4.8 Article

Self-Assembled Perovskite Nanocomposite With Beneficial Lattice Tensile Strain as High Active and Durable Cathode for Low Temperature Solid Oxide Fuel Cell

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ADVANCED FUNCTIONAL MATERIALS
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出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202310790

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electrochemical performance; lattice tensile strain; oxygen reduction reaction; solid oxide fuel cell; stability

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This study presents a highly active and durable nanocomposite cathode material for low-temperature SOFCs. The material self-assembles into two perovskite structures, balancing high catalytic activity and stability. PBSCF-c serves as a highly conductive and active catalyst, while BSCFW-c significantly enhances the ORR activity through introducing lattice tensile strain.
The sluggish kinetics of oxygen reduction reaction (ORR) at low temperatures and the fast degradation of the cathode are the main obstacles to the commercialization of solid oxide fuel cells (SOFCs). However, it is still very challenging to achieve both high catalytic activity and favorable stability for single-phase materials. Herein, a highly active and durable nanocomposite cathode (Ba0.5Sr0.5)(0.75)Pr0.25Co0.575Fe0.3W0.125O3-delta (BSPCFW) for low-temperature SOFC (<= 650 degrees C) is presented, which self-assembles into two cubic perovskites: the simple perovskite Pr0.38Ba0.25Sr0.37Co0.62Fe0.38O3-delta (PBSCF-c) and the B-site cations ordered double perovskite Ba1.30Sr0.70Co1.0Fe0.25W0.75O6-delta (BSCFW-c). The former PBSCF-c serves as the highly conductive and active catalyst for ORR, while the latter BSCFW-c with a large lattice parameter introduces a key beneficial lattice tensile strain into the PBSCF-c phase through a coherent interface, which significantly promotes the ORR activity at low temperatures with the area specific resistance of 0.034 Omega cm(2) at 650 degrees C, and the long-term stability of 2 years storage and 1280 h operation in symmetrical cell. The introduction of the beneficial lattice tensile strain in self-assembled composite catalysts is an effective way to synergistically enhance the electrochemical activity and durability of the electrode materials for electrochemical devices.

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