☆ 4.8 Review

Green Synthesis of Reticular Materials

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Engineering, Environmental

Room temperature synthesis of monolithic MIL-100(Fe) in aqueous solution for energy-efficient removal and recovery of aromatic volatile organic compounds

Xianming Zheng et al.

Summary: This study reports a green method for the room temperature synthesis of a stable Fe-based MOF monolith using water as the solvent. The optimized monolith exhibits high porosity and mechanical strength, and shows excellent adsorption performance for aromatic VOCs. It can also be rapidly regenerated at lower temperature.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Chemistry, Multidisciplinary

A biodegradable covalent organic framework for synergistic tumor therapy

Wen-Yan Li et al.

Summary: Stimulus-responsive biodegradable nanocarriers based on a redox-responsive disulfide-linked porphyrin covalent organic framework (COF) were developed for tumor-selective targeted drug delivery. The nanoscale COF-based multifunctional nanoagent could be effectively dissociated by endogenous glutathione (GSH) in tumor cells, achieving selective chemotherapy and enhancing photodynamic therapy (PDT) for breast cancer. The therapeutic efficacy was significantly improved by responding to the high concentrations of GSH in the tumor microenvironment (TME).

CHEMICAL SCIENCE (2023)

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Article Chemistry, Multidisciplinary

Structure Control Using Bioderived Solvents in Electrochemical Metal-Organic Framework Synthesis

Meha Bhindi et al.

Summary: Electrochemical synthesis of metal-organic frameworks (MOFs) offers environmental advantages compared to traditional methods, but the use of toxic solvents like DMF poses challenges. This study investigates the use of bioderived solvents Cyrene(TM) and GVL as an alternative for MOF synthesis. Results show that Cyrene(TM) and GVL solvents can produce crystalline MOFs comparable to those obtained with DMF, but may also lead to less stable, higher porosity structures. This study demonstrates the first electrochemical synthesis of MOFs using bio solvents and highlights the potential for obtaining unique MOF phases.

APPLIED SCIENCES-BASEL (2023)

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Review Chemistry, Multidisciplinary

Advancing mechanochemical synthesis by combining milling with different energy sources

Valentina Martinez et al.

Summary: Mechanochemical processing is an efficient and unique tool for the synthesis and transformation of various materials. Recent advancements combine mechanochemical reactivity with other energy sources, achieving reactions not possible with traditional methods. Thermo-mechanochemistry, sono-mechanochemistry, electro-mechanochemistry, and photo-mechanochemistry represent significant advances in modern mechanochemistry, introducing a new level of solid-state reactivity.

NATURE REVIEWS CHEMISTRY (2023)

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Article Materials Science, Multidisciplinary

Plasmonically Active Supramolecular Polymer-Metal-Organic Framework Hydrogel Nanocomposite for Localized Chemo- photothermal Therapy

Navneet Kaur et al.

Summary: Researchers developed an injectable plasmonic hydrogel by cross-linking carboxymethyl chitosan (CMC) with ZIF8 nanoparticles and Mg2+. The hydrogel exhibited viscoelastic and self-healing properties, and could release ultrasmall gold nanoparticles (UsGNPs) and an anticancer drug curcumin for localized chemo-photothermal therapy. The photothermal conversion efficiency of the hydrogel was over 41%, and it effectively inhibited breast cancer growth in both in vitro and in vivo experiments.

ACS APPLIED POLYMER MATERIALS (2023)

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Review Electrochemistry

Conductive Metal-Organic Frameworks for Rechargeable Lithium Batteries

Fengjun Deng et al.

Summary: Rechargeable lithium batteries, despite being representative of high-energy-density battery systems, face various problems that hinder their development. Metal-organic frameworks (MOFs), with their specific surface areas and pore structures, have recently attracted attention in energy-related applications. The insulating nature of traditional MOFs has limited their use in electrochemistry energy storage, but recent developments in electron- and proton-conductive MOFs (c-MOFs) have overcome this limitation. This review explores the use of c-MOFs in rechargeable lithium batteries and discusses their preparation methods, conductive mechanisms, and research progress, highlighting the challenges and opportunities in the field of electrochemical energy storage and conversion.

BATTERIES-BASEL (2023)

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Review Chemistry, Multidisciplinary

Three-Dimensional Covalent Organic Frameworks: From Synthesis to Applications

Xinyu Guan et al.

Summary: Three-dimensional covalent organic frameworks (3D COFs) with spatially periodic networks have significant advantages over their 2D counterparts, such as larger specific surface areas, interconnected channels, and more exposed active sites. However, the research on these materials faces challenges in crystallization and stability, which need to be addressed for practical applications. In this Minireview, strategies for preparing functional 3D COFs, including crystallization techniques and functionalization methods, are summarized. Applications of these functional materials in adsorption, separation, catalysis, fluorescence, sensing, and batteries are presented. Finally, the future challenges and perspectives for the development of 3D COFs are discussed.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

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Review Chemistry, Physical

Monolithic Covalent Organic Frameworks with Hierarchical Architecture: Attractive Platform for Contaminant Remediation

Lijin Huang et al.

Summary: To address the insolubility and poor processability of powder covalent organic frameworks (COFs), monolithic COFs with hierarchical structures have been constructed as a feasible and effective solution. This review provides a comprehensive summary of the recent advances in the synthesis of monolithic COF materials and their application in environmental remediation, as well as discussing current challenges and future perspectives.

CHEMISTRY OF MATERIALS (2023)

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Article Green & Sustainable Science & Technology

Environmental impact analysis of surface printing and 3D inkjet printing applications using an imine based covalent organic framework: A life cycle assessment study

Juan J. Espada et al.

Summary: This study aims to assess the environmental impact of using an imine-based covalent organic framework (RT-COF-1) for surface printing (Case A) and 3D inkjet printing (Case B) through life cycle assessment (LCA) methodology. The results show that monomer synthesis is the main contributor to environmental impacts in both cases, and solvents used in Case A also have a significant contribution. Case B has lower environmental impacts compared to Case A. Furthermore, RT-COF-1 compares favorably with polymerizable ionic liquids (PILs) in terms of environmental performance for 3D printing.

JOURNAL OF CLEANER PRODUCTION (2023)

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Article Green & Sustainable Science & Technology

The global warming potential and the material utility of PET and bio-based PEF bottles over multiple recycling trips

Paul Stegmann et al.

Summary: Biomass use and recycling can help reduce greenhouse gas emissions in the plastics industry. Polyethylene furanoate (PEF), a bio-based plastic, shows promise as an alternative to polyethylene terephthalate (PET) for small bottle applications. Life cycle assessments were conducted in the Netherlands, comparing the global warming potential (GWP) of PET and PEF bottles through multiple mechanical and chemical recycling trips. Results showed that after one recycling trip, bio-based PEF had 50-74% lower GWP compared to PET, depending on the waste management scenario. The study also highlighted the importance of deposit-based recycling systems in reducing overall GHG emissions for both bottle types.

JOURNAL OF CLEANER PRODUCTION (2023)

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Article Biochemical Research Methods

High-yield, green and scalable methods for producing MOF-303 for water harvesting from desert air

Zhiling Zheng et al.

Summary: This article presents a detailed protocol for the green, water-based preparation of MOF-303 on both gram and kilogram scales, showing high yield and quality. It also demonstrates that the synthetic procedure can produce MOF within a short period of time.

NATURE PROTOCOLS (2023)

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Review Chemistry, Inorganic & Nuclear

Metal-organic framework nanoshell structures: Preparation and biomedical applications

Jia Tang et al.

Summary: The combination of metal-organic frameworks (MOFs) and nanoshells has great potential in biomedical applications. MOF nanoshells, including hollow-shells, core-shells, and yolk-shells, possess the advantages of MOFs and nanoshells, making them ideal materials for biomedicine. The incorporation of functional nanoparticles or chemotherapeutic molecules with MOF nanoshells enables multi-component synergy. This review article introduces the synthesis strategies for various MOF nanoshells and explores their applications in drug delivery, biosensing, bioimaging, and cancer therapy.

COORDINATION CHEMISTRY REVIEWS (2023)

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Review Chemistry, Multidisciplinary

Synthesis, characterization, and activation of metal organic frameworks (MOFs) for the removal of emerging organic contaminants through the adsorption-oriented process: A review

Olaniran K. Akeremale et al.

Summary: Water is essential for life, but increasing human activities are releasing various pollutants into water bodies, posing a serious challenge. These emerging organic contaminants, including synthesized compounds and newly discovered pollutants such as dyes, pesticides, pharmaceutical products, etc., are of great concern as they harm the ecosystem and human health. Among various remediation techniques, adsorption using metal organic frameworks has been identified as the most promising due to its ease of operation and cost efficiency. This study aims to explore the removal of these contaminants from water through adsorption using metal organic frameworks.

RESULTS IN CHEMISTRY (2023)

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Review Chemistry, Multidisciplinary

A Review on Mechanochemistry: Approaching Advanced Energy Materials with Greener Force

Xingang Liu et al.

Summary: Solvent-free and environmentally friendly mechanochemistry is a promising alternative to traditional liquid-phase reactions, utilizing mechanical energy to promote chemical transformations and design complex molecules and nanostructured materials, accelerating reaction rates and efficiencies. This review discusses the latest advances in mechanochemistry for energy materials preparation and modification, and proposes next-generation advanced energy materials.

ADVANCED MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Time-Resolved In Situ Monitoring of Mechanochemical Reactions

Adam A. L. Michalchuk et al.

Summary: Mechanochemical transformations offer environmentally friendly routes for synthesis, increasing reaction speed and selectivity. Time-resolved in situ (TRIS) approaches have provided new insights into mechanochemical reactions, revealing new features and advancing our understanding through the combination of complementary techniques.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Watching Microwave-Induced Microscopic Hot Spots via the Thermosensitive Fluorescence of Europium/Terbium Mixed-Metal Organic Complexes

Zhenyu Zhao et al.

Summary: The study utilized Eu/Tb mixed-metal organic complexes as nano thermometers to probe the intrinsic temperature of MW-absorbing particles in MW fields, and derived an MW-irradiated energy transfer model to predict the extent of microscopic hot spots. The results show that the MW-induced temperature gradient can be enlarged by increasing MW intensity, dielectric loss, and particle size, while lowered by the increase in thermal conductivity and dielectric loss of the liquid.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Geomimetic Hydrothermal Synthesis of Polyimide-Based Covalent Organic Frameworks

Taehyung Kim et al.

Summary: In this study, highly crystalline PICs with various pore dimensions were successfully synthesized under geomimetic hydrothermal conditions. The solubility of the oligomeric intermediates under hydrothermal conditions was found to affect the stacking structures of the crystalline PICs. Additionally, the synthesized PICs show promising potential as an anode material in lithium-ion batteries due to their unique redox-active properties and high surface area.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Review Chemistry, Multidisciplinary

Toxicity of metal-organic framework nanoparticles: from essential analyses to potential applications

Romy Ettlinger et al.

Summary: The field of metal-organic frameworks (MOFs), particularly MOF nanoparticles, has seen significant growth in the last two decades. This tutorial review emphasizes the importance of systematic toxicity assessment and discusses the current state of in vitro and in vivo toxicity studies of MOF nanoparticles, as well as the key factors affecting their toxicity.

CHEMICAL SOCIETY REVIEWS (2022)

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Article Chemistry, Physical

Direct and Linker-Exchange Alcohol-Assisted Hydrothermal Synthesis of Imide-Linked Covalent Organic Frameworks

Johannes Maschita et al.

Summary: Covalent organic frameworks (COFs) are a special type of porous materials, and a new environmentally friendly strategy - alcohol-assisted hydrothermal polymerization approach (aaHTP) can be used to synthesize stable and crystalline COFs, avoiding the use of toxic solvents.

CHEMISTRY OF MATERIALS (2022)

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Article Chemistry, Physical

Surfactant-free synthesis of covalent organic framework nanospheres in water at room temperature

Jia He et al.

Summary: Covalent organic frameworks (COFs) are a new class of porous materials with unique characteristics. This study introduces a surfactant-free method to synthesize COF nanomaterial in water, allowing for control over the morphology and size of COFs. The use of tiny amounts of co-solvents ensures stability of COF nanomaterials in aqueous solution, and water plays a crucial role in size adjustment of COFs.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

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Review Chemistry, Physical

Heterostructured hybrids of metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs)

Chuanpan Guo et al.

Summary: Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) possess ordered crystalline structures and superior performance, combining them into one system can generate hybrid nanomaterials with better performance. MOF/COF heterostructures exhibit excellent properties due to the synergistic effects of components, showing a wide range of potential applications.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Green & Sustainable Science & Technology

Environmental Impacts of Aqueous Zinc Ion Batteries Based on Life Cycle Assessment

Maider Iturrondobeitia et al.

Summary: Aqueous zinc ion batteries (AZIBs) are gaining attention for their safety and potential environmental sustainability, showing promise as a sustainable stationary energy storage solution. Research indicates that AZIBs have high environmental competitiveness and attractiveness from a Circular Economy perspective.

ADVANCED SUSTAINABLE SYSTEMS (2022)

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Article Green & Sustainable Science & Technology

Ecodesign coupled with Life Cycle Assessment to reduce the environmental impacts of an industrial enzymatic cleaner

Rocio Lopez de Lapuente Diaz de Otazu et al.

Summary: The study focused on the environmental impacts of enzymatic multipurpose cleaner throughout its life cycle, proposing five ecodesigned scenarios to reduce the overall environmental footprint. Among these scenarios, increasing packaging volume was found to be the most effective choice.

SUSTAINABLE PRODUCTION AND CONSUMPTION (2022)

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Review Chemistry, Multidisciplinary

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

Stipe Lukin et al.

Summary: In the past two decades, mechanochemistry has experienced rapid development and has been applied to various areas of chemical and materials synthesis. The recent introduction of real-time in situ monitoring techniques has revolutionized the study of mechanochemical reactions, leading to significant advancements in understanding reaction mechanisms and identifying new molecules and materials that were previously unknown.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

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Article Chemistry, Multidisciplinary

Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production

Wei Zhao et al.

Summary: A high-throughput sonochemical synthesis and testing strategy was developed to discover covalent organic frameworks (COFs) for photocatalysis. Among the screened COFs, one showed excellent photocatalytic activity for hydrogen peroxide production, but its activity decreased after long-term testing. The introduction of a two-phase catalytic system greatly enhanced its photostability.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Green & Sustainable Science & Technology

Recent progress of industrial preparation of metal-organic frameworks: synthesis strategies and outlook

Qingqing He et al.

Summary: This article reviews the scalable and sustainable manufacturing aspects of metal-organic frameworks (MOFs). While MOFs have broad application prospects, their industrial adoption has been slow due to lack of scalable manufacturing methods and high costs. The article discusses the key points for achieving industrial production of MOFs and proposes scalable and sustainable production methods for material preparation.

MATERIALS TODAY SUSTAINABILITY (2022)

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Article Chemistry, Applied

Room temperature aqueous synthesis of Ce(IV)-MOFs with UiO-66 architecture and their photocatalytic decarboxylative oxygenation of arylacetic acids

Hong-Guang Jin et al.

Summary: Cerium(IV)-based metal-organic frameworks (MOFs) have gained attention due to their potential in redox catalysis and photocatalysis, but the synthetic pathways are mainly solvothermal. Research on photocatalysis of Ce(IV)-MOFs is still in its early stages. We have developed a sustainable and green synthetic route for nanocrystalline Ce(IV)-MOFs with the UiO-66 structure. These MOFs showed promising photocatalytic activity for the decarboxylative oxygenation under blue light-emitting diodes (LEDs) irradiation and air.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

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Article Multidisciplinary Sciences

A cellulose-derived supramolecule for fast ion transport

Qi Dong et al.

Summary: In this study, a scalable and cost-effective synthesis method is reported for cellulose-derived supramolecules with high ionic conductivity and potential applications.

SCIENCE ADVANCES (2022)

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Article Chemistry, Multidisciplinary

Using genetic algorithms to systematically improve the synthesis conditions of Al-PMOF

Nency P. Domingues et al.

Summary: In this study, a joint machine learning and experimental approach is used to optimize the synthesis conditions of Al-PMOF, resulting in improved yield and crystallinity. The most important experimental variables that determine the outcome are identified through analysis of failed and partially successful experiments.

COMMUNICATIONS CHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

Fast Room-Temperature Synthesis of an Extremely Alkaline-Resistant Cationic Metal-Organic Framework for Sequestering TcO4- with Exceptional Selectivity

Kang Kang et al.

Summary: A cationic MOF (Ag-TPPE) with high selectivity for removing TcO4- has been rapidly synthesized at room temperature through mixing, stirring, or sonication. It exhibits exceptional removal rate for TcO4- in waste streams, overcoming the drawback of overused sorbent.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Physical

Biomimetic Mineralization of Iron-Fumarate Nanoparticles for Protective Encapsulation and Intracellular Delivery of Proteins

Negar Mirzazadeh Dizaji et al.

Summary: Biomimetic mineralization of proteins and nucleic acids into hybrid metal-organic nanoparticles allows for protection and cellular delivery of these biomolecules. In this study, amorphous iron-fumarate nanoparticles were synthesized under mild acidic conditions in water to encapsulate various proteins and ribonucleoproteins. The resulting nanoparticles preserved the activity of the biomolecules and successfully delivered them into cells, even under challenging conditions.

CHEMISTRY OF MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Methods for Monitoring Milling Reactions and Mechanistic Studies of Mechanochemistry: A Primer

Patrick Julien et al.

Summary: Mechanochemistry by ball milling is an important research field that aims to minimize the use of solvents and energy while understanding the mechanisms and pathways of solid-state molecular and materials transformations. Recent developments in monitoring techniques have greatly contributed to our understanding of mechanochemical reactions and have the potential to accelerate reaction development and enhance our knowledge of solid-state chemistry.

CRYSTAL GROWTH & DESIGN (2022)

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Article Green & Sustainable Science & Technology

Comparative life cycle assessment on zeolitic imidazolate framework-8 (ZIF-8) production for CO2 capture

Wenhao Xia et al.

Summary: This study investigated the environmental impacts of different synthesis methods for ZIF-8 through life cycle assessment (LCA), with a focus on the contribution of solvents. The findings showed that replacing the solvent DMF with methanol could significantly reduce the impact on human health, ecosystem, and resources. The mechanochemical method had the least environmental impact due to its simplicity and fewer production steps.

JOURNAL OF CLEANER PRODUCTION (2022)

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Article Chemistry, Multidisciplinary

Biodegradable Redox-Responsive AIEgen-Based-Covalent Organic Framework Nanocarriers for Long-Term Treatment of Myocardial Ischemia/Reperfusion Injury

Chenguang Huang et al.

Summary: A nanocarrier has been developed to protect against myocardial ischemia/reperfusion (MI/R) injury by reducing cardiomyocyte apoptosis and improving cardiac function. The carrier efficiently delivers an anti-cryptosporidial drug and significantly reduces MI/R-induced functional deterioration and cardiomyocyte injury in experimental models.

SMALL (2022)

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Article Chemistry, Multidisciplinary

Environmental Impact Assessment of Chitin Nanofibril and Nanocrystal Isolation from Fungi, Shrimp Shells, and Crab Shells

Maria Berroci et al.

Summary: Chitin nanoparticles, responsible for the excellent mechanical properties of crustacean exoskeletons, have wide applications in various scientific and technological fields. This study quantifies the environmental impacts of a novel environmentally sustainable method for chitin nanofibril extraction from fungi using life-cycle assessment. The results demonstrate the environmentally friendly character of chitin nanofibril extraction from fungi and provide new cues for the synthesis of nanochitin.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Review Chemistry, Multidisciplinary

Covalent Organic Frameworks with Ionic Liquid-Moieties (ILCOFs): Structures, Synthesis, and CO2 Conversion

Ruina Zhang et al.

Summary: This article introduces the structures and synthesis of covalent organic frameworks with ionic liquid-moieties (ILCOFs), and discusses their applications in CO2 capture and conversion. The study is beneficial for academic researchers to gain an overall understanding of ILCOFs and their application in CO2 conversion. Furthermore, this research opens a direction for developing novel ILCOFs materials for the capture, separation, and utilization of other typical gases.

NANOMATERIALS (2022)

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Article Chemistry, Physical

Green Synthesis of Robust Imine-Linked Two-Dimensional Covalent Organic Frameworks in Supercritical Carbon Dioxide

Tianwei Xue et al.

Summary: In this work, a robust imine-linked 2D COF was synthesized in supercritical CO2, which could maintain a high surface area and prevent pore collapse after vacuum activation. The method used in this study is universal and has the potential to be applied in the synthesis of other imine-linked 2D COFs.

CHEMISTRY OF MATERIALS (2022)

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Review Chemistry, Inorganic & Nuclear

Covalent organic frameworks and their composites as multifunctional photocatalysts for efficient visible-light induced organic transformations

Guang-Bo Wang et al.

Summary: Light-involved catalysis, especially photocatalysis and photothermal catalysis, is a promising alternative to traditional thermocatalysis. Highly efficient photocatalysts are crucial for the development of light-mediated catalysis. Covalent organic frameworks (COFs) are crystalline molecular solids with designable structures, light-harvesting, and semiconducting properties. The recent development of COFs has brought opportunities for visible-light induced organic transformations. This review comprehensively summarizes and discusses the applications of COFs in selective light-initiated organic transformations, provides an overview of COF-based photocatalysts, and discusses the limitations, challenges, and future perspectives of COF photocatalysis and photothermal catalysis.

COORDINATION CHEMISTRY REVIEWS (2022)

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Review Chemistry, Multidisciplinary

Latest trends in the large-scale production of MOFs in accordance with the principles of green chemistry

Kacper Poblocki et al.

Summary: This review presents the latest trends in the large-scale production of metal-organic frameworks (MOFs) based on green chemistry principles. It includes the latest patents from renowned MOF manufacturers and provides a critical review of the procedures for obtaining MOFs.

GREEN CHEMISTRY (2022)

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Article Chemistry, Inorganic & Nuclear

The chemistry behind room temperature synthesis of hafnium and cerium UiO-66 derivatives

Orysia Zaremba et al.

Summary: As the production scale of metal-organic frameworks (MOFs) increases, there is a need to find safer and more energy efficient synthetic protocols. Effective methods that operate under ambient conditions will be advantageous for promoting MOF industrialization. This study investigates the room temperature synthesis of Hf and Ce UiO-66 derivatives and proposes a green, one-step synthesis protocol.

INORGANIC CHEMISTRY FRONTIERS (2022)

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Review Chemistry, Multidisciplinary

Cyrene: a bio-based novel and sustainable solvent for organic synthesis

Naya A. Stini et al.

Summary: Cyrene, a biomass-derived solvent, is biodegradable, non-mutagenic and non-toxic. Since 2014, it has been increasingly used as a substitute for toxic organic solvents in various research fields.

GREEN CHEMISTRY (2022)

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Review Chemistry, Multidisciplinary

Metal-organic framework-based solid-state electrolytes for all solid-state lithium metal batteries: a review

Tao Wei et al.

Summary: This work systematically reviewed the recent progress of MOF-based solid electrolytes in all solid-state metal batteries and summarized the advantages and current or future problems of MOFs in different systems. It also proposed typical design strategies and development trends.

CRYSTENGCOMM (2022)

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Article Engineering, Multidisciplinary

Ultrasound and microwave assisted-synthesis of ZIF-8 from zinc oxide for the adsorption of phosphate

Loubna Bazzi et al.

Summary: The conversion of solid matters into metal-organic frameworks (MOFs) offers a new method for MOF synthesis. This study focuses on using ultrasound and microwave methods to transform zinc oxide into MOFs with higher conversion rates and excellent phosphate adsorption capacity. The results show the potential of using these methods for the development of MOFs from other inorganic solid resources.

RESULTS IN ENGINEERING (2022)

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Article Materials Science, Multidisciplinary

Room temperature synthesis of a luminescent crystalline Cu-BTC coordination polymer and metal-organic framework

Shiraz Ahmed Siddiqui et al.

Summary: In this study, the synthesis of two crystalline structures by controlling the pH of the reaction mixture was demonstrated, along with the post-synthesis transformation from one structure to another. Both structures exhibited photoluminescence within the optical gap range, potentially due to crystallographic defects, providing a basis for further in-depth study of optical properties.

MATERIALS ADVANCES (2022)

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Review Chemistry, Multidisciplinary

Microwave-Assisted Synthesis of Covalent Organic Frameworks: A Review

Borja Diaz de Grenu et al.

Summary: This article presents a comprehensive compilation of research results on microwave-assisted synthesis of COFs, covering the synthesis, characteristics, and general issues related to COFs and microwaves. Current and future perspectives on this topic are also discussed.

CHEMSUSCHEM (2021)

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Article Nanoscience & Nanotechnology

In Situ Investigation of Multicomponent MOF Crystallization during Rapid Continuous Flow Synthesis

Brandon He et al.

Summary: Rapid synthesis of phase pure and highly crystalline multicomponent MOFs can be achieved using continuous flow chemistry. Key differences in the formation mechanisms between ternary UMCM-1 and quaternary MUF-7 have been uncovered, providing insights into MOFs formation.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Review Chemistry, Multidisciplinary

Mechanochemical Synthesis of Catalytic Materials

Amol P. Amrute et al.

Summary: The mechanochemical synthesis of nanomaterials for catalytic applications is a growing research field due to its simplicity, scalability, and eco-friendliness. The distinct material properties achieved by mechanochemistry are related to their improved catalytic performance.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Recent advances in the synthesis techniques for zeolitic imidazolate frameworks and their sensing applications

Preeti Kukkar et al.

Summary: Zeolitic imidazolate frameworks (ZIFs) belong to metal-organic frameworks (MOFs) or metalazolate frameworks (MAFs) with unique topologies, allowing for robust coordination and advantageous properties such as easy crystallization, high loading capacities, and good biocompatibility. Technical advancements in porous coordination polymers synthesis have diversified fabrication approaches for ZIFs, leading to the characterization of their structural and functional attributes.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Applied

Synthesis of nitrogen-containing covalent organic framework with reversible iodine capture capability

Run Chen et al.

Summary: This study explored the crystallization of a stable nitrogen-containing COF for efficient and reversible volatile iodine capture, demonstrating high uptake capacity and recyclability.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Low Power, Low Temperature and Atmospheric Pressure Plasma-Induced Polymerization: Facile Synthesis and Crystal Regulation of Covalent Organic Frameworks

Juan He et al.

Summary: Low temperature and atmospheric pressure plasma-induced polymerization is shown as a fast and facile method for tailoring COF-1 packing phase and preparing diverse COFs, including 2D and 3D structures. The plasma approach allows for rapid synthesis of various COFs under mild conditions, requiring less time, lower power, and no additional heating or gas protection.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Exploring the Role of Cluster Formation in UiO Family Hf Metal-Organic Frameworks with in Situ X-ray Pair Distribution Function Analysis

Francesca C. N. Firth et al.

Summary: The structures of Zr and Hf metal-organic frameworks (MOFs) are sensitive to small changes in synthetic conditions, with the choice of solvent and reaction temperature determining the cluster identity and hence the MOF structure. The nature of Hf metal clusters in different reaction solutions can be tracked during UiO MOF synthesis, leading to insights on the formation mechanism and potential for designing new MOF structures.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Inorganic & Nuclear

Evaluating the purification and activation of metal-organic frameworks from a technical and circular economy perspective

John Luke Woodliffe et al.

Summary: Metal-organic frameworks (MOFs) are highly porous materials with tunable structures and functionalities, but face challenges in purification and activation due to technical and sustainability concerns. The circular economy model aims to promote sustainable development in the chemical industry by designing and manufacturing more environmentally friendly chemical products and processes. By applying a circular economy approach, future economically and environmentally sustainable MOF purification and activation processes can be designed to realize the immense opportunities offered by these materials.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Solvent-Free and Phase-Selective Synthesis of Aluminum Trimesate Metal-Organic Frameworks

Jiahong Li et al.

Summary: Aluminum-based metal-organic frameworks (Al-MOFs) have shown promise as commercially valuable materials due to their wide range of applications, excellent thermal and chemical stabilities, and the abundance of aluminum. The solvent-free synthesis method in this study offers valuable insights for future industrial scale-up production of Al-MOFs and promotes their potential commercialization.

INORGANIC CHEMISTRY (2021)

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Article Materials Science, Multidisciplinary

Mechanochemistry: Toward green synthesis of metal-organic frameworks

Sylwia Glowniak et al.

Summary: Metal-organic frameworks (MOFs) are receiving special attention for their adjustable pore sizes and high potential in various applications, with mechanochemistry seen as an efficient and environmentally friendly synthesis method.

MATERIALS TODAY (2021)

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Article Chemistry, Applied

Sonochemical synthesis of Zr-based porphyrinic MOF-525 and MOF-545: Enhancement in catalytic and adsorption properties

Kwangsun Yu et al.

Summary: In this study, Zr-based porphyrinic MOF-525 and MOF-545 were successfully synthesized with high purity and uniform size through a sonochemical route, showing the potential of sonochemical synthesis in preparing MOFs with improved textural properties. The sonochemically synthesized MOF samples had more defect sites than conventionally prepared ones, leading to enhanced hydrolysis of dimethyl-4-nitrophenyl phosphate and faster and higher bisphenol-A adsorption.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Chemistry, Physical

Polyoxometalate@Metal-Organic Framework Composites as Effective Photocatalysts

Yang Liu et al.

Summary: POM@MOF composites have been attracting attention in photocatalysis due to their enhanced performance, which benefits from the high specific surface area and long-range ordered structure of MOFs that ensure a uniform distribution of POMs and provide more active catalytic sites.

ACS CATALYSIS (2021)

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Review Pharmacology & Pharmacy

Metal-organic frameworks for advanced drug delivery

Siyu He et al.

Summary: Metal-organic frameworks (MOFs) are highly porous, crystalline materials composed of organic ligands and metal ions/metal clusters. They are increasingly popular in drug delivery due to their tunable porosity, chemical composition, and surface functionalization capabilities. Despite their potential in biomedical applications, challenges such as biostability and biosafety need to be addressed in the development of MOFs for drug delivery systems.

ACTA PHARMACEUTICA SINICA B (2021)

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Article Chemistry, Physical

Polyoxometalate/metal-organic framework hybrids and their derivatives for hydrogen and oxygen evolution electrocatalysis

Z-H Wang et al.

Summary: Transition metal-based materials have become significant electrocatalysts for hydrogen and oxygen evolution due to their low cost and excellent electronic transfer ability. Polyoxometalates (POMs) show promise as catalytic components with tunable compositions and diverse structures. Incorporating POMs into metal-organic frameworks (MOFs) can enhance the complexity of derived materials. This review summarizes recent research on POM/MOF composites and their derivatives, focusing on their designable synthesis and electrocatalytic performance.

MATERIALS TODAY ENERGY (2021)

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Review Chemistry, Multidisciplinary

25 Years of Reticular Chemistry

Ralph Freund et al.

Summary: The core of reticular chemistry has brought precision and expertise of organic and inorganic synthesis to the solid state. The most profound scientific innovation of this field has been the design strategies for the synthesis of extended crystalline solids through strong directional bonds, highlighting the different classes of reticular materials developed and how complexity can be introduced into their backbones. Structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

The Current Status of MOF and COF Applications

Ralph Freund et al.

Summary: The amalgamation of different disciplines at the heart of reticular chemistry has broadened the boundaries of chemistry. Reticular design enables precise prediction of crystalline framework structures, tunability of chemical composition, and fine-tuning of material properties in metal-organic frameworks and covalent organic frameworks. Leveraging the unique properties of reticular materials has led to significant advances in both fundamental and applied research.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Environmental Impacts of Graphite Recycling from Spent Lithium-Ion Batteries Based on Life Cycle Assessment

Irene Rey et al.

Summary: The increasing production of lithium-ion batteries poses environmental and health threats. Focus on circular economy principles and graphite recycling processes will be crucial for the sustainable development of the battery industry.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

Rapid, Ambient Temperature Synthesis of Imine Covalent Organic Frameworks Catalyzed by Transition-Metal Nitrates

Dongyang Zhu et al.

Summary: Transition metal nitrates can catalyze the rapid synthesis of COFs, especially for imine COFs, under ambient conditions. By optimizing the catalyst loading and selecting appropriate transition metal nitrates, highly crystalline COF products can be obtained in a short period of time.

CHEMISTRY OF MATERIALS (2021)

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Article Environmental Sciences

Metal-organic frameworks/alginate composite beads as effective adsorbents for the removal of hexavalent chromium from aqueous solution

Sneha Daradmare et al.

Summary: The study investigated the adsorption performance of MOFs@ABs for Cr(VI) removal, revealing that UiO-66@ABs exhibit strong adsorption capacity for Cr(VI) with good regeneration efficiency, promising potential application in wastewater treatment.

CHEMOSPHERE (2021)

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Review Chemistry, Multidisciplinary

Sustainability Assessment of Mechanochemistry by Using the Twelve Principles of Green Chemistry

Karen J. Ardila-Fierro et al.

Summary: Mechanochemistry has become a widely accepted alternative for chemical synthesis due to its efficiency, practicality, and sustainability, satisfying multiple Principles of Green Chemistry.

CHEMSUSCHEM (2021)

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Article Chemistry, Multidisciplinary

Insights into the Mechanochemical Synthesis of MOF-74

Jethro Beamish-Cook et al.

Summary: Mechanochemical synthesis of MOF-74 from ZnO and H(4)HDTA involves the formation of four short-lived intermediate phases before the final crystallization of highly crystalline MOF-74.

CRYSTAL GROWTH & DESIGN (2021)

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Article Nanoscience & Nanotechnology

HKUST-1 Metal-Organic Framework Nanoparticle/Graphene Oxide Nanocomposite Aerogels for CO2 and CH4 Adsorption and Separation

Albert Rosado et al.

Summary: The synthesis of nanostructured composites involving HKUST-1 and a continuous GO matrix using supercritical CO2 allows for the formation of 3D aerogels while maintaining the oxidized state of GO. These composites exhibit enhanced textural properties and practical working capacity for gas separation compared to physical mixtures, with a high selectivity for CO2.

ACS APPLIED NANO MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy

Ioanna Christodoulou et al.

Summary: Metal-Organic Frameworks (MOFs) have attracted interest for biomedical applications, but the balance between stability and biodegradability and degradation mechanisms in physiological media are not well studied. Research found that MOF crystal surfaces can rapidly respond to changes in the media composition, which is crucial for designing nanosized MOFs for drug delivery applications.

NANOMATERIALS (2021)

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Review Chemistry, Multidisciplinary

Degradation Behavior, Biocompatibility, Electrochemical Performance, and Circularity Potential of Transient Batteries

Neeru Mittal et al.

Summary: Transient technology focuses on developing materials, devices, or systems that degrade after a stable operation period, leaving harmless residues, with transient batteries enabling longer operation of fully transient devices. This technology enhances recycling efficiency and reduces exposure to hazardous pollutants, while transient batteries have the potential to change the current perception of batteries as harmful waste.

ADVANCED SCIENCE (2021)

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Review Nanoscience & Nanotechnology

Fibre-based composites from the integration of metal-organic frameworks and polymers

Gregory W. Peterson et al.

Summary: This review outlines the integration of metal-organic frameworks (MOFs) with polymer fibers to create fibrous composite materials with enhanced properties. It discusses the various methods for incorporating MOFs into or onto polymer fibers, as well as potential applications in clothing, protective equipment, air purification, biomedical devices, and more. The review also highlights the importance of understanding structure-processing-activity relationships and suggests research directions for further advancement in this field.

NATURE REVIEWS MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Light-Activated Biodegradable Covalent Organic Framework-Integrated Heterojunction for Photodynamic, Photothermal, and Gaseous Therapy of Chronic Wound Infection

Baohong Sun et al.

Summary: Chronic wound healing is hindered by bacterial infections and drug resistance. Antibacterial phototherapy combined with COFs offers a potential strategy for treating wound infections.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

Monodispersed MOF-808 Nanocrystals Synthesized via a Scalable Room-Temperature Approach for Efficient Heterogeneous Peptide Bond Hydrolysis

Shan Dai et al.

Summary: Zr(IV)-based metal-organic frameworks (MOFs) such as Zr(IV) trimesate MOF-808 are promising materials for catalytic applications. This work introduces a room-temperature strategy to produce well-defined monodispersed MOF-808 nanocrystals with high space-time yield, excellent crystallinity, and porosity, showing potential for highly efficient peptide or protein hydrolysis.

CHEMISTRY OF MATERIALS (2021)

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Article Energy & Fuels

Life Cycle Assessment on Different Synthetic Routes of ZIF-8 Nanomaterials

Vasileios Ntouros et al.

Summary: This study assessed the environmental performance of various synthetic routes of MOF nanoparticles, particularly ZIF-8, and found that the main environmental weak points were the use of solvents like DMF and MeOH, as well as electricity consumption. Suggestions were made to use cleaner renewable energy sources to decrease the environmental impacts.

ENERGIES (2021)

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Article Chemistry, Inorganic & Nuclear

Shake 'n Bake Route to Functionalized Zr-UiO-66 Metal-Organic Frameworks

Roberto D'Amato et al.

Summary: A novel synthetic procedure for high-yield synthesis of metal-organic frameworks (MOFs) with fcu topology is reported in this study, utilizing a simple shake 'n bake procedure inspired by the solid-state reaction of inorganic materials. The acidity of linkers and the amount of water are found to be crucial factors in obtaining materials of comparable quality to those obtained under solvo- or hydrothermal conditions.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Applied

Room temperature synthesis of high-quality Ce(IV)-based MOFs in water

Jemal M. Yassin et al.

Summary: This study explores the outstanding ability of Ce(IV) to prepare high-quality MOFs based on carboxylates at room temperature without energy input and in water as solvent. Various new approaches were used to successfully synthesize crystalline terephthalate-based UiO66(Ce), fumarate-based UiO-66(Ce) and Ce-MOF-808 at room temperature. These novel, rapid, simple, reproducible, inexpensive, energetically efficient, and environmentally benign methodologies provide new strategies for the preparation of tetravalent metal based MOFs, which are generally scarce compared to the whole number of known MOFs, particularly at room temperature.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Article Biochemical Research Methods

Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions

Stipe Lukin et al.

Summary: This protocol details the setup and use of Raman spectroscopy for monitoring solid-state reactions in vibratory ball mills, providing insights into mechanochemical reactions. The use of translucent reaction jars and Raman spectroscopy offers a convenient in situ monitoring method, along with data analysis software for qualitative analysis of reaction paths.

NATURE PROTOCOLS (2021)

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Article Acoustics

Sonocrystallisation of ZIF-8 in water with high excess of ligand: Effects of frequency, power and sonication time

Silvia Nalesso et al.

Summary: A systematic study on sonocrystallisation of ZIF-8 in a water-based system was conducted, revealing that ultrasound and mixing affect crystal morphology and size, while increasing mixing speed can enhance the BET specific surface area.

ULTRASONICS SONOCHEMISTRY (2021)

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Article Chemistry, Physical

Life-Cycle Assessment Considerations for Batteries and Battery Materials

Jason Porzio et al.

Summary: Rechargeable batteries are crucial for energy system decarbonization, but there is still no consensus on the environmental impacts of producing them. Future studies should focus on long-term trends in resource depletion, non-compliant extraction practices, and various battery manufacturing scales.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Toward Sustainable Metal-Organic Frameworks for Post-Combustion Carbon Capture by Life Cycle Assessment and Molecular Simulation

Jingying Hu et al.

Summary: This study evaluates the impact of approximately 50 MOFs on carbon capture and sequestration, identifying the critical role of solvent use in the production process for environmental impacts. In addition to the separation of CO2, the type and amount of solvents used can significantly contribute to environmental effects such as eutrophication potential.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Re-thinking organic synthesis: Mechanochemistry as a greener approach

Claudia Espro et al.

Summary: The increasing advances in mechanochemistry have led to new possibilities for developing organic processes in a more sustainable manner. Recent progress in this area, ranging from laboratory scale protocols to industrial applications, has been described. Innovations in mechanochemical procedures and in-situ characterization analyses have also been discussed, with technologies such as twin-screw extrusion and high-throughput reaction platforms being investigated for scale-up applications. Mechanochemistry is a highly promising approach with numerous potentialities yet to be uncovered.

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2021)

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Review Green & Sustainable Science & Technology

Biomimetic Wood-Inspired Batteries: Fabrication, Electrochemical Performance, and Sustainability within a Circular Perspective

Inaki Gomez et al.

Summary: Nature's hierarchical materials, after millions of years of evolution, possess exceptional multifunctional properties, making biomimicry an exciting research field with great potential. Wood, as a fascinating biomaterial, has unique properties that have inspired scientists to develop batteries with remarkable electrochemical performance by mimicking its structure and features.

ADVANCED SUSTAINABLE SYSTEMS (2021)

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Article Chemistry, Multidisciplinary

Synthesis of covalent organic frameworks using sustainable solvents and machine learning

Sushil Kumar et al.

Summary: This study explores the use of green solvents to synthesize COFs, evaluating crystallinity and porosity to assess quality and identifying gamma-butyrolactone, para-cymene, and PolarClean as excellent green solvents. For the first time, the researchers successfully predicted the surface area and crystallinity of COFs using quantitative structure-property relationships and machine learning approaches.

GREEN CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Simplifying and expanding the scope of boron imidazolate framework (BIF) synthesis using mechanochemistry

Cameron B. Lennox et al.

Summary: Mechanochemistry allows rapid synthesis of boron imidazolate frameworks (BIFs) with improved porosity compared to solution methods, replacing harsh reactants with safer alternatives. DFT calculations show that heavy-atom nodes increase the stability of BIFs structures.

CHEMICAL SCIENCE (2021)

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Review Materials Science, Multidisciplinary

Integration of metal-organic frameworks and covalent organic frameworks: Design, synthesis, and applications

Yang Li et al.

Summary: Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), which are porous crystalline materials, can be intermeshed into MOF/COF hybrids to enhance performance and extend applications.

MATTER (2021)

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Article Chemistry, Physical

MOFs industrialization: a complete assessment of production costs

Maria Ines Severino et al.

Summary: The study evaluated the potential of safe and low-cost batch production processes for Metal-Organic Frameworks (MOFs), finding that high practical value bio-derived materials can be produced with high yield using green ambient pressure conditions. By considering all process parameters and using data from laboratory tests, the production cost was determined, with future expected costs projected to decrease further.

FARADAY DISCUSSIONS (2021)

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Article Chemistry, Physical

Monolithic metal-organic frameworks for carbon dioxide separation

David G. Madden et al.

Summary: Carbon dioxide is a major contributor to global warming and an industrial impurity. Traditional carbon capture methods are costly and corrosive, while metal-organic frameworks (MOFs) have gained attention for their tunable nature in capturing CO2.

FARADAY DISCUSSIONS (2021)

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Article Chemistry, Physical

Towards MOFs' mass market adoption: MOF Technologies' efficient and versatile one-step extrusion of shaped MOFs directly from raw materials

Jose Casaban et al.

Summary: Metal Organic Frameworks (MOFs) are important in commercial gas storage and separation applications due to their unique physical and sorption properties. MOF Technologies has developed innovative solutions and demonstrated a one-step production method for MOFs, addressing current market entry barriers.

FARADAY DISCUSSIONS (2021)

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Article Chemistry, Multidisciplinary

Accelerated and scalable synthesis of UiO-66(Zr) with the assistance of inorganic salts under solvent-free conditions

Yulong Gu et al.

Summary: This study successfully achieved the accelerated and scalable synthesis of UiO-66(Zr) under solvent-free conditions with the assistance of inorganic salts. The product obtained has a large surface area and high yield, suitable for large-scale production. By adjusting various parameters and types of inorganic salts, the synthesis conditions were optimized, and the approach can also be extended to prepare functionalized UiO-66(Zr) materials.

NEW JOURNAL OF CHEMISTRY (2021)

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Article Engineering, Environmental

Comparison between conventional solvothermal and aqueous solution-based production of UiO-66-NH2: Life cycle assessment, techno-economic assessment, and implications for CO2 capture and storage

Hongxi Luo et al.

Summary: Metal-organic frameworks (MOFs) are a promising new class of materials, with potential applications in various fields. Aqueous synthesis of MOFs eliminates organic solvents, reducing environmental burdens and costs associated with production. This study highlights the significant environmental and economic benefits of using aqueous-based methods for producing MOFs.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Exploiting in situ NMR to monitor the formation of a metal-organic framework

Corey L. Jones et al.

Summary: In situ NMR studies on the formation of MFM-500(Ni) provide insights into the solution-phase processes and kinetics of crystallization, revealing activation energies for nucleation and growth. Complementary nanoscale information on rapid self-assembly prior to MOF crystallization is obtained through ex situ small-angle X-ray scattering, while in situ powder X-ray diffraction confirms the presence of phase-pure MFM-500(Ni) during the reaction. This work demonstrates the potential of in situ NMR experiments in shedding new light on MOF synthesis.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Green synthesis of covalent organic frameworks based on reaction media

Yan Chen et al.

Summary: The synthesis of COFs has traditionally relied on the solvothermal method using a large amount of organic solvents, but there is a growing interest in green synthesis methods. This Feature Article summarizes the green COF synthesis strategies that aim to reduce or avoid the use of organic solvents and facilitate large-scale synthesis, discussing basic operations, yields, key factors, product qualities, advantageous applications, and limitations.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

One-Step Room-Temperature Synthesis of Metal(IV) Carboxylate Metal-Organic Frameworks

Shan Dai et al.

Summary: Room-temperature synthesis of highly porous M-6-oxocluster-based MOFs including 8- or 12-connected micro/mesoporous solids with different functionalized organic ligands was reported. The compounds showed varying degrees of defects while maintaining the chemical stability of the parent MOFs. The synthesis had a high space-time yield and provided the possibility to tune the particle size for practical use.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Solvent- and HF-Free Synthesis of Flexible Chromium-Based MIL-53 and MIL-88B

Wei Liang Teo et al.

CHEMNANOMAT (2020)

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Article Chemistry, Multidisciplinary

Green Full Conversion of ZnO Nanopowders to Well-Dispersed Zeolitic Imidazolate Framework-8 (ZIF-8) Nanopowders via a Stoichiometric Mechanochemical Reaction for Fast Dye Adsorption

Mahdiar Taheri et al.

CRYSTAL GROWTH & DESIGN (2020)

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Article Chemistry, Multidisciplinary

Biomimetic Synthesis of Sub-20 nm Covalent Organic Frameworks in Water

Carlos Franco et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Analytical

A covalent triazine framework as an oxidase mimetic in the luminol chemiluminescence system: application to the determination of the antioxidant rutin

Haonan Tan et al.

MICROCHIMICA ACTA (2020)

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Review Green & Sustainable Science & Technology

Methodological review and detailed guidance for the life cycle interpretation phase

Alexis Laurent et al.

JOURNAL OF INDUSTRIAL ECOLOGY (2020)

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Article Chemistry, Physical

Phase-Selective Microwave Assisted Synthesis of Iron(III) Aminoterephthalate MOFs

Ana Arenas-Vivo et al.

MATERIALS (2020)

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Review Chemistry, Inorganic & Nuclear

Green synthesis of metal-organic frameworks: A state-of-the-art review of potential environmental and medical applications

Sandeep Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Generalized Approach for Rapid Aqueous MOF Synthesis by Controlling Solution pH

Luke Huelsenbeck et al.

CRYSTAL GROWTH & DESIGN (2020)

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Article Multidisciplinary Sciences

Understanding the diversity of the metal-organic framework ecosystem

Seyed Mohamad Moosavi et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

A Robust and Biocompatible Bismuth Ellagate MOF Synthesized Under Green Ambient Conditions

Erik Svensson Grape et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Applied

CO2 cycloaddition to epichlorohydrin over an aluminum fumarate metal-organic framework synthesized by a sonochemical route

Hyun Sub Kim et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2020)

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Article Multidisciplinary Sciences

Bridging Lab and Industry with Flow Electrochemistry

Nour Tanbouza et al.

ISCIENCE (2020)

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Article Nanoscience & Nanotechnology

Multifaceted Study of the Interactions between CPO-27-Ni and Polyurethane and Their Impact on Nitric Oxide Release Performance

Simon M. Vornholt et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Review Chemistry, Multidisciplinary

A Mini Review on Yolk-Shell Structured Nanocatalysts

Xiaohuan Sun et al.

FRONTIERS IN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Extensive Screening of Green Solvents for Safe and Sustainable UiO-66 Synthesis

Diletta Morelli Venturi et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Review Chemistry, Multidisciplinary

The Role of Machine Learning in the Understanding and Design of Materials

Seyed Mohamad Moosavi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Multidisciplinary

Development of biological metal-organic frameworks designed for biomedical applications: from bio-sensing/bio-imaging to disease treatment

Huai-Song Wang et al.

NANOSCALE ADVANCES (2020)

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Article Chemistry, Multidisciplinary

An ionic liquid as a green solvent for high potency synthesis of 2D covalent organic frameworks

Limin Zhao et al.

NEW JOURNAL OF CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Accelerated ageing reactions: towards simpler, solvent-free, low energy chemistry

Igor Huskic et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Facile and reversible digestion and regeneration of zirconium-based metal-organic frameworks

Jun Chu et al.

COMMUNICATIONS CHEMISTRY (2020)

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Review Chemistry, Physical

Expeditious synthesis of covalent organic frameworks: a review

Xinle Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Inorganic & Nuclear

Sonochemical synthesis of microscale Zn(ii)-MOF with dual Lewis basic sites for fluorescent turn-on detection of Al3+and methanol with low detection limits

Theanchai Wiwasuku et al.

DALTON TRANSACTIONS (2020)

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Review Chemistry, Multidisciplinary

Mechanochemistry: an efficient and versatile toolbox for synthesis, transformation, and functionalization of porous metal-organic frameworks

Tomislav Stolar et al.

CRYSTENGCOMM (2020)

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Article Chemistry, Multidisciplinary

Waste to MOFs: sustainable linker, metal, and solvent sources for value-added MOF synthesis and applications

El-Sayed M. El-Sayed et al.

GREEN CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Advances in the green chemistry of coordination polymer materials

Emile R. Engel et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Self-sacrificed construction of defect-rich ZnO@ZIF-8 nanocomposites with enhanced photocurrent properties

Yali Ma et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Multidisciplinary

Remarkably efficient removal of toxic bromate from drinking water with a porphyrin-viologen covalent organic framework

Tina Skorjanc et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Applied

Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance

Ying Mao et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2019)

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Article Engineering, Environmental

A calcium-based microporous metal-organic framework for efficient adsorption separation of light hydrocarbons

Liangying Li et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Biochemistry & Molecular Biology

The essential metals for humans: a brief overview

Maria Antonietta Zoroddu et al.

JOURNAL OF INORGANIC BIOCHEMISTRY (2019)

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Editorial Material Chemistry, Multidisciplinary

Circular chemistry to enable a circular economy

Tom Keijer et al.

NATURE CHEMISTRY (2019)

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Article Multidisciplinary Sciences

Capturing chemical intuition in synthesis of metal-organic frameworks

Seyed Mohamad Moosavi et al.

NATURE COMMUNICATIONS (2019)

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Article Environmental Sciences

Laccase immobilization on amino-functionalized magnetic metal organic framework for phenolic compound removal

Enhui Wu et al.

CHEMOSPHERE (2019)

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Article Chemistry, Inorganic & Nuclear

A bifunctional luminescent Zn(II)-organic framework: Ionothermal synthesis, selective Fe(III) detection and cationic dye adsorption

Xiaojun Luo et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2019)

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Article Materials Science, Multidisciplinary

Microwave-assisted synthesis and simultaneous electrochemical determination of dopamine and paracetamol using ZIF-67-modified electrode

Nguyen Thi Thanh Tu et al.

JOURNAL OF MATERIALS SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Solvent-Free Synthesis of ZIFs: A Route toward the Elusive Fe(II) Analogue of ZIF-8

Javier Lopez-Cabrellesr et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

Ghada Ayoub et al.

CHEMISTRY OF MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Crystalline Anionic Germanate Covalent Organic Framework for High CO2 Selectivity and Fast Li Ion Conduction

Shumaila Ashraf et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Article Environmental Sciences

How green are ionic liquids? - A multicriteria decision analysis approach

Marta Bystrzanowska et al.

ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY (2019)

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Article Chemistry, Multidisciplinary

Synthesis of Two-Dimensional Covalent Organic Frameworks in Ionic Liquids

Yanan Gao et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Article Engineering, Chemical

Highly Efficient Adsorption of Au(III) from Water by a Novel Metal-Organic Framework Constructed with Sulfur-Containing Ligands and Zn(II)

Chenghong Hu et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

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Review Chemistry, Analytical

A review on metal-organic frameworks: Synthesis and applications

Mohadeseh Safaei et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2019)

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Article Nanoscience & Nanotechnology

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In Situ Charge Exfoliated Soluble Covalent Organic Framework Directly Used for Zn-Air Flow Battery

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Article Engineering, Environmental

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Article Engineering, Environmental

Novel room-temperature synthesis of MIL-100(Fe) and its excellent adsorption performances for separation of light hydrocarbons

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Article Engineering, Chemical

Design and Synthesis of Ionic Liquid Supported Hierarchically Porous Zr Metal-Organic Framework as a Novel Bronsted-Lewis Acidic Catalyst in Biodiesel Synthesis

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

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Article Green & Sustainable Science & Technology

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CHEMICAL COMMUNICATIONS (2018)

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Room Temperature Synthesis of an 8-Connected Zr-Based Metal-Organic Framework for Top-Down Nanoparticle Encapsulation

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CHEMISTRY OF MATERIALS (2018)

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beta-Cyclodextrin Covalent Organic Framework for Selective Molecular Adsorption

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Greener synthesis of Cu-MOF-74 and its catalytic use for the generation of vanillin

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DALTON TRANSACTIONS (2018)

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Efficient visible light-driven water oxidation and proton reduction by an ordered covalent triazine-based framework

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Review Chemistry, Physical

Realising the environmental benefits of metal-organic frameworks: recent advances in microwave synthesis

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Article Nanoscience & Nanotechnology

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Covalent triazine-based frameworks/iron oxide for highly sensitive magnetic solid-phase extraction of phenolic pollutants in water samples

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Metal Acetylacetonates as a Source of Metals for Aqueous Synthesis of Metal-Organic Frameworks

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Review Crystallography

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Effect of Microwave Radiation on the Solvent-Free Synthesis of MOF-199

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An ambient-temperature aqueous synthesis of zirconium-based metal-organic frameworks

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Assessing the life cycle environmental impacts of titania nanoparticle production by continuous flow solvo/hydrothermal syntheses

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Green Synthesis of Zr-CAU-28: Structure and Properties of the First Zr-MOF Based on 2,5-Furandicarboxylic Acid

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Viologen-Based Conjugated Covalent Organic Networks via Zincke Reaction

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Colorimetric determination of copper ions based on regulation of the enzyme-mimicking activity of covalent triazine frameworks

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TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2017)

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Ionic liquid accelerates the crystallization of Zr-based metal-organic frameworks

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Controlled Formation of Hierarchical Metal-Organic Frameworks Using CO2-Expanded Solvent Systems

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Metal-organic frameworks in seconds via selective microwave heating

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Supercritical CO2 for the synthesis of nanometric ZIF-8 and loading with hyperbranched aminopolymers. Applications in CO2 capture

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Rapid room-temperature synthesis of hierarchical porous zeolitic imidazolate frameworks with high space-time yield

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SCIENCE CHINA-MATERIALS (2017)

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Article Green & Sustainable Science & Technology

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CHEMICAL ENGINEERING JOURNAL (2017)

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Review Pharmacology & Pharmacy

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Article Chemistry, Multidisciplinary

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CRYSTAL GROWTH & DESIGN (2017)

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Article Chemistry, Physical

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Active Sites Implanted Carbon Cages in Core Shell Architecture: Highly Active and Durable Electrocatalyst for Hydrogen Evolution Reaction

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Article Chemistry, Multidisciplinary

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Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks

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CHEMICAL COMMUNICATIONS (2016)

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Article Chemistry, Physical

Room Temperature Batch and Continuous Flow Synthesis of Water-Stable Covalent Organic Frameworks (COFs)

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CHEMISTRY OF MATERIALS (2016)

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Assembling Metal-Organic Frameworks in Ionic Liquids and Supercritical CO2

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Review Chemistry, Inorganic & Nuclear

Synthetic design of functional boron imidazolate frameworks

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Water based scale-up of CPO-27 synthesis for nitric oxide delivery

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Ambient pressure synthesis of MIL-100(Fe) MOF from homogeneous solution using a redox pathway

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EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

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CHEM21 selection guide of classical- and less classical-solvents

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GREEN CHEMISTRY (2016)

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Binary supercritical CO2 solvent mixtures for the synthesis of 3D metal-organic frameworks

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MICROPOROUS AND MESOPOROUS MATERIALS (2016)

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Article Chemistry, Physical

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Article Multidisciplinary Sciences

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SCIENTIFIC REPORTS (2016)

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Review Polymer Science

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Dihydrolevoglucosenone (Cyrene) As a Green Alternative to N,N-Dimethylformamide (DMF) in MOF Synthesis

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Article Chemistry, Physical

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Article Energy & Fuels

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Towards scalable and controlled synthesis of metal-organic framework materials using continuous flow reactors

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Article Nanoscience & Nanotechnology

Mixed-Metal-Organic Framework with Effective Lewis Acidic Sites for Sulfur Confinement in High-Performance Lithium-Sulfur Batteries

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Design of Hydrophilic Metal Organic Framework Water Adsorbents for Heat Reallocation

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The Structure of the Aluminum Fumarate Metal-Organic Framework A520

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A biocompatible porous Mg-gallate metal-organic framework as an antioxidant carrier

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ZIF-8: A comparison of synthesis methods

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CHEMICAL SOCIETY REVIEWS (2015)

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In Situ Synthesis of Covalent Organic Frameworks (COFs) on Carbon Nanotubes and Graphenes by Sonochemical Reaction for CO2 Adsorbents

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Exploring a novel preparation method of 1D metal organic frameworks based on supercritical CO2

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Synthesis of metal-organic frameworks in water at room temperature: salts as linker sources

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GREEN CHEMISTRY (2015)

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Room Temperature Synthesis of Covalent-Organic Framework Films through Vapor-Assisted Conversion

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Optimised room temperature, water-based synthesis of CPO-27-M metal-organic frameworks with high space-time yields

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Towards multicomponent MOFs via solvent-free synthesis under conventional oven and microwave assisted heating

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Solvent-Mediated Reconstruction of the Metal-Organic Framework HKUST-1 (Cu3(BTC)2)

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From assembled metal-organic framework nanoparticles to hierarchically porous carbon for electrochemical energy storage

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CHEMICAL COMMUNICATIONS (2014)

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Ultrasound-driven preparation and pair distribution function-assisted structure solution of a copper-based layered coordination polymer

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In Situ Energy-Dispersive X-ray Diffraction for the Synthesis Optimization and Scale-up of the Porous Zirconium Terephthalate UiO-66

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INORGANIC CHEMISTRY (2014)

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Article Engineering, Environmental

A system boundary identification method for life cycle assessment

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INTERNATIONAL JOURNAL OF LIFE CYCLE ASSESSMENT (2014)

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Influence of the solvent in the synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals at room temperature

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Highly mesoporous metal-organic framework assembled in a switchable solvent

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NATURE COMMUNICATIONS (2014)

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Two appealing alternatives for MOFs synthesis: solvent-free oven heating vs. microwave heating

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RSC ADVANCES (2014)

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Aqueous room temperature synthesis of zeolitic imidazole framework 8 (ZIF-8) with various concentrations of triethylamine

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Green, scalable and morphology controlled synthesis of nanofibrous covalent organic frameworks and their nanohybrids through a vapor-assisted solid-state approach

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Article Chemistry, Physical

Enhanced lithium storage capacity of Co3O4 hexagonal nanorings derived from Co-based metal organic frameworks

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Scalable Room-Temperature Conversion of Copper(II) Hydroxide into HKUST-1 (Cu3(btc)2)

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Small-angle X-ray scattering documents the growth of metal-organic frameworks

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Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework

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Review Chemistry, Multidisciplinary

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The historical development of mechanochemistry

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Water-Based Synthesis of Zeolitic Imidazolate Framework-90 (ZIF-90) with a Controllable Particle Size

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Nanostructured Zeolitic Imidazolate Frameworks Derived from Nanosized Zinc Oxide Precursors

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Mineral neogenesis as an inspiration for mild, solvent-free synthesis of bulk microporous metal-organic frameworks from metal (Zn, Co) oxides

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Ultrafast microwave-enhanced ionothermal synthesis of luminescent crystalline polyimide nanosheets for highly selective sensing of chromium ions

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Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) in aqueous solution via microwave irradiation

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High yield 1-L scale synthesis of ZIF-8 via a sonochemical route

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Post consumer PET waste as potential feedstock for metal organic frameworks

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MATERIALS LETTERS (2013)

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Porous, Fluorescent, Covalent Triazine-Based Frameworks Via Room-Temperature and Microwave-Assisted Synthesis

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ADVANCED MATERIALS (2012)

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Review Chemistry, Multidisciplinary

Conventional and Unconventional Metal-Organic Frameworks Based on Phosphonate Ligands: MOFs and UMOFs

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Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites

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Microwave-assisted Ionothermal Synthesis and Characterization of Zeolitic Imidazolate Framework-8

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Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)

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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

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CO2 capture and conversion using Mg-MOF-74 prepared by a sonochemical method

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Green Microwave Synthesis of MIL-100(Al, Cr, Fe) Nanoparticles for Thin-Film Elaboration

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Room Temperature Synthesis and Size Control of HKUST-1

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Facile green synthesis of crystalline polyimide photocatalyst for hydrogen generation from water

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Selective adsorption and extraction of C70 and higher fullerenes on a reusable metal-organic framework MIL-101(Cr)

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Review Materials Science, Multidisciplinary

Synthesis of nanostructured materials using supercritical CO2: Part I. Physical transformations

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Large scale fluorine-free synthesis of hierarchically porous iron(III) trimesate MIL-100(Fe) with a zeolite MTN topology

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The progression of Al-based metal-organic frameworks - From academic research to industrial production and applications

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MICROPOROUS AND MESOPOROUS MATERIALS (2012)

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Rapid and efficient crystallization of MIL-53(Fe) by ultrasound and microwave irradiation

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Accelerated aging: a low energy, solvent-free alternative to solvothermal and mechanochemical synthesis of metal-organic materials

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Facile synthesis of covalent organic frameworks COF-1 and COF-5 by sonochemical method

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Accelerated aging: a low energy, solvent-free alternative to solvothermal and mechanochemical synthesis of metal-organic materials

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Kinetic Control of Metal-Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering

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Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-Resolved In Situ Small-Angle and Wide-Angle X-Ray Scattering

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system

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Room-Temperature Synthesis of ZIF-8: The Coexistence of ZnO Nanoneedles

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Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering

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Sonochemical Synthesis and Characterization of Submicrometer Crystals of the Metal-Organic Framework Cu[(hfipbb)(H2hfipbb)0.5]

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Microwave-enhanced synthesis of magnetic porous covalent triazine-based framework composites for fast separation of organic dye from aqueous solution

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Control of catenation in CuTATB-n metal-organic frameworks by sonochemical synthesis and its effect on CO2 adsorption

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Cathode Composites for Li-S Batteries via the Use of Oxygenated Porous Architectures

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Controllable Synthesis of Metal-Organic Frameworks: From MOF Nanorods to Oriented MOF Membranes

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Review Chemistry, Multidisciplinary

Applications of Ultrasound to the Synthesis of Nanostructured Materials

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Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal-Organic Frameworks Reveals Salt Inclusion and Anion Templating

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Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal-Organic Frameworks

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Metal-Organic Frameworks from Edible Natural Products

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Synthesis and properties of nano zeolitic imidazolate frameworks

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A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

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Review Chemistry, Multidisciplinary

Green Chemistry: Principles and Practice

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Synthesis of a Metal-Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study

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The use of ionic liquids in the synthesis of zinc imidazolate frameworks

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Facile synthesis of MOF-177 by a sonochemical method using 1-methyl-2-pyrrolidinone as a solvent

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Article Chemistry, Inorganic & Nuclear

Accelerated Syntheses of Porous Isostructural Lanthanide-Benzenetricarboxylates (Ln-BTC) Under Ultrasound at Room Temperature

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Article Chemistry, Physical

Highly energy- and time-efficient synthesis of porous triazine-based framework: microwave-enhanced ionothermal polymerization and hydrogen uptake

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Structural Evolution of Zeolitic Imidazolate Framework-8

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Evaluation of synthetic methods for microporous metal-organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3] and [Cu2(btc)(OH)(H2O)]

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Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes

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MICROPOROUS AND MESOPOROUS MATERIALS (2010)

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Review Chemistry, Multidisciplinary

Induction of chiral porous solids containing only achiral building blocks

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NATURE CHEMISTRY (2010)

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Understanding microwave heating effects in single mode type cavities-theory and experiment

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The ionothermal synthesis of metal organic frameworks, Ln(C9O6H3)((CH3NH)2CO)2, using deep eutectic solvents

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Ionothermal synthesis-ionic liquids as functional solvents in the preparation of crystalline materials

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CHEMICAL COMMUNICATIONS (2009)

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Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks

Neil L. Campbell et al.

CHEMISTRY OF MATERIALS (2009)

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Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework

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CHEMISTRY OF MATERIALS (2009)

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Article Chemistry, Multidisciplinary

The role of solvent in mechanochemical and sonochemical cocrystal formation: a solubility-based approach for predicting cocrystallisation outcome

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CRYSTENGCOMM (2009)

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Review Environmental Sciences

Recent developments in Life Cycle Assessment

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JOURNAL OF ENVIRONMENTAL MANAGEMENT (2009)

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In Situ Comparison of Ionothermal Kinetics Under Microwave And Conventional Heating

David S. Wragg et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2009)

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Microwave synthesis of hybrid inorganic-organic materials including porous Cu3(BTC)2 from Cu(II)-trimesate mixture

You-Kyong Seo et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2009)

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Article Materials Science, Multidisciplinary

Ultrasonic synthesis of the microporous metal-organic framework Cu3(BTC)2 at ambient temperature and pressure: An efficient and environmentally friendly method

Zong-Qun Li et al.

MATERIALS LETTERS (2009)

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Porous, covalent triazine-based frameworks prepared by ionothermal synthesis

Pierre Kuhn et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Article Chemistry, Multidisciplinary

Facile synthesis of nanocrystals of a microporous metal-organic framework by an ultrasonic method and selective sensing of organoamines

Ling-Guang Qiu et al.

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Article Chemistry, Multidisciplinary

Sonochemical synthesis of MOF-5

Won-Jin Son et al.

CHEMICAL COMMUNICATIONS (2008)

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Hydrogen-bond-directing effect in the ionothermal synthesis of metal coordination polymers

Zhuojia Lin et al.

DALTON TRANSACTIONS (2008)

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Fabrication of nanosheets of a fluorescent metal-organic framework [Zn(BDC)(H2O)]n (BDC=1,4-benzenedicarboxylate): Ultrasonic synthesis and sensing of ethylamine

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INORGANIC CHEMISTRY COMMUNICATIONS (2008)

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Article Chemistry, Multidisciplinary

Crystals as molecules: Postsynthesis covalent functionalization of zeolitic imidazolate frameworks

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

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Pharmacokinetics and biodistribution of nanoparticles

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MOLECULAR PHARMACEUTICS (2008)

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Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0

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TETRAHEDRON (2008)

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Review Chemistry, Multidisciplinary

Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids

Emily R. Parnham et al.

ACCOUNTS OF CHEMICAL RESEARCH (2007)

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Article Chemistry, Multidisciplinary

Chiral induction in the ionothermal synthesis of a 3-D coordination polymer

Zhuojia Lin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

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Article Chemistry, Multidisciplinary

Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores

Patricia Horcajada et al.

CHEMICAL COMMUNICATIONS (2007)

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Article Chemistry, Multidisciplinary

Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis

Zheng Ni et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

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Article Chemistry, Physical

Metal-organic frameworks -: prospective industrial applications

U Mueller et al.

JOURNAL OF MATERIALS CHEMISTRY (2006)

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Microwave-assisted synthesis of anionic metal-organic frameworks under ionothermal conditions

ZJ Lin et al.

CHEMICAL COMMUNICATIONS (2006)

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Solvent-free synthesis of a microporous metal-organic framework

Anne Pichon et al.

CRYSTENGCOMM (2006)

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Article Chemistry, Multidisciplinary

Green solvents for sustainable organic synthesis: state of the art

RA Sheldon

GREEN CHEMISTRY (2005)

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Article Chemistry, Inorganic & Nuclear

Self-assembly of lanthanide helicate coordination polymers into 3D metal-organic framework structures

SK Ghosh et al.

INORGANIC CHEMISTRY (2004)

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Review Chemistry, Inorganic & Nuclear

Ionic liquids in catalysis

T Welton

COORDINATION CHEMISTRY REVIEWS (2004)

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Review Multidisciplinary Sciences

Reticular synthesis and the design of new materials

OM Yaghi et al.

NATURE (2003)

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Hydrothermal synthesis of a novel thermally stable three-dimensional ytterbium-organic framework

FAA Paz et al.

CHEMICAL COMMUNICATIONS (2003)

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Article Chemistry, Physical

Hydrothermal synthesis, structure determination, and magnetic properties of three new copper(II) methylenediphosphonates with hybrid frameworks (MIL-54, 55, 56), and of the Cu homologue of Na2Co(O3P-CH2-PO3)•(H2O)

K Barthelet et al.

CHEMISTRY OF MATERIALS (2002)

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Article Chemistry, Physical

Hydrothermal synthesis, structure determination, and thermal behavior of new three-dimensional europium terephthalates:: MIL-51LT,HT and MIL-52 or EU2n(OH)x(H2O)y(O2C-C6H4-CO2)z (n = III, III, II; x = 4, 0, 0; y = 2, 0, 0; z = 1, 1, 2)

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CHEMISTRY OF MATERIALS (2002)

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Article Chemistry, Physical

Hydrothermal synthesis, thermal behaviour and structure determination from powder data of a porous three-dimensional europium trimesate: Eu-3(H2O)(OH)(6)[C6H3(CO2)(3)]center dot 3H(2)O or MIL-63

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JOURNAL OF MATERIALS CHEMISTRY (2002)

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Article Chemistry, Multidisciplinary

Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation

JG Huddleston et al.

GREEN CHEMISTRY (2001)

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Article Chemistry, Physical

Hydrothermal synthesis and characterization of an ethylenediamine-templated mixed-valence titanium phosphate

S Ekambaram et al.

CHEMISTRY OF MATERIALS (2000)

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