相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。
Review
Nanoscience & Nanotechnology
Furkan H. Isikgor et al.
Summary: Metal-oxide-based charge-transport layers are crucial for the development of perovskite solar cells, but the metal-oxide/perovskite interfaces often have defects that hinder charge transfer and cause non-radiative recombination. This review explores the challenges associated with these interfaces and proposes solutions using molecular engineering, such as self-assembled monolayers, to improve their performance and commercial viability.
NATURE REVIEWS MATERIALS
(2023)
Editorial Material
Multidisciplinary Sciences
Mingliang Li et al.
Article
Chemistry, Multidisciplinary
Benfang Niu et al.
Summary: A simple and scalable interfacial strategy is reported to facilitate the assembly of high-performance inverted perovskite solar cells (PSCs) and scale-up modules. This strategy improves the chemical stability, charge extraction, and energy level alignment of the hole-selective interface, while promoting perovskite crystallization. As a result, the corresponding inverted PSCs and modules achieve remarkable power conversion efficiencies (PCEs) of 24.5% and 20.7% (aperture area of 19.4 cm(2)), respectively. This strategy is also effective for perovskite with various bandgaps, demonstrating the highest PCE of 19.6% for the 1.76-eV bandgap PSCs.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Leyu Bi et al.
Summary: In this study, the roles of chloride-based additives and methylammonium-based additives in inverted FAPbI3-based perovskite solar cells were systematically investigated. It was found that these additives have different effects on the crystallization and phase transition of FAPbI3. By optimizing the amount of MACl, the highest efficiency of inverted FAPbI3-based perovskite solar cells was achieved.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Minh Anh Truong et al.
Summary: Hole-collecting monolayers in perovskite solar cell research have gained attention for their easy processing, high performance, and good durability. This study utilized multiple phosphonic acid anchoring groups to control the molecular orientation, resulting in improved efficiency and stability of inverted perovskite solar cells.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Multidisciplinary Sciences
Rui He et al.
Summary: All-perovskite tandem solar cells exhibit high power conversion efficiency and low cost. The efficiency improvement in small-area tandem solar cells is driven by advances in low-bandgap perovskite bottom subcells. However, wide-bandgap perovskite top subcells still face issues, especially in large-area tandem solar cells. In this study, a self-assembled monolayer of (4-(7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid is developed as a hole-selective layer for wide-bandgap perovskite solar cells, which enables efficient hole extraction. By integrating this layer, a high efficiency monolithic all-perovskite tandem solar cell with a large area is achieved.
Article
Multidisciplinary Sciences
Jaewang Park et al.
Summary: Controlling the crystallinity and surface morphology of perovskite layers is crucial for achieving high-efficiency perovskite solar cells. By adding alkylammonium chlorides (RACl) to a-formamidinium lead iodide (FAPbI(3)), the crystallization process and surface morphology of the perovskite thin films can be controlled. The resulting perovskite thin layers facilitate the fabrication of perovskite solar cells with a high power-conversion efficiency of 26.08%.
Article
Optics
Fengzhu Li et al.
Summary: A multifunctional additive is used to modulate the kinetics of perovskite film growth, resulting in improved film quality and enhanced performance of perovskite solar cells. The additive enables the formation of large perovskite grains and coherent grain growth, which reduces non-radiative recombinations and boosts power conversion efficiency. The unencapsulated devices also exhibit improved thermal stability.
Article
Multidisciplinary Sciences
Shuo Zhang et al.
Summary: In this study, an amphiphilic molecular hole transporter with a multifunctional cyanovinyl phosphonic acid group was used to deposit a superwetting underlayer for perovskite deposition. This enabled the formation of high-quality perovskite films with minimized defects at the buried interface. The resulting perovskite film showed excellent photoluminescence properties and achieved a certified PCE of 25.4%, demonstrating its potential for application in solar cells.
Article
Chemistry, Physical
Asmat Ullah et al.
Summary: Recent advancements in perovskite solar cells have shown improvements in performance through enhanced interfacial engineering and charge selective contacts. A novel phenothiazine-based self-assembled monolayer has been introduced as a hole-selective contact, demonstrating significantly improved charge extraction/transport and device stability, leading to high power conversion efficiencies and exceptional operational stability.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xiang Deng et al.
Summary: This paper introduces a new method of using co-assembled monolayer (co-SAM) to achieve efficient hole selection and suppressed recombination in inverted perovskite solar cells (PSCs) by adjusting the position of substituents in the compound. By utilizing co-SAM, excellent performance and stability of the solar cells are achieved.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Multidisciplinary Sciences
K. O. Brinkmann et al.
Summary: Multijunction solar cells can surpass the efficiency limits of single-junction devices. Metal halide perovskite solar cells, in combination with silicon and copper indium gallium selenide (CIGS) or as all-perovskite tandems, have shown promising results. Narrow-gap non-fullerene acceptors have also significantly improved the efficiencies of organic solar cells. In this study, perovskite-organic tandem cells with high efficiency and voltage are demonstrated, utilizing optimized charge extraction layers and an ultrathin metal-like indium oxide layer for interconnection. This milestone work outperforms the best perovskite single junctions and is comparable to perovskite-CIGS and all-perovskite multijunctions.
Review
Chemistry, Multidisciplinary
Yiguo Yao et al.
Summary: This review systematically summarizes recent progress in using organic hole-transporting layers (HTLs) in inverted p-i-n perovskite solar cells (PSCs), including conductive polymers, small molecules, and self-assembled monolayers. The molecular structure, hole-transport properties, energy levels, and relevant device properties and performances of organic HTLs are analyzed. Design principles and future outlook for highly efficient organic HTLs in inverted PSCs are proposed, aiming to inspire further innovative development of novel organic HTLs for more efficient, stable, and scalable inverted PSCs.
ADVANCED MATERIALS
(2022)
Article
Energy & Fuels
Ludong Li et al.
Summary: Lightweight flexible perovskite solar cells have great potential for various applications, but their efficiency lags behind rigid solar cells. In this study, a self-assembled monolayer bridged hole-selective contact with reduced defects and improved bending durability was developed, resulting in a certified efficiency of 24.4% for flexible all-perovskite tandem solar cells.
Article
Chemistry, Multidisciplinary
Wenlin Jiang et al.
Summary: Carbazole-derived self-assembled monolayers show promise as hole-selective materials for inverted perovskite solar cells. However, their small dipoles limit their effectiveness in modulating the workfunction of the substrate. In this study, two new carbazole-derived SAMs were designed to improve the dipole moment and pi-pi interaction, leading to improved efficiency and stability in the PSC.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Multidisciplinary Sciences
Qi Jiang et al.
Summary: In this study, a reactive surface engineering approach was used to enhance the performance of perovskite solar cells with an inverted structure. The resulting p-i-n solar cells showed a high power conversion efficiency of over 25% and remained stable after long-term operation under extreme conditions.
Review
Energy & Fuels
Yuanyuan Zhou et al.
Summary: The emergence of perovskite photovoltaic technology has greatly advanced our understanding of metal halide perovskite thin-film microstructures and their effects on optoelectronic properties, device efficiency, and stability. This article discusses the morphological characteristics of three key microstructure types in perovskites, explores their impacts on performance and degradation, and calls for more research on hidden microstructures and high-spatiotemporal-resolution characterizations.
Article
Chemistry, Multidisciplinary
Fengzhu Li et al.
Summary: With the rapid industrialization, the demand for clean and renewable energy sources has been increasing. Photovoltaics (PV) has shown great potential in directly converting sunlight into electricity. Solution-processed thin-film solar cells, such as organic solar cells (OSCs) and organic-inorganic hybrid perovskite solar cells (PVSCs), have unique advantages over conventional PVs based on crystalline silicon. The design of interfaces plays a vital role in achieving high power conversion efficiency (PCE) and stability in PV devices. This Account provides an introduction to the fundamental roles of interfaces in PVs and discusses detailed analysis of interfaces and related surface science. Various interfacial materials with different functionalities are also highlighted, along with the challenges and future perspectives for the commercialization of solution-processed thin-film PVs.
ACCOUNTS OF MATERIALS RESEARCH
(2022)
Article
Multidisciplinary Sciences
Zhenghong Dai et al.
Summary: The use of iodine-terminated self-assembled monolayer (I-SAM) in perovskite solar cells (PSCs) leads to increased adhesion toughness at the interface, improved power conversion efficiency, reduced hysteresis, and enhanced operational stability. This is attributed to a decrease in hydroxyl groups at the interface and higher interfacial toughness achieved with I-SAM treatment.
Article
Chemistry, Physical
Igal Levine et al.
Summary: Identification of electronic processes at buried interfaces of charge selective contacts is crucial for photovoltaic and photocatalysis research. Transient surface photovoltage and photoluminescence provide complementary information on charge transfer kinetics and trapping/de-trapping mechanisms. Hole transfer rates and interface trap densities can be influenced by the chemical structure of SAMs, and high densities of interface traps can lead to significant losses in solar cells.
Article
Multidisciplinary Sciences
Bin Chen et al.
NATURE COMMUNICATIONS
(2020)
Article
Chemistry, Multidisciplinary
Bo Liu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Yang Wang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Fengzhu Li et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Review
Chemistry, Multidisciplinary
Christian M. Wolff et al.
ADVANCED MATERIALS
(2019)
Review
Chemistry, Multidisciplinary
Zewen Xiao et al.
ADVANCED MATERIALS
(2019)
Article
Chemistry, Multidisciplinary
Amran Al-Ashouri et al.
ENERGY & ENVIRONMENTAL SCIENCE
(2019)
Article
Chemistry, Physical
Artiom Magomedov et al.
ADVANCED ENERGY MATERIALS
(2018)
Article
Polymer Science
Ilin Sadeghi et al.
MACROMOLECULAR CHEMISTRY AND PHYSICS
(2017)
Article
Multidisciplinary Sciences
Nam Joong Jeon et al.
Review
Chemistry, Multidisciplinary
A. Sorrenti et al.
CHEMICAL SOCIETY REVIEWS
(2013)
Article
Chemistry, Physical
Onder Topel et al.
JOURNAL OF MOLECULAR LIQUIDS
(2013)
Article
Multidisciplinary Sciences
Samuel D. Stranks et al.
Article
Energy & Fuels
Wenying Li et al.
Article
Chemistry, Physical
Zujin Zhao et al.
JOURNAL OF MATERIALS CHEMISTRY
(2012)
