期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202300364
关键词
Cobalt catalysis; alkene diamination; & alpha;-tertiary amines; 1; 2-diamine
A commercially available cobalt complex Cp*Co-III(CO)I-2 has been discovered to efficiently catalyze the diamination of α-alkyl styrenes with anilines under mild reaction conditions, using dioxygen as the oxidant. This reaction exhibits a reasonably wide substrate scope of amines and good functional group tolerance. Preliminary mechanistic studies have indicated that Cp*Co-III(CO)I-2 alone can facilitate the diamination reaction.
A commercially available cobalt complex Cp*Co-III(CO)I-2 has been found to effectively catalyze the diamination of a-alkyl styrenes with anilines under a mild reaction condition, using dioxygen as the oxidant. This reaction features a reasonably good substrate scope of amines and a good functional group tolerance. Preliminary mechanistic studies have shown that Cp*Co-III(CO)I-2 alone can promote the diamination reaction.
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