期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202300720
关键词
annulation; angular polycyclic aromatic molecules; cyclic 2-diazo-1,3-diones; nitrones; rhodium
We have disclosed a simple and general method for the synthesis of chromendiones through Rh(III)-catalyzed C-H functionalization/annulation reactions of nitrones with cyclic 2-diazo-1,3-diones by using nitrones as a traceless directing group. This method shows high efficiency and wide functional group compatibility. The derivatization of these chromendiones has also been demonstrated to enhance the synthetic utility of the transformation.
We herein disclose a simple and general method for the synthesis of chromendiones through Rh(III)-catalyzed C-H functionalization/annulation reactions of nitrones with cyclic 2-diazo-1,3-diones by using nitrone group as a traceless directing group. This method exhibits high efficiency and broad functional group compatibility. The derivatization of these chromendiones has been also demonstrated to further strengthen the synthetic utility of the transformation. image
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据