Modeling and Simulation of Non-Aqueous Redox Flow Batteries: A Mini-Review

Redox flow batteries (RFBs) have been widely recognized in the domain of large-scale energy storage due to their simple structure, long lifetime, quick response, decoupling of capacity and power, and structural simplicity. Because of the limited open circuit voltage (OCV) by hydrogen and oxygen evolution reactions, together with the relatively low solubility of active species, RFBs with aqueous electrolytes are challenging to reach high energy densities. Researchers have been trying to develop new solvent systems without water to remove the electrochemical window limitation of water and pursue higher cell potential. However, non-aqueous solvents are also hindered by some key problems, such as high viscosity and poor safety. Meeting these challenges require a comprehensive understanding of relevant structural design parameters and multi-variable operation in the non-aqueous flow battery (NAFB) system. Modeling and simulation are not only an effective way to understand the basic mechanism of flow batteries at different scales of size and time but also an ideal tool for optimizing the reaction process, battery assembly, and the whole flow battery installation. This review paper introduces the development of the non-aqueous flow battery, the challenges it faces, and the research progress of related modeling and simulation for verification or optimization. Finally, the future development prospects of the non-aqueous flow battery model are pointed out, especially for those systems and fields that have not yet been explored.

Automated summary

Redox flow batteries (RFBs) are recognized for their simple structure, long lifetime, quick response, decoupling of capacity and power, and structural simplicity in large-scale energy storage. However, RFBs with aqueous electrolytes face challenges in achieving high energy densities due to limited open circuit voltage and low solubility of active species. Non-aqueous solvents are being explored to overcome these limitations, but they also have issues like high viscosity and poor safety.