☆ 3.8 Article

Lignin Valorization for Added-Value Chemicals: Kraft Lignin versus Lignin Fractions

CHEMENGINEERING (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Review Agricultural Engineering

Lignin valorization: Status, challenges and opportunities

Sivasamy Sethupathy et al.

Summary: As an abundant aromatic biopolymer, lignin holds great potential for producing various chemicals and biofuels through biorefinery activities, contributing to a sustainable circular economy. However, lignin valorization faces challenges such as its heterogeneous nature, intrinsic recalcitrance, strong smell, dark color, difficulties in lignocellulosic fractionation, and high bond dissociation enthalpies in its functional groups. Despite these constraints, recent research and development have shown promising applications of lignin-based hydrogels, surfactants, 3D printing materials, electrodes, and fine chemicals production. This review summarizes the main limitations and possible solutions for industrial lignin valorization, and provides future perspectives based on its abundance and potential applications reported in scientific literature.

BIORESOURCE TECHNOLOGY (2022)

添加到收藏夹

Article Engineering, Chemical

Fractionation of Lignin Streams Using Tangential Flow Filtration

Jipeng Yan et al.

Summary: Fractionation of lignin using TFF was studied, and the effects of different membrane pore sizes on lignin molecular weight, sugar distribution, viscosity, and lignin functional groups were investigated. The results showed that TFF could effectively separate low-molecular-weight lignin from the aqueous stream.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

Green solvents-based molecular weight controllable fractionation process for industrial alkali lignin at room temperature

Huiqi Jin et al.

Summary: A green solvent system was developed for the molecular weight-controllable fractionation of industrial alkali lignin. The fractionation process, achieved by adjusting the ratio of water, ethanol, and gamma-Valerolactone, resulted in six levels of lignin with stepwise controllable molecular weight. The fractionation was confirmed to be a physical process without altering the chemical structure of lignin. The fractionated lignin with higher molecular weight exhibited narrower polydispersity and the fractionated lignin with lower molecular weight had higher content of hydroxyl and carboxyl groups, which could enhance its chemical reactivity in downstream applications.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

Hardwood and softwood lignins from sulfite liquors: Structural characterization and valorization through depolymerization

Filipa M. Casimiro et al.

Summary: This study evaluated the structural characteristics of lignins obtained from hardwood and softwood sulfite liquors and studied their oxidative depolymerization process. The results showed that lignin could be used as a raw material to produce high-value products such as vanillin and syringaldehyde.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2022)

添加到收藏夹

Article Biochemistry & Molecular Biology

Fractionation of lignin using organic solvents: A combined experimental and theoretical study

Veerapandian Ponnuchamy et al.

Summary: The study investigated the single-step fractionation of industrial hardwood kraft lignin using different polarity organic solvents. The experimental results showed that higher polarity solvents such as ethanol and acetone had higher solubility yield. Density functional theory (DFT) results indicated that ethanol had the highest interaction energy, followed by acetone, diethyl ether, and hexane.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

添加到收藏夹

Article Environmental Sciences

2G waste lignin to fuel and high value-added chemicals: Approaches, challenges and future outlook for sustainable development

P. Sivagurunathan et al.

Summary: This critical review discusses the isolation and transformation of lignin into value-added chemicals and materials for the economic viability of current biorefineries. It covers the chemical structure of lignocellulosic biomass/lignin, worldwide availability of lignin, and various thermochemical and biotechnological developments for the production of bio-based low molecular weight phenolics. Additionally, functional chemicals applications and challenges, opportunities, and prospects related to lignin valorization are examined.

CHEMOSPHERE (2021)

添加到收藏夹

Review Engineering, Chemical

Lignin Fractionation Methods: Can Lignin Fractions Be Separated in a True Industrial Process?

Jessica S. Rodrigues et al.

Summary: Lignin, as one of the largest natural resources in the world, has diverse applications; a better understanding of its chemical structure and valorization methods is crucial. The main challenge lies in the fractionation of lignin to obtain more homogeneous and less complex fractions.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Perspective on Technical Lignin Fractionation

Hasan Sadeghifar et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

添加到收藏夹

Article Agricultural Engineering

Kraft lignin fractionation by organic solvents: Correlation between molar mass and higher heating value

Luisa Carvalho Pereira Araujo et al.

BIORESOURCE TECHNOLOGY (2020)

添加到收藏夹

Article Engineering, Chemical

Kinetics of Oxidative Degradation of Lignin-Based Phenolic Compounds in Batch Reactor

Filipa M. Casimiro et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

添加到收藏夹

Article Biochemistry & Molecular Biology

Fractionation of lignin macromolecules by sequential organic solvents systems and their characterization for further valuable applications

Shin Young Park et al.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2018)

添加到收藏夹

Article Biochemistry & Molecular Biology

Aqueous acetone fractionation of kraft, organosolv and soda lignins

Juan Dominguez-Robles et al.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2018)

添加到收藏夹

Article Engineering, Chemical

Lignin fractionation from E. Globulus kraft liquor by ultrafiltration in a three stage membrane sequence

Carina A. Esteves Costa et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fast Fractionation of Technical Lignins by Organic Cosolvents

Yun-Yan Wang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fractionation and Characterization of Kraft Lignin by Sequential Precipitation with Various Organic Solvents

Xiao Jiang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fractionation of Organosolv Lignin Using Acetone:Water and Properties of the Obtained Fractions

Hasan Sadeghifar et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

添加到收藏夹

Article Agricultural Engineering

Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity

A. -S. Jaaskelainen et al.

INDUSTRIAL CROPS AND PRODUCTS (2017)

添加到收藏夹

Review Biochemistry & Molecular Biology

Catalytic Oxidation of Lignins into the Aromatic Aldehydes: General Process Trends and Development Prospects

Valery E. Tarabanko et al.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

New insights into the structure and composition of technical lignins: a comparative characterisation study

Sandra Constant et al.

GREEN CHEMISTRY (2016)

添加到收藏夹

Article Forestry

Structural analysis of hardwood native lignins by quantitative 13C NMR spectroscopy

Mikhail Yu Balakshin et al.

HOLZFORSCHUNG (2016)

添加到收藏夹

Article Engineering, Chemical

Radar Tool for Lignin Classification on the Perspective of Its Valorization

Carina A. Esteves Costa et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2015)

添加到收藏夹

Article Agricultural Engineering

Fractionation of five technical lignins by selective extraction in green solvents and characterisation of isolated fractions

Carmen G. Boeriu et al.

INDUSTRIAL CROPS AND PRODUCTS (2014)

添加到收藏夹

Article Agricultural Engineering

Evaluation of chemical processing impact on E. globulus wood lignin and comparison with bark lignin

Carina A. Esteves Costa et al.

INDUSTRIAL CROPS AND PRODUCTS (2014)

添加到收藏夹

Article Engineering, Chemical

Oxidation of Lignin from Eucalyptus globulus Pulping Liquors to Produce Syringaldehyde and Vanillin

Paula Cristina Rodrigues Pinto et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2013)

添加到收藏夹

Review Green & Sustainable Science & Technology

Liquid fuels, hydrogen and chemicals from lignin: A critical review

Pooya Azadi et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2013)

添加到收藏夹

Article Engineering, Chemical

Insights into Oxidative Conversion of Lignin to High-Added-Value Phenolic Aldehydes

Paula C. Rodrigues Pinto et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2011)

添加到收藏夹

Article Engineering, Environmental

Comparative study of lignin fractionation by ultrafiltration and selective precipitation

A. Toledano et al.

CHEMICAL ENGINEERING JOURNAL (2010)

添加到收藏夹

Article Engineering, Chemical

Comparative Study of Solid-Phase Extraction and Liquid-Liquid Extraction for the Reliable Quantification of High Value Added Compounds from Oxidation Processes of Wood-Derived Lignin

Paula C. Rodrigues Pinto et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2010)

添加到收藏夹

Article Biochemical Research Methods

Size-exclusion chromatography of technical lignins in dimethyl sulfoxide/water and dimethylacetamide

O Ringena et al.

JOURNAL OF CHROMATOGRAPHY A (2006)

添加到收藏夹

Article Agriculture, Multidisciplinary

A comprehensive approach for quantitative lignin characterization by NMR spectroscopy

EA Capanema et al.

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2004)

添加到收藏夹

Article Chemistry, Physical

New mechanism for the catalytic oxidation of lignin to vanillin

VE Tarabanko et al.

KINETICS AND CATALYSIS (2004)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.