期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 39, 页码 8229-8232出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01714a
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资金
- CNRS [UMR 8232]
- UPMC
- Labex Michem
- French Ministry of Research
- ANR Switch [2010-Blan-712]
- ANR E-storic [14-CE05-0002]
- Spanish Ministerio de Economia y Competitividad [CTQ2011-23862-C02-01]
- regional Generalitat de Catalunya authority [2009SGR1459]
Photo-induced spin transition in a molybdenum-zinc complex has been evidenced and fully characterized by Squid magnetometry and several spectroscopies performed under irradiation (IR, EPR, etc.). The phenomenon has been confirmed by X-ray diffraction and DFT calculations yielding a Light-Induced Excited Spin State Trapping Effect (LIESST) on a 4d transition metal ion.
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