Designing Highly Active S-g-C3N4/Te@NiS Ternary Nanocomposites for Antimicrobial Performance, Degradation of Organic Pollutants, and Their Kinetic Study

The current research is about the synthesis of pure nickel sulfide, a series of Te (0, 0.5, 1, 1.5, 2, and 3 wt.%)-doped NiS (Te@NiS) nanoparticles (NPs), and a series of S-g-C3N4 (10, 30, 50, 70, and 80 wt.%)/Te@NiS nanocomposites (NCs), fabricated through a hydrothermal route. XRD and FTIR spectroscopic techniques demonstrated the successful synthesis of NPs and NCs. SEM-EDX images confirmed the flakelike structure and elemental constituents of the fabricated materials. Tauc plots were drawn, to calculate the band gaps of the synthesized samples. Te doping resulted in a significant reduction in the band gap of the NiS NPs. The photocatalytic efficiency of the NPs and NCs was investigated against MB, under sunlight. The results obtained for the photocatalytic activity, showed that 1%Te@NiS nanoparticles have an excellent dye degradation capacity in sunlight. This was made even better by making a series of SGCN/1% Te@NiS nanocomposites with different amounts of S-g-C3N4. When compared to NiS, Te@NiS, SGCN, and 70%SGCN/1%Te@NiS, the 70%SGCN/1%Te@NiS NCs have excellent antifungal ability. The higher impact of SGCN/Te@NiS, may be due to its enhanced ability to disperse and interact with the membranes and intracellular proteins of fungi. The 70%SGCN/1%Te@NiS NCs showed excellent antibacterial and photocatalytic efficiency. Thus, the 70%SGCN/1%Te@NiS NCs might prove fruitful in antibacterial and photocatalytic applications.

Automated summary

This research synthesized pure nickel sulfide nanoparticles and a series of Te-doped NiS nanoparticles, as well as a series of S-g-C3N4/Te@NiS nanocomposites, through a hydrothermal route. The synthesized materials were characterized using XRD, FTIR, and SEM-EDX techniques. The photocatalytic activity tests showed that 1%Te@NiS nanoparticles exhibited excellent dye degradation capacity under sunlight. The S-g-C3N4/1%Te@NiS nanocomposites with different amounts of S-g-C3N4 showed enhanced antifungal ability and excellent antibacterial and photocatalytic efficiency.