期刊
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
卷 79, 期 -, 页码 637-+出版社
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S205698902300511X
关键词
crystal structure; azo compounds; C-H center dot center dot center dot pi and C-Cl center dot center dot center dot pi interactions; Hirshfeld surface analysis
The crystal structures and Hirshfeld surface analyses of four similar azo compounds have been studied. The compounds (I) and (II) crystallize in the monoclinic space group C2/c, while (III) crystallizes in the monoclinic space group P2(1)/c, and (IV) crystallizes in the triclinic space group P (1) over bar. The crystal structures reveal different types of interactions between molecules, leading to the formation of various layer or network structures.
The crystal structures and Hirshfeld surface analyses of four similar azo compounds are reported. (E)-1-[1-(4-tert-Butylphenyl)-2,2-dichloroethenyl]-2phenyldiazene, C18H18Cl2N2, (I), and (E)-1-[1-(4-tert-butylphenyl)-2,2-dichloroethenyl]-2-(4-methylphenyl)diazene, C19H20Cl2N2, (II), crystallize in the monoclinic space group C2/c with Z = 8, and (E)-1-[1-(4-tert-butylphenyl)-2,2-dichloroethenyl]-2-(4-methoxyphenyl)diazene, C19H20Cl2N2O, (III), in the monoclinic space group P2(1)/c with Z = 4. (E)-1-[1-(4-tert-Butylphenyl)-2,2-dichloroethenyl]-2-(3-methylphenyl)diazene, C19H20Cl2N2, (IV), crystallizes in the triclinic space group P (1) over bar with Z = 4 and comprises two molecules (A and B) in the asymmetric unit. In the crystal structures of (I) and (II), molecules are linked by C-H center dot center dot center dot pi and C-Cl center dot center dot center dot pi interactions, forming layers parallel to ((2) over bar 02), while molecules of (III) are linked by C-H center dot center dot center dot O contacts, C-H center dot center dot center dot pi and C-Cl center dot center dot center dot pi interactions forming layers parallel to ((3) over bar 02). The stability of the molecular packing is ensured by van der Waals forces between these layers. In the crystal structure of (IV), molecules are linked by C-H center dot center dot center dot pi and C-Cl center dot center dot center dot pi interactions, forming a tri-periodic network.
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