☆ 4.7 Article

Cobalt(III)-Catalyzed Aerobic Diamination of α-Alkyl Styrenes with Anilines

ADVANCED SYNTHESIS & CATALYSIS (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Multidisciplinary Sciences

Allylic C-H amination cross-coupling furnishes tertiary amines by electrophilic metal catalysis

Siraj Z. Ali et al.

Summary: In this study, a self-regulatory mechanism was developed for allylic carbon-hydrogen amination cross-coupling. By coupling the release of amine nucleophiles with catalyst turnover, excellent regio- and stereoselectivity were achieved. The method successfully produced a variety of drug compounds and complex drug derivatives.

SCIENCE (2022)

添加到收藏夹

Article Multidisciplinary Sciences

Iron-mediated ligand-to-metal charge transfer enables 1,2-diazidation of alkenes

Muliang Zhang et al.

Summary: Given the importance of vicinal diamine units in various fields, a strategy that avoids the use of stoichiometric strong oxidants is highly desirable. This study presents the application of ligand-to-metal charge transfer (LMCT) excitation to achieve 1,2-diazidation reactions using iron salt as the catalyst. The LMCT-homolysis mode enables the generation of electrophilic azidyl radical intermediate and subsequent carbon-nitrogen bond formation, providing a versatile and eco-friendly approach for the synthesis of structurally diverse diazides from alkenes.

NATURE COMMUNICATIONS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-catalysed selective oxidative amination of olefins with Lewis basic amines

Yangbin Jin et al.

Summary: A palladium-catalysed oxidative amination method has been developed for the synthesis of versatile and diverse allylamines, with high yields and good selectivity.

NATURE CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Organic

Synthesis of 1,2-Diamines from Vinyl Sulfonium Salts and Arylamines

Cheng Wang et al.

Summary: A procedure for the mild synthesis of 1,2-diamines without the need for a catalyst and oxidizing reagent has been developed. This method demonstrated practicality through one-pot synthesis, scale-up reaction, and transformation of products. Mechanistic studies revealed the crucial role of aziridine formation in this diamination process.

ORGANIC LETTERS (2022)

添加到收藏夹

Article Chemistry, Physical

Dioxygen-promoted cobalt-catalyzed oxidative hydroamination using unactivated alkenes and free amines

Wei-Ting Ye et al.

Summary: A cobalt-hydride-catalyzed hydroamination reaction based on a bimetallic redox-triggered oxidative amination pathway has been developed to selectively hydroaminate unactivated alkenes, demonstrating intra-and intermolecular addition of secondary amines across various substrates at ambient temperature.

CHEM CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrochemical Synthesis of Allylic Amines from Terminal Alkenes and Secondary Amines

Diana J. Wang et al.

Summary: Allylic amines are important synthetic targets for various biologically active compounds. A new electrochemical process was developed in this study to prepare aliphatic allylic amines by coupling secondary amines and unactivated alkenes. This method allows for the functionalization of feedstock gaseous alkenes and can be used to synthesize complex biologically active molecules.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Diastereodivergent Intermolecular 1,2-Diamination of Unactivated Alkenes Enabled by Iodine Catalysis

Satoshi Minakata et al.

Summary: This study demonstrates the stereospecific, substrate-controlled intermolecular anti- and syn-1,2-diaminations of unactivated alkenes using an iodine catalyst. The combined use of the two methods allows access to all diastereomeric forms of 1,2-diamines, even in the presence of E- and Z-alkenes, with the resulting products easily convertible into free vicinal diamines.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Organic

Copper-Catalyzed Diamination of Unactivated Alkenes With Electron-Rich Amino Sources

Yang Li et al.

Summary: Using a directing-group strategy, a copper-catalyzed diamination of unactivated alkenes efficiently generates symmetrical diamines with high diastereoselectivity using readily available dialkylamines as amino sources, while unsymmetrical diamines require a one-pot or two-step operation. These reactions are proposed to proceed through aziridinium intermediates.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Chemistry, Organic

Cobalt-Catalyzed Divergent Aminofluorination and Diamination of Styrenes with N-Fluorosulfonamides

Peng Guo et al.

Summary: A cobalt-catalyzed aminofluorination reaction of styrenes with N-fluorosulfonamides has been developed, with the selectivity easily switched to diamination by the addition of PPh3. Both transformations are tolerant to a wide array of substrates under mild reaction conditions.

ORGANIC LETTERS (2021)

添加到收藏夹

Review Chemistry, Organic

Catalytic, Enantioselective Diamination of Alkenes

Zhong-Lin Tao et al.

Summary: Enantioselective diamination of alkenes is an important method for accessing enantioenriched, vicinal diamines, with broad applications in asymmetric synthesis. Despite lagging behind dihydroxylation of olefins, successful methods using different reaction mechanisms have been developed for enantioselective olefin diamination. This review highlights recent advances and limitations in the field, aiming to inspire further developments.

SYNTHESIS-STUTTGART (2021)

添加到收藏夹

Review Chemistry, Organic

Recent developments in the difunctionalization of alkenes with C-N bond formation

Xiang Chen et al.

Summary: The difunctionalization of carbon-carbon double bonds is a powerful tool in synthetic chemistry to enhance the complexity of molecules by introducing two novel functional groups in one pot. Research on difunctionalization of alkenes involving the participation of a N source is a hotspot due to the broad existence of N-containing functional groups in various compounds, and further developments in this area are expected.

ORGANIC CHEMISTRY FRONTIERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Photoinduced Olefin Diamination with Alkylamines

Sebastian Govaerts et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Organic

Intermolecular Vicinal Diaminative Assembly of Tetrahydroquinoxalines via Metal-free Oxidative [4+2] Cycloaddition Strategy

Dangui Wang et al.

ORGANIC LETTERS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium(II)-Catalyzed Enantioselective Azidation of Unactivated Alkenes

Xiaonan Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

Szabolcs Makai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Physical

Catalytic enantioselective synthesis of chiral tetraarylmethanes

Xingguang Li et al.

NATURE CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Selenophosphoramide-catalyzed diamination and oxyamination of alkenes

John R. Tabor et al.

CHEMICAL SCIENCE (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Practical Aryliodine(I/III) Catalysis for the Vicinal Diamination of Styrenes

Eric Cots et al.

CHEMSUSCHEM (2019)

添加到收藏夹

Article Multidisciplinary Sciences

Hindered dialkyl ether synthesis with electrogenerated carbocations

Jinbao Xiang et al.

NATURE (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic, Enantioselective syn-Diamination of Alkenes

Zhonglin Tao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Review Multidisciplinary Sciences

The importance of synthetic chemistry in the pharmaceutical industry

Kevin R. Campos et al.

SCIENCE (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Hypercoordinate iodine for catalytic asymmetric diamination of styrene: insights into the mechanism, role of solvent, and stereoinduction

A. Sreenithya et al.

CHEMICAL SCIENCE (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Promoting Intermolecular C-N Bond Formation under the Auspices of Iodine(III)

Kilian Muniz

ACCOUNTS OF CHEMICAL RESEARCH (2018)

添加到收藏夹

Article Chemistry, Organic

Pd(II)-Catalyzed Asymmetric Oxidative 1,2-Diamination of Conjugated Dienes with Ureas

Min-Song Wu et al.

ORGANIC LETTERS (2018)

添加到收藏夹

Article Chemistry, Organic

Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines

Joseph B. Parry et al.

SYNLETT (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles

Kun Shen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic Asymmetric Diamination of Styrenes

Kilian Muniz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Organic

Pd(II)-Catalyzed Aerobic Intermolecular 1,2-Diamination of Conjugated Dienes: A Regio- and Chemoselective [4+2] Annulation for the Synthesis of Tetrahydroquinoxalines

Zhengxing Wu et al.

ORGANIC LETTERS (2017)

添加到收藏夹

Article Multidisciplinary Sciences

Metal-catalyzed electrochemical diazidation of alkenes

Niankai Fu et al.

SCIENCE (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Access to -Amino Acid Esters through Palladium-Catalyzed Oxidative Amination of Vinyl Ethers with Hydrogen Peroxide as the Oxidant and Oxygen Source

Lu Ouyang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Biochemistry & Molecular Biology

Synthetic approaches towards alkaloids bearing α-tertiary amines

Anastasia Hager et al.

NATURAL PRODUCT REPORTS (2016)

添加到收藏夹

Article Multidisciplinary Sciences

Practical olefin hydroamination with nitroarenes

Jinghan Gui et al.

SCIENCE (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalytic Diamination of Olefins via N-N Bond Activation

Yingguang Zhu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Vicinal Diamination of Alkenes under Rh-Catalysis

David E. Olson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Article Chemistry, Organic

Copper-Catalyzed Intermolecular Aminoazidation of Alkenes

Bo Zhang et al.

ORGANIC LETTERS (2014)

添加到收藏夹

Review Chemistry, Organic

Catalytic Asymmetric Electrophilic Amination Reactions To Form Nitrogen-Bearing Tetrasubstituted Carbon Stereocenters

Feng Zhou et al.

SYNTHESIS-STUTTGART (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Defined Hypervalent Iodine(III) Reagents Incorporating Transferable Nitrogen Groups: Nucleophilic Amination through Electrophilic Activation

Jose A. Souto et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper-Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

Hongwei Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonimide

Erica L. Ingalls et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

添加到收藏夹

Article Chemistry, Organic

Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes

Richard G. Cornwall et al.

ORGANIC LETTERS (2013)

添加到收藏夹

Article Chemistry, Organic

Oxidative Diamination Promoted by Dinuclear Iodine(III) Reagents

Caren Roeben et al.

ORGANIC LETTERS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Vicinal Difunctionalization of Internal Alkenes: Diastereoselective Synthesis of Diamines

Claudio Martinez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Article Chemistry, Organic

Methods for direct alkene diamination, new & old

Sam De Jong et al.

TETRAHEDRON (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Metal-free diamination of alkenes employing bromide catalysis

Patricia Chavez et al.

CHEMICAL SCIENCE (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Metal-Free Diamination of Styrenes

Caren Roeben et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Quaternary centres bearing nitrogen (alpha-tertiary amines) as products of molecular rearrangements

Jonathan Clayden et al.

CHEMICAL COMMUNICATIONS (2011)

添加到收藏夹

Article Chemistry, Medicinal

The Medicinal Chemist's Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

Stephen D. Roughley et al.

JOURNAL OF MEDICINAL CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species

Baoguo Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Article Chemistry, Organic

Complementary Regioselectivity in the Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamides

Richard G. Cornwall et al.

ORGANIC LETTERS (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

An Intermolecular Palladium-Catalyzed Diamination of Unactivated Alkenes

Alvaro Iglesias et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways

Baoguo Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Diamine ligands in copper-catalyzed reactions

David S. Surry et al.

CHEMICAL SCIENCE (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Transition-Metal-Catalyzed Diamination of Olefins

Renata Marcia de Figueiredo

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mechanism of N-Fluorobenzenesulfonimide Promoted Diamination and Carboamination Reactions: Divergent Reactivity of a Pd(IV) Species

Paul A. Sibbald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Metal-catalysed 1,2-diamination reactions

Francesca Cardona et al.

NATURE CHEMISTRY (2009)

添加到收藏夹

Review Chemistry, Multidisciplinary

Chiral tertiary diamines in asymmetric synthesis

Jean-Claude Kizirian

CHEMICAL REVIEWS (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Oxidative diamination of alkenes with ureas as nitrogen sources:: Mechanistic pathways in the presence of a high oxidation state palladium catalyst

Kilian Muniz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation

Haifeng Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic asymmetric diamination of conjugated dienes and triene

Haifeng Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Pd(0)-catalyzed diamination of terminal olefins at allylic and homoallylic carbons via formal C-H activation under solvent-free conditions

Haifeng Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes

Haifeng Du et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

添加到收藏夹

Review Chemistry, Organic

Asymmetric catalysis for the construction of quaternary carbon centres: nucleophilic addition on ketones and ketimines

Olivier Riant et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

Exploring the nickel-catalyzed oxidation of alkenes: A diamination by sulfamide transfer

Kilian Muniz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

添加到收藏夹

Review Biochemistry & Molecular Biology

Vicinal diamino functionalities as privileged structural elements in biologically active compounds and exploitation of their synthetic chemistry

SRSS Kotti et al.

CHEMICAL BIOLOGY & DRUG DESIGN (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: A dramatic effect of counteranions on reaction efficiency

LL Anderson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes

J Streuff et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper(II) acetate promoted intramolecular diamination of unactivated olefins

TP Zabawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes

GLJ Bar et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.