications of POCs, leading to improved stability, tunable porosity, and selective guest binding. This approach allows for the realization of intricate structures and unique gas adsorption selectivity that cannot be achieved through traditional predesign methods.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Supramolecular structures based on metal-organic cages

Ehsan Raee et al.

Summary: Molecular metal-organic cages (MOCs) are constructed via coordination among diverse ligands and metal acceptors, allowing great control over size, shape, and composition, and enabling different types of intermolecular interactions to co-exist in solution. The interplay of multiple attractive forces drives the self-assembly of MOCs into various supramolecular structures, necessitating further research for understanding and design.

GIANT (2021)

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Structural self-sorting of pseudopeptide homo and heterodimeric disulfide cages in water: mechanistic insights and cation sensing

Marcin Konopka et al.

Summary: This study presents a versatile strategy for the synthesis of water-soluble, pseudopeptide molecular cages based on disulfide bonds, showing a degree of self-sorting related to the symmetry and size of the trithiol. Detailed kinetic studies and DFT molecular modeling provided original insights into the properties of the disulfide cages. The selected cage system was applied in the fluorometric detection of La3+ cations, resulting in a strongly luminescent metal-organic assembly.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Emerging Applications of Elemental 2D Materials

Nicholas R. Glavin et al.

ADVANCED MATERIALS (2020)

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Chiral metal-organic cages used as stationary phase for enantioseparations in capillary electrochromatography

Li-Xiao He et al.

ELECTROPHORESIS (2020)

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Metal-Organic Framework@Carbon Hybrid Magnetic Material as an Efficient Adsorbent for Pollutant Extraction

Mateo del Rio et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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The Chemistry of Porous Organic Molecular Materials

Marc A. Little et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Incorporation of homochiral metal-organic cage into ionic liquid based monolithic column for capillary electrochromatography

Zhentao Li et al.

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Metal-Organic Cages (MOCs): From Discrete to Cage-based Extended Architectures

El-Sayed M. El-Sayed et al.

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Ultrathin Films of Porous Metal-Organic Polyhedra for Gas Separation

Miguel A. Andres et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Coordination cages as permanently porous ionic liquids

Lillian Ma et al.

NATURE CHEMISTRY (2020)

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Coordination-Driven Self-Assembly in Polymer-Inorganic Hybrid Materials

Vincent J. Pastore et al.

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Application of Zero-Dimensional Nanomaterials in Biosensing

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Self-assembly of metalla[3]catenanes, Borromean rings and ring-in-ring complexes using a simple π-donor unit

Ye Lu et al.

NATIONAL SCIENCE REVIEW (2020)

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3D Nanostructures for the Next Generation of High-Performance Nanodevices for Electrochemical Energy Conversion and Storage

Huaping Zhao et al.

ADVANCED ENERGY MATERIALS (2020)

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Metal-Organic Frameworks and Metal-Organic Cages - A Perspective

Ben S. Pilgrim et al.

CHEMPLUSCHEM (2020)

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Multiscale investigation of adsorption properties of novel 3D printed UTSA-16 structures

Carlos A. Grande et al.

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Design and Applications of Water-Soluble Coordination Cages

Edmundo G. Percastegui et al.

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Ultrafine Palladium Nanoparticles Stabilized in the Porous Liquid of Covalent Organic Cages for Photocatalytic Hydrogen Evolution

Jian-Hua Zhang et al.

ACS APPLIED ENERGY MATERIALS (2020)

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UiO-66 derivatives and their composite membranes for effective proton conduction

Lu Feng et al.

DALTON TRANSACTIONS (2020)

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Metal-organic polyhedra crosslinked supramolecular polymeric elastomers

Jun Zhao et al.

CHEMICAL COMMUNICATIONS (2020)

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Computational screening for nested organic cage complexes

Enrico Berardo et al.

MOLECULAR SYSTEMS DESIGN & ENGINEERING (2020)

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A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra

Arnau Carne-Sanchez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Conversion of Metal-Organic Cage to Ligand-Free Ultrasmall Noble Metal Nanocluster Catalysts Confined within Mesoporous Silica Nanoparticle Supports

Wei Zhu et al.

NANO LETTERS (2019)

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Article Chemistry, Analytical

FRET-Based Semiconducting Polymer Dots for pH Sensing

Jiemei Ou et al.

SENSORS (2019)

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Strategies for binding multiple guests in metal-organic cages

Felix J. Rizzuto et al.

NATURE REVIEWS CHEMISTRY (2019)

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Heterogenization of Photochemical Molecular Devices: Embedding a Metal-Organic Cage into a ZIF-8-Derived Matrix To Promote Proton and Electron Transfer

Yu-Cheng Luo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Self-Healing Hyper-Cross-Linked Metal-Organic Polyhedra (HCMOPs) Membranes with Antimicrobial Activity and Highly Selective Separation Properties

Jinjin Liu et al.

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Fluorescence Emission of Polyethylenimine-Derived Polymer Dots and Its Application to Detect Copper and Hypochlorite Ions

Hao Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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MOP x MOF: Collaborative Combination of Metal-Organic Polyhedra and Metal Organic Framework for Proton Conductivity

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Coordinative Binding of Polymers to Metal-Organic Framework Nanoparticles for Control of Interactions at the Biointerface

Andreas Zimpel et al.

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Dynamic polyimine macrobicyclic cryptands - self-sorting with component selection

Michal Kolodziejski et al.

CHEMICAL SCIENCE (2019)

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Self-assembly of a cationic-cage via the formation of Ag-carbene bonds followed by imine condensation

Ritwik Modak et al.

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Shape-persistent porous organic cage supported palladium nanoparticles as heterogeneous catalytic materials

Shan Jiang et al.

NANOSCALE (2019)

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Metal-organic framework composites and their electrochemical applications

Yuqi Xue et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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In Situ Synthesis of Amino Acid Functionalized Carbon Dots with Tunable Properties and Their Biological Applications

Subrata Pandit et al.

ACS APPLIED BIO MATERIALS (2019)

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Understanding the multiscale self-assembly of metal-organic polyhedra towards functionally graded porous gels

Alexandre Legrand et al.

CHEMICAL SCIENCE (2019)

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