Selective electrocatalytic carbon dioxide reduction with electrochemically stable frustrated Lewis pairs

Article Chemistry, Physical

Crystal facet-dependent frustrated Lewis pairs on dual-metal hydroxide for photocatalytic CO2 reduction

Weining Zhang et al.

Summary: Research shows that FLPs with shorter acid-base distance are more efficient in CO2 activation. The combination effects between facet junction separating charges and FLPs activating molecules can accelerate CO2 reduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Review Chemistry, Multidisciplinary

Carbon-Supported Single Metal Site Catalysts for Electrochemical CO2 Reduction to CO and Beyond

Yuanzhi Zhu et al.

Summary: This passage describes the application of carbon-supported single-atom catalysts in the electrochemical CO2 reduction reaction, and summarizes research progress on synthesis methods, intrinsic activity differences of metal centers, and strategies for enhancing activity.

SMALL (2021)

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Article Multidisciplinary Sciences

Isolated copper-tin atomic interfaces tuning electrocatalytic CO2 conversion

Wenhao Ren et al.

Summary: The study reports Cu-Sn single-atom surface alloys for efficient CO2 reduction catalysis. These surface alloys exhibit unique geometric and electronic structures, enabling a high CO Faradaic efficiency and current density in an alkaline flow cell.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Engineering Bismuth-Tin Interface in Bimetallic Aerogel with a 3D Porous Structure for Highly Selective Electrocatalytic CO2 Reduction to HCOOH

Zexing Wu et al.

Summary: The study introduced the use of a metallic bismuth-tin aerogel for electrochemical reduction of CO2 with selective formic acid production, demonstrating high FEHCOOH and stability. Experimental and theoretical findings confirmed that the coexistence of bismuth and tin optimized the energy barrier for formic acid generation, enhancing catalytic activity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Advances and Challenges for the Electrochemical Reduction of CO2 to CO: From Fundamentals to Industrialization

Song Jin et al.

Summary: The electrochemical carbon dioxide reduction reaction is an important pathway for converting renewable electricity into fuels and feedstocks, with the conversion of CO2 into CO being a promising reaction. Advancements in catalyst and electrolyte design, along with understanding the catalytic mechanism, are crucial for promoting the technology towards industrial implementation. However, there are still challenges and future directions for the industrial application of this technology.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Nanoscience & Nanotechnology

Polarons in materials

Cesare Franchini et al.

Summary: Polarons, arising from the interaction of electrons with lattice vibrations, strongly influence materials properties. This Review provides a map of the theoretical models and experimental techniques used to study polarons in materials, presenting paradigmatic examples of different types of polarons and polaron-driven phenomena.

NATURE REVIEWS MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Direct Electrochemical Protonation of Metal Oxide Particles

Heng Zhu et al.

Summary: A newly developed electrochemical approach allows direct protonation of oxide particles in a neutral electrolyte, enabling precise functionalization of the particle surface without the need for external electrical connections. By following a particle-by-particle surface protonation mechanism, this method unlocks the potential of semiconductor oxides for various applications.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution

Mariana C. O. Monteiro et al.

Summary: The study found that metal cations play a crucial role in stabilizing the CO2 intermediate during the reduction process on gold electrodes. Density functional theory simulations confirmed that partially desolvated metal cations enable the reduction by stabilizing the CO2- intermediate through short-range electrostatic interactions. In conclusion, the positively charged species from the electrolyte are key to stabilizing the crucial reaction intermediate.

NATURE CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Electrocatalysis for CO2 conversion: from fundamentals to value-added products

Genxiang Wang et al.

Summary: This article provides a comprehensive review of recent research progress on the selective electrocatalytic conversion of CO2 into value-added products. It covers the history and fundamental science of electrocatalytic CO2RR, the design, preparation, and performance evaluation of electrocatalysts, factors influencing the CO2RR, and associated theoretical calculations. Emphasis is placed on emerging trends in selective electrocatalytic conversion of CO2 and discussions on structure-performance relationships and mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Atomically Defined Undercoordinated Active Sites for Highly Efficient CO2 Electroreduction

Wanzhen Zheng et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Molecular enhancement of heterogeneous CO2 reduction

Dae-Hyun Nam et al.

NATURE MATERIALS (2020)

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Review Chemistry, Physical

Promises of Main Group Metal-Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate

Na Han et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

High-Current-Density CO2-to-CO Electroreduction on Ag-Alloyed Zn Dendrites at Elevated Pressure

Sarah Lamaison et al.

JOULE (2020)

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Article Multidisciplinary Sciences

Polymorph selection towards photocatalytic gaseous CO2 hydrogenation

Tingjiang Yan et al.

NATURE COMMUNICATIONS (2019)

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Review Energy & Fuels

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Yuvraj Y. Birdja et al.

NATURE ENERGY (2019)

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Article Multidisciplinary Sciences

pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Xinyan Liu et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Physical

A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes

Zhuo Wang et al.

JOULE (2019)

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Article Chemistry, Multidisciplinary

A Heterogeneous Metal-Free Catalyst for Hydrogenation: Lewis Acid-Base Pairs Integrated into a Carbon Lattice

Yuxiao Ding et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Review Chemistry, Multidisciplinary

Semi-solid and solid frustrated Lewis pair catalysts

Yuanyuan Ma et al.

CHEMICAL SOCIETY REVIEWS (2018)

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Article Chemistry, Multidisciplinary

Electrochemical CO Reduction Builds Solvent Water into Oxygenate Products

Yanwei Lum et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Review Chemistry, Physical

Excess electrons in reduced rutile and anatase TiO2

Wen-Jin Yin et al.

SURFACE SCIENCE REPORTS (2018)

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Article Chemistry, Multidisciplinary

Frustrated Lewis Pairs Accelerating CO2 Reduction on Oxyhydroxide Photocatalysts with Surface Lattice Hydroxyls as a Solid-State Proton Donor

Xiaohui Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Chemistry, Physical

Orbital Interactions in Bi-Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO2 Reduction toward Formate Production

Guobin Wen et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Direct observation of tin sites and their reversible interconversion in zeolites by solid- state NMR spectroscopy

Guodong Qi et al.

COMMUNICATIONS CHEMISTRY (2018)

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Review Chemistry, Multidisciplinary

Electrocatalytic Alloys for CO2 Reduction

Jingfu He et al.

CHEMSUSCHEM (2018)

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Article Chemistry, Multidisciplinary

Atomistic Mechanisms Underlying Selectivities in C1 and C2 Products from Electrochemical Reduction of CO on Cu(111)

Hai Xiao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

An NMR Scale for Measuring the Base Strength of Solid Catalysts with Pyrrole Probe: A Combined Solid-State NMR Experiment and Theoretical Calculation Study

Xianfeng Yi et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

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Article Multidisciplinary Sciences

Cu metal embedded in oxidized matrix catalyst to promote CO2 activation and CO dimerization for electrochemical reduction of CO2

Hai Xiao et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2017)

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Article Chemistry, Physical

Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

Jeremy T. Feaster et al.

ACS CATALYSIS (2017)

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Review Chemistry, Multidisciplinary

31P NMR Chemical Shifts of Phosphorus Probes as Reliable and Practical Acidity Scales for Solid and Liquid Catalysts

Anmin Zheng et al.

CHEMICAL REVIEWS (2017)

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Review Chemistry, Multidisciplinary

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

Dong Dong Zhu et al.

ADVANCED MATERIALS (2016)

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Article Chemistry, Physical

A kinetic study on the reduction of CO2 by frustrated Lewis pairs: from understanding to rational design

Lei Liu et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

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Review Multidisciplinary Sciences

The broadening reach of frustrated Lewis pair chemistry

Douglas W. Stephan

SCIENCE (2016)

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Article Chemistry, Physical

Identification of intrinsic hydrogen impurities in ZnO with 1H solid-state nuclear magnetic resonance spectroscopy

Meng Wang et al.

CHEMICAL PHYSICS LETTERS (2015)

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Article Chemistry, Physical

Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide

Ruud Kortlever et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

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Article Nanoscience & Nanotechnology

Reversible oxygen scavenging at room temperature using electrochemically reduced titanium oxide nanotubes

Thomas Close et al.

NATURE NANOTECHNOLOGY (2015)

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Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold-copper bimetallic nanoparticles

Dohyung Kim et al.

NATURE COMMUNICATIONS (2014)

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Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

Tibor Andras Rokob et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

Cornelia M. Moemming et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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Article Physics, Applied

Proton dynamics in ZnO nanorods quantified by in situ solid-state 1H nuclear magnetic resonance spectroscopy

Li-Qiong Wang et al.

APPLIED PHYSICS LETTERS (2007)

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Semiempirical GGA-type density functional constructed with a long-range dispersion correction

Stefan Grimme

JOURNAL OF COMPUTATIONAL CHEMISTRY (2006)

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Reversible, metal-free hydrogen activation

Gregory C. Welch et al.

SCIENCE (2006)

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Oxygen vacancies on TiO2(110) and their interaction with H2O and O2:: A combined high-resolution STM and DFT study

S Wendt et al.

SURFACE SCIENCE (2005)

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Insights into photoexcited electron scavenging processes on TiO2 obtained from studies of the reaction of O2 with OH groups adsorbed at electronic defects on TiO2(110)

MA Henderson et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2003)

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Article Chemistry, Physical

From molecules to solids with the DMol3 approach

B Delley

JOURNAL OF CHEMICAL PHYSICS (2000)

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Article Materials Science, Multidisciplinary

Structures of the 4X1 and 1X2 reconstructions of SnO2(110)

CL Pang et al.

PHYSICAL REVIEW B (2000)

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Article Chemistry, Multidisciplinary

Pyrrole as an NMR probe molecule to characterise zeolite basicity

M Sanchez-Sanchez et al.

CHEMICAL COMMUNICATIONS (2000)

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Selective electrocatalytic carbon dioxide reduction with electrochemically stable frustrated Lewis pairs

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