期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 57, 页码 11359-11361出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02800k
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资金
- EPSRC
- STFC
- Kyoto University Global Frontier Project for Young Professionals (John-Mung Advanced Program)
Gentle oxidation of lithium titanate spinel (LiTi2O4) with water at room temperature gives Li-deficient Li0.33Ti2O4. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.
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