4.8 Article

Zinc-Ion and Proton as Joint Charge Carriers of S-MoO2 for High-Capacity Aqueous Zinc-Ion Batteries

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Amorphization Boost Multi-Ions Storage for High-Performance Aqueous Batteries

Bowen Jin et al.

Summary: This study reports an amorphization strategy to increase the cation-ion storage capacity of anode materials, where the capacity of amorphous MoOx is more than four times that of crystalline MoOx in monovalent, divalent, and even trivalent aqueous electrolytes. Experimental and theoretical calculations reveal the generation of ample active sites and isotropic ions in the amorphous phase, which facilitates cation migration within the electrode bulk. Amorphous MoOx can be coupled with multi-ion storage cathodes to achieve high energy and power densities in electrochemical energy storage devices.

ADVANCED FUNCTIONAL MATERIALS (2023)

Review Chemistry, Multidisciplinary

Aqueous Organic Batteries Using the Proton as a Charge Carrier

Mangmang Shi et al.

Summary: Aqueous rechargeable batteries with low cost, nonflammability, and high operational safety have emerged as promising candidates for large-scale energy-storage applications. Proton batteries, using the proton as a charge carrier, exhibit a salient rate capability, a long-term life span, and an excellent low-temperature electrochemical performance. The use of organic materials as electrode materials in proton batteries is significant, and this research article provides a comprehensive summary and evaluation of the latest research progress and performance of organic electrodes in proton batteries.

ADVANCED MATERIALS (2023)

Article Chemistry, Physical

The high-performance MoO3-x/MXene cathodes for zinc-ion batteries based on oxygen vacancies and electrolyte engineering

Junjie Shi et al.

Summary: The study introduces Ti3C2Tx MXenes with a two-dimensional (2D) layered structure and hydrophobic trifluoromethane sulfonate (OTf-) into AZIBs to address the low conductivity and poor stability issues of MoO3, resulting in exceptional high capacity and cycling life performance.

NANO ENERGY (2022)

Article Electrochemistry

High zinc-ion intercalation reaction activity of MoS2 cathode based on regulation of thermodynamic metastability and interlayer water

Li Liu et al.

Summary: In this study, the electrochemical activity of cathode materials in aqueous zinc-ion batteries was improved by inserting a monolayer of water in 1T-MoS2 nanosheets. The interlayer water not only expanded the interlayer spacing, but also maintained the metastable structure of 1T-MoS2, reducing the activation energy for Zn2+ intercalation and enhancing the specific capacity.

ELECTROCHIMICA ACTA (2022)

Article Chemistry, Physical

Uncovering sulfur doping effect in MnO2 nanosheets as an efficient cathode for aqueous zinc ion battery

Yajun Zhao et al.

Summary: This study proposes sulfur doped MnO2 nanosheets as a high-performance cathode material for zinc-ion batteries, exhibiting large discharge capacity, high rate performance, and long cycle life. The incorporation of sulfur improves the intrinsic electronic conductivity of MnO2 and accelerates reaction kinetics by weakening the electrostatic interactions with Zn(2+) cations. The sulfur doping also induces an amorphous surface with abundant oxygen defects, contributing to additional Zn storage sites with pseudocapacitive behavior.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Multidisciplinary

A Volume Self-Regulation MoS2 Superstructure Cathode for Stable and High Mass-Loaded Zn-Ion Storage

Zeying Yao et al.

Summary: This paper presents the design of a multifunctional superlattice cathode structure, MoS2/C(19)H(4)2N(+) (CTAB), which overcomes the problems of slow kinetics and large volume changes associated with zinc-ion batteries. The cathode incorporates soft organic CTAB into a rigid MoS2 host, enabling efficient transport of Zn2+ and structural stability. This optimized superlattice cathode exhibits high-rate performance, long-term cycling stability, and flexibility in a pouch cell, making it a promising candidate for practical applications.

ACS NANO (2022)

Article Chemistry, Multidisciplinary

Activated Proton Storage in Molybdenum Selenide through Electronegativity Regulation

Xingyu Zhao et al.

Summary: This study presents a simple method to enhance the specific capacity of MoSe2 by incorporating oxygen. Experimental results show that oxygen-incorporated MoSe2 undergoes proton-dominated insertion electrochemistry during cycling. Theoretical calculations demonstrate that the introduction of oxygen effectively reduces the binding energy of adsorbing H+ and modifies charge distribution in the interlayer, promoting H+ adsorption and diffusion, and thus significantly increasing the specific capacity of MoSe2. This study provides an effective strategy to improve the kinetics of TMDs and achieve high-performance aqueous zinc-based batteries.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Eliminating the Micropore Confinement Effect of Carbonaceous Electrodes for Promoting Zn-Ion Storage Capability

Li Wang et al.

Summary: By effectively enhancing the Zn2+ storage capability of activated nitrogen-doped hierarchical porous carbon materials, the micropore confinement effect was eliminated and the utilization of active sites was increased, leading to impressive electrochemical properties. The novel ANHPC-2 exhibits excellent capacity, energy density, and durability for ZICs, indicating promising potential for practical applications.

ADVANCED MATERIALS (2022)

Article Materials Science, Multidisciplinary

Metal-organic framework derived porous cathode materials for hybrid zinc ion capacitor

Ying Liu et al.

RARE METALS (2022)

Review Nanoscience & Nanotechnology

Electrochemical Proton Storage: From Fundamental Understanding to Materials to Devices

Tiezhu Xu et al.

Summary: This article reviews the research progress on electrode materials for electrochemical proton storage, aiming to improve the energy density and power density of electrochemical energy storage systems. By utilizing the high capacity and rapid kinetics of electrochemical proton storage, the power limit of batteries and the energy limit of capacitors can be overcome. Different charge storage mechanisms, such as surface redox, intercalation, and conversion materials, are classified and introduced in detail, with a focus on the influence of crystal water and other nanostructures on proton migration kinetics. Advanced full cell devices are also summarized to promote the commercialization of electrochemical proton storage. Finally, this review provides a framework for research directions, material structure design principles, and goals of practical application for electrochemical proton storage.

NANO-MICRO LETTERS (2022)

Article Chemistry, Physical

Drastically-enlarged interlayer-spacing MoS2 nanocages by inserted carbon motifs as high performance cathodes for aqueous zinc-ion batteries

Changwei Li et al.

Summary: This study introduces N-doped carbon motifs between the layers of MoS2 to create enlarged MoS2 nanocages with increased interlayer spacing. This novel material exhibits excellent high rate performance and cycling stability when used as the cathode in aqueous zinc ion batteries. Additionally, quasi-solid batteries based on this cathode show excellent electrochemical performance under different bending conditions.

ENERGY STORAGE MATERIALS (2022)

Article Chemistry, Multidisciplinary

Sodium-Intercalated Manganese Oxides for Achieving Ultra-Stable and Fast Charge Storage Kinetics in Wide-Voltage Aqueous Supercapacitors

Zhongyou Peng et al.

Summary: In this study, nanostructured sodium-intercalated manganese oxides (NMOx) with modulated oxygen defects were fabricated, which exhibited good structural stability and fast ion diffusion ability, and the capacitive charge storage mechanism was governed by interlayer cation intercalation and deintercalation. Furthermore, a horizontally oriented carbon nanotube microfilm was reported as the electrode material for aqueous asymmetric supercapacitors (ASCs), achieving high energy density and excellent cycle performance. A flexible planar ASC with landmark volumetric energy/power densities and excellent mechanical flexibility was also prepared.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Unveiling the Proton Lubricant Chemistry in Aqueous Zinc-MoS2 Batteries

Shengwei Li et al.

Summary: In this study, highly efficient and reversible H+/Zn2+ co-insertion/extraction behaviors were successfully demonstrated in aqueous Zn-MoS2 batteries by innovatively preparing a MoS2/PEDOT hybrid. The co-inserted protons act as lubricants to enhance ion-diffusion kinetics and rate performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Article Materials Science, Multidisciplinary

Deciphering H+/Zn2+ co-intercalation mechanism of MOF-derived 2D MnO/C cathode for long cycle life aqueous zinc-ion batteries

Zheng-Xiang Zhu et al.

Summary: In this study, a two-dimensional MnO/C composite derived from MOF was prepared and demonstrated to exhibit high cyclic stability and capacity retention at different current densities, providing a new approach for the development of high-performance AZIBs cathode with controllable morphology.

RARE METALS (2022)

Article Chemistry, Physical

Tailoring layered transition metal compounds for high-performance aqueous zinc-ion batteries

Quan Zong et al.

Summary: The development of cathodes is crucial for high-performance aqueous Zn-ion batteries. Layered transition metal compounds have shown potential but face challenges such as slow desolvation process and strong electrostatic interaction. This review comprehensively examines the progress and challenges in using layered transition metal compounds as cathodes for ZIBs and discusses different materials and storage mechanisms.

ENERGY STORAGE MATERIALS (2022)

Article Engineering, Chemical

Effect of homojunction structure in boosting sodium-ion storage: The case of MoO2

Sheng Li et al.

Journal of Energy Chemistry (2022)

Article Materials Science, Multidisciplinary

Oxygen vacancies and N-doping in organic-inorganic pre-intercalated vanadium oxide for high-performance aqueous zinc-ion batteries

Feng Zhang et al.

Summary: Metal ion pre-intercalation into vanadium oxide is an effective strategy for optimizing the performance of rechargeable zinc-ion battery (ZIB) cathodes. However, improving the battery's long lifespan and high-capacity retention remains a challenge. This study introduces N-doped vanadium oxide as a cathode material for aqueous ZIBs, showing enhanced electronic conductivity and accelerated diffusion kinetics of zinc ions, leading to excellent electrochemical performance and long cycle life.

INFOMAT (2022)

Review Electrochemistry

Defect engineering in molybdenum-based electrode materials for energy storage

Weixiao Wang et al.

Summary: This article systematically reviews recent progress in defect engineering for molybdenum-based electrode materials, including vacancy modulation, doping engineering, topochemical substitution, and amorphization. The essential optimization mechanisms of defect engineering in molybdenum-based electrode materials, as well as the existing challenges and future objectives for high-energy and high-power energy storage devices, are discussed.

ESCIENCE (2022)

Article Chemistry, Multidisciplinary

Interlayer Engineering of α-MoO3 Modulates Selective Hydronium Intercalation in Neutral Aqueous Electrolyte

Haozhe Zhang et al.

Summary: This study demonstrates the selective H3O+ intercalation in a neutral ZnCl2 electrolyte for water-proton co-intercalated alpha-MoO3 (WP-MoO3), which shows significantly enhanced specific capacity, rate capability, and cycling stability compared to the Zn2+ intercalation mechanism. This work highlights the possibility of modulating electrochemical intercalating ions through interlayer engineering to construct high-rate and long-life electrodes for aqueous batteries.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Sandwich-Like Heterostructures of MoS2/Graphene with Enlarged Interlayer Spacing and Enhanced Hydrophilicity as High-Performance Cathodes for Aqueous Zinc-Ion Batteries

Shengwei Li et al.

Summary: The research successfully increased the MoS2 interlayer spacing and enhanced hydrophilicity by innovatively intercalating graphene into MoS2 layers, forming MoS2/graphene nanocomposites with flower-like structures. These composites showed exceptional high-rate capability and long-term cycling stability, paving a new direction for high-performance cathodes in aqueous zinc-ion batteries.

ADVANCED MATERIALS (2021)

Review Chemistry, Multidisciplinary

Advances and Perspectives of Cathode Storage Chemistry in Aqueous Zinc-Ion Batteries

Xiao Wang et al.

Summary: This review discusses the key challenges of rechargeable aqueous zinc-ion batteries, analyzing the structural features and electrochemical properties of different cathode materials, and proposing various electrode design strategies to guide future research activities. The focus is mainly on achieving high energy density and durable cathode materials.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

In Situ Carbon Insertion in Laminated Molybdenum Dioxide by Interlayer Engineering Toward Ultrastable Rocking-Chair Zinc-Ion Batteries

Bo Wang et al.

Summary: By incorporating carbon layers into MoO2 materials, the structural integrity and electrochemical performance of aqueous zinc-ion batteries have been enhanced, resulting in excellent cycling stability and rate capability.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Physical

Toward fast zinc-ion storage of MoS2 by tunable pseudocapacitance

Meihong Huang et al.

Summary: A hierarchical hybrid of MoS2 nanosheets with 86% of 1T phase grown on reduced graphene oxide scaffolds is proposed as a superior cathode material for aqueous rechargeable zinc ion batteries. The incorporation of reduced graphene oxide effectively stabilizes the 1T phase and reduces electron transfer resistance, resulting in high discharge capacity and excellent cycling performance. This study sheds light on the rational design of MoS2 nanoscale architecture for superior cathode materials in divalent/multivalent aqueous batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

Alkali Ions Pre-Intercalated Layered MnO2 Nanosheet for Zinc-Ions Storage

Liyuan Liu et al.

Summary: By pre-intercalating alkali ions and water crystals into layered delta-MnO2, ultra-thin nanosheets of K0.27MnO2∙0.54H2O (KMO) and Na0.55Mn2O4∙1.5H2O were prepared, which act as pillars to stabilize the structures and enable rapid cation diffusion in the KMO structure, leading to high power capability and good cycling stability. The charge storage mechanism of KMO in an aqueous Zn-ion battery involves (de)intercalation of H3O+ with further dissolution-precipitation of Zn-4(OH)6(SO4)∙5H2O solid product on the KMO surface, as revealed by electrochemical quartz crystal microbalance measurements and in-operando X-ray diffraction techniques.

ADVANCED ENERGY MATERIALS (2021)

Article Electrochemistry

High-performance Zn battery with transition metal ions co-regulated electrolytic MnO2

Mingyan Chuai et al.

Summary: Electrolytic MnO2/Zn batteries co-regulated with transition metal ions show improved electrochemical performance in terms of deposition and stripping chemistries, with the incorporation of Co and Ni leading to more active electron states, faster charge-transfer kinetics, and better electrical conductivity. This approach offers a versatile strategy for enhancing the performance of aqueous electrolytic MnO2/Zn batteries in large-scale energy storage applications.

ESCIENCE (2021)

Review Multidisciplinary Sciences

Roadmap for advanced aqueous batteries: From design of materials to applications

Dongliang Chao et al.

SCIENCE ADVANCES (2020)

Article Engineering, Environmental

Boosting aqueous zinc-ion storage in MoS2 via controllable phase

Jiapeng Liu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Chemistry, Multidisciplinary

A High Performing Zn-Ion Battery Cathode Enabled by In Situ Transformation of V2O5Atomic Layers

Yanying Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Materials Science, Multidisciplinary

Recent progress of molybdenum-based materials in aqueous rechargeable batteries

J. Xie et al.

MATERIALS TODAY ADVANCES (2020)

Review Chemistry, Multidisciplinary

Preintercalation Strategy in Manganese Oxides for Electrochemical Energy Storage: Review and Prospects

Qinghe Zhao et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Aqueous Zinc-Ion Storage in MoS2 by Tuning the Intercalation Energy

Hanfeng Liang et al.

NANO LETTERS (2019)

Article Energy & Fuels

Building aqueous K-ion batteries for energy storage

Liwei Jiang et al.

NATURE ENERGY (2019)

Article Chemistry, Multidisciplinary

Joint Charge Storage for High-Rate Aqueous Zinc-Manganese Dioxide Batteries

Yan Jin et al.

ADVANCED MATERIALS (2019)

Article Chemistry, Physical

MoS2 nanosheets with expanded interlayer spacing for rechargeable aqueous Zn-ion batteries

Hongfei Li et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Physical

Defect engineering activating (Boosting) zinc storage capacity of MoS2

Wangwang Xu et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Multidisciplinary

Self-Supported Nanotube Arrays of Sulfur-Doped TiO2 Enabling Ultrastable and Robust Sodium Storage

Jiangfeng Ni et al.

ADVANCED MATERIALS (2016)

Article Chemistry, Multidisciplinary

Core-Shell Nanostructured Black Rutile Titania as Excellent Catalyst for Hydrogen Production Enhanced by Sulfur Doping

Chongyin Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Physical

Sulfur-doped highly ordered TiO2 nanotubular arrays with visible light response

Xinhu Tang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2008)

Article Multidisciplinary Sciences

Visible-light photocatalysis in nitrogen-doped titanium oxides

R Asahi et al.

SCIENCE (2001)