期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 65, 页码 12966-12969出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04123f
关键词
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资金
- Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, Offices of Sciences, U.S. Department of Energy [DE FG02-05-ER15751]
A new (RuRhIII)-Rh-II structural motif [(bpy)(2)Ru(dpp)RhCl(tpy)](4+) with one halide on the Rh-III center demonstrates light-driven proton reduction ability, establishing that two halide ligands are not mandatory despite all prior systems containing a cis-RhCl2 catalytic site. This new design provides a novel approach to modulate Rh-III redox behavior and catalytic activity with insight into catalytic intermediates.
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