期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 44, 页码 9093-9096出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00383k
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资金
- Beijing Nova Program [Z141103001814065]
- National Science Foundation [21201177]
- State Key Project of Fundamental Research [2014CB931900, 2012CB932504]
- Chinese Academy of Sciences (Hundred Talents Project'')
Lithium-rich Li1.13Ni0.30Mn0.57O2 has been functionally modified with fast Li+-ion conducting Li2SiO3 via a facile and novel method, based on the reaction between Ni0.35Mn0.65C2O4.xH(2)O and Si(OC2H5)(4). Due to the unique Li2SiO3 coating layer which greatly improves the Li+ ion diffusion rate, Li2SiO3@Li1.13Ni0.30Mn0.57O2 exhibits outstanding rate capability, cycle stability and low polarization.
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